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国家自然科学基金(20472063): 作品数：15被引量：16H指数：3; 导出分析报告; 相关作者：沈琪姚英明张勇张振琴黄华更多>>; 相关机构：苏州大学南京医科大学泰州师范高等专科学校更多>>; 相关期刊：《化学研究与应用》《Science Bulletin》《Chinese Journal of Chemistry》《Journal of Rare Earths》更多>>; 相关主题：INORGANIC_CHEMISTRYLANTHANIDE晶体结构THFLANTHANIDE_COMPLEX更多>>; 相关领域：理学更多>>

(β-二亚胺基)Yb-Li双金属氯化物的合成和晶体结构: 《南京工业大学学报（自然科学版）》2008年第5期54-57,共4页黄华张振琴张勇姚英明; 国家自然科学基金资助项目(20472063); β-二亚胺基锂与无水YbCl3在四氢呋喃(THF)中按摩尔比为1∶1反应,可以高产率生成(β-二亚胺基)Yb-Li双核金属配合物LYbCl(μ-Cl)2Li(THF)2[L为{(C6H3-2,6-(CH3)2)NC(CH3)}2CH](1).配合物(1)经过元素分析、EDTA络合滴定、红外光谱分析等...; 关键词：合成晶体结构稀土金属化合物 β-二亚胺基

Metallotricycle of Lanthanide Supported by a Bridging Diamide： Syntheses and Molecular Structures of {Li（THF）3[LnCl（μ2-trans- 1,2-（NSiMe3）2C6H10）（μ2-Cl）]}2·2THF （Ln=Yb, Nd）: 《Chinese Journal of Chemistry》2007年第10期1588-1592,共5页陆澄容李红海赵蓓沈琪姚英明张勇; Project supported by the National Natural Science Foundation of China （No. 20472063）.; The reactions of dilithium salt of trans-1,2-bis（trimethylsilylamino）cyclohexane with anhydrous lanthanide trichlorides LnCl3 （Ln = Yb, Nd） in THF afforded the dianionic binuclear tricycles of lanthanide chlorides...; 关键词：METALLOMACROCYCLE bridging diamide ytterbium complex neodymium complex crystal structure

双烯酮亚胺基铕双金属配合物的合成和晶体表征(英文)被引量：1: 《化学研究与应用》2007年第7期735-739,共5页杨子健张振琴张勇姚英明沈琪; 国家自然科学基金(20472063)资助项目; 双烯酮亚胺基锂与无水三氯化铕在四氢呋喃中按1∶1的摩尔比反应可以高产率生成双烯酮亚胺基铕双核金属配合物[(DMP)2nacnac]EuCl(THF)(μ-Cl)2Li(THF)2[(DMPh)2nacnac={(2,6-Me2C6H3)NC(Me)}2CH](1)。配合于1经过全面表征,并测定了其晶...; 关键词：合成晶体结构稀土金属化合物双烯酮亚胺基

胺基桥联双芳氧基稀土金属氯化物的合成和表征(英文): 《宁波大学学报（理工版）》2007年第3期368-372,共5页戚瑞鹏王余明马猛涛姚英明张勇沈琪; Supported by the National Natural Science Foundation of China (20472063).; 无水三氯化稀土LnCl_3与1倍量的胺基桥联双芳氧基钠LNa_2[L=Me_2NCH_2CH_2N{CH_2-(2-O-C_6H_2- Bu^t-3-Me-5)}_2]在四氢呋喃中室温下反应生成胺基桥联双芳氧基稀土金属氯化物LLnCl(THF)(Ln=Yb(1),Ln=Er(2)).这些配合物都经过了元素分析...; 关键词：稀土金属胺基桥联双芳氧基合成晶体结构

Well-defined bis(phenolate) lanthanide methoxides as efficient initiators for the polymerization of cyclic carbonate and lactide被引量：3: 《Chinese Science Bulletin》2007年第12期1623-1628,共6页XU XiaoPing YAO YingMing ZHANG Yong SHEN Qi; Supported by the National Natural Science Foundation of China (Grant No. 20472063);the Innovation Project of Graduate Education of Jiangsu Province;the State Key Laboratory of Polymer Physics and Chemistry;the Key Laboratory of Organic Synthesis of Jiangsu Province; Lanthanide methoxides supported by carbon-bridged bis(phenolate) ligands 2,2′-methylene-bis(6-tert- butyl-4-methylphenoxo) (MBMP2-) [(MBMP)Ln( μ-OMe)(THF)2]2 (Ln = Nd (1), Yb (2)) were synthesized in high yields by ...; 关键词：稀土元素甲醇盐二苯酚盐配体丙交酯碳酸盐聚合物

A Novel Divalent Ytterbium Complex Supported by a Bridged Diamide Ligand： Synthesis and Structure of [{Me2Si（NPh ）2Yb（THF）2}（μ3-CI）（μ4-CI）{Li（TH F） }2]2·2THF: 《Chinese Journal of Chemistry》2007年第5期670-673,共4页陆澄容赵蓓周利英沈琪姚英明张勇; Project-supported by the National Natural Science Foundation of China （No. 20472063）.; The reaction of anhydrous YbCl3 with 1 equiv, of Li2Me2Si（NPh）2 in THF, after workup, yielded a ytterbium（Ⅲ） chloride [{Me2Si（NPh）2Yb}（μ2-CI）（TMEDA）]2·3PhMe （1）（TMEDA=tetramethylethanediamine）. The s...; 关键词：ytterbium complex bridged diamide SYNTHESIS crystal structure

Synthesis, Characterization, and Reactivity of Amine Bis(phenolato) Cyclopentadienyl Lanthanide Complexes被引量：1: 《Journal of Rare Earths》2007年第5期544-548,共5页周兰芝王余明姚英明张勇沈琪; Project supported by the National Natural Science Foundation of China (20472063);the Key Laboratory of Organic Synthesis of Jiangsu Province; （C5H5）3Ln（THF）reacted with amine bis（phenol） LH2 [ L = Me2NCH2CH2N {CH2-（2-O-C6H2-But^1-3-Me- 5）}2 ] in a 1：1 molar ratio in THF to generate the amine bis（phenolato） cyclopentadienyl lanthanide complexes LL...; 关键词：inorganic chemistry amine bis（phenolate） lanthanide complex crystal structure rare earths

Synthesis and structural characterization of lanthanide coordination polymers constructed from a 13-membered macrocycle: 《Chinese Science Bulletin》2007年第4期467-470,共4页YAO YingMing SHEN Qi WONG Wing Tak; Supported by the National Natural Science Foundation of China (Grant No. 20472063);the University of Hong Kong (WTW); The lanthanide coordination polymers bearing a 13-membered macrocycle, [(13-EDTA-pnOH)H2] were synthesized. The products [Ln(13-EDTA-pnOH)(H2O)2·NO3]n (Ln = Eu(1), Tb(2), Dy(3)) have been obtained by MS, IR and eleme...; 关键词：镧系元素复合物配位聚合物官能化大环合成结构表征

二(环戊二烯基)(双烯酮亚胺基)镱配合物的合成和晶体结构被引量：1: 《化学研究与应用》2006年第11期1336-1339,共4页黄华张勇姚英明戚瑞朋沈琪; 国家自然科学基金资助项目(20472063); Reaction of the β-diketiminate ytterbium dichloride LYbCl2（THF）2（L=2,6-Pri2C6H3）NC（Me）CHC（Me）N（C6H3-2,60Pri2）（1）with 2equiv off C5H5Na in THF gave rise to the title complex LYb（C5H5）2（2）,and the cryst...; 关键词：合成晶体结构烯土金属化合物双烯酮亚胺基

Synthesis and Characterization of A Polynuclear Yttrium Trifluoroethoxide and Its Activity for Oligomerization of Phenyl Isocyanate被引量：4: 《Journal of Rare Earths》2006年第4期509-512,共4页彭红梅姚英明邓明宇张勇沈琪; Project supported bythe National Natural Science Foundation of China (20472063); A polynuclear yttrium trifluoroethoxide was synthesized and its activity for the oligomerization of phenyl isocyanate was tested. Reaction of anhydrous YC13 with CF3CH2ONa in a 1 ： 3 molar ratio in THF at room temper...; 关键词：inorganic chemistry lanthanide alkoxo complex trifluoroethoxide crystal structure rare earths

国家自然科学基金(20472063)