Supported by the National Natural Science Foundation of China(Nos.20771013, 20476011 and 20371007)
Three new Keggin polyoxometalates, [Zn(phen)3]2[SiW12O40]'5H2O(1), [Co(phen)3]2[SiW12O40](2) and [Ni(phen)3]2[SiW12O40].2H2O(3)(phen=1,10'-phenanthroline) have been hydrothermally synthesized and chara...
Sponsored by the National Natural Science Foundation of China (20371007 ,20476011 ,20771013);Excellent Young Scholars Research Fund of Beijing Institute of Technology(2006Y0715)
The title complex, [ [ Cd(Him) (OH-BDC) (H2O)2 ]· 3H2O]n ( 1 ) (Him is imidazole, OH-H2BDC is 5-hydroxyisophthalic acid), was synthesized by liquid/liquid diffusion method at room temperature. The complex c...
A novel coordination polymers [Cu2(ETU)6]SO4(1)(ETU=ethylidene thiourea) was synthesized under solvothermal conditions.The crystal structure of the polymer was determined by X-ray diffraction: trigonal,space gro...
Supported by the National Natural Science Foundation of China(Nos. 20476011 and 20371007).
The self-assembly of clusters in inorganic systems is an interesting subject. The self-assembly of big molecules has been well established in biological systems. In addition, the coordination chemistry of metal-sulfur...
Supported by the National Natural Science Foundation of China(No.2 0 3710 0 7)
Polyoxometallates Co(en) 3PMo 12O 40·8H 2O(+,-)[abbreviated as PMo 12-Co(+,-)], nanoparticles were synthesized by the chemical precipitation reaction at room temperature for the first time. They were chara...