高等学校学科创新引智计划(B07012)

作品数:56被引量:113H指数:5
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相关作者:李前树韦天新徐文国卢士香胡长文更多>>
相关机构:北京理工大学华南师范大学成都市公安消防支队中国检验检疫科学研究院更多>>
相关期刊:《Science China Chemistry》《化学进展》《高等学校化学学报》《分析化学》更多>>
相关主题:表面等离子体共振分子印迹分子印迹膜CRYSTAL_STRUCTUREOH更多>>
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Syndiotactic Polymerization of Styrene and Copolymerization with Ethylene Catalyzed by Chiral Half-sandwich Rare-earth Metal Dialkyl Complexes被引量:1
《Chinese Journal of Polymer Science》2018年第2期222-230,共9页De-Qian Peng Xin-Wen Yan Shao-Wen Zhang Xiao-Fang Li 
financially supported by the National Natural Science Foundation of China (Nos. 20974014, 21274012, 21322401 and 21774014);the 111 project (No. B07012)
The syndiotactic polymerization of styrene(St) and the copolymerization of St with ethylene(E) were carried out by using a series of chiral half-sandwich rare-earth metal dialkyl complexes(Cp^x*) as the catalys...
关键词:HALF-SANDWICH Rare-earth metal complex Syndiotacti cpolymerization COPOLYMERIZATION STYRENE ETHYLENE 
基于可逆加成-断裂链转移聚合的孕酮分子印迹膜制备与检测被引量:1
《科学通报》2018年第1期68-77,共10页王洋 焦少勤 陈小丽 韦天新 
国家自然科学基金(20771015);高等学校学科创新引智计划(B07012)资助
基于可逆加成-断裂链转移(reversible addition fragmentation chain transfer,RAFT)聚合原理,通过紫外光引发方式,以2-(十二烷基硫代碳酸酯基)-2-甲基丙烯酸(DDMAT)作为唯一的控制试剂,在DDMAT修饰的金膜表面合成了针对孕酮分子的分子...
关键词:可逆加成-断裂链转移聚合 分子印迹物 孕酮 水相兼容 表面等离子体共振传感器 
The enhanced electronic communication in ferrocenemethanol molecular cluster based on intermolecular hydrogen-bonding
《Chinese Chemical Letters》2018年第1期179-182,共4页Yifan Yang Qing Zheng Yuanyuan Yan Yao Liu Huibo Shao 
the financial support from the National Natural Science Foundation of China(No. 21173023);National 111 Project of China(No. B07012)
This work presents an electrochemical study of enhanced electronic communication based on intermolecular hydrogen-bonding in ferrocenemethanol (described as FcCH2OH) molecular clusters. The enhanced electronic commu...
关键词:Enhanced electronic communicationlntermolecular hydrogen-bondingMolecular clustersElectron transferCyclic voltammetry 
表面接枝法制备睾酮素分子印迹表面等离子体共振传感器被引量:4
《分析化学》2016年第8期1157-1164,共8页景丽静 王洋 韦天新 
国家自然科学基金(No.20771015);高等学校学科创新引智计划(No.B07012)资助~~
构建了一种选择性检测睾酮素的分子印迹表面等离子体共振(Surface plasmon resonance,SPR)传感器。采用紫外光引发表面接枝技术,在固定引发转移终止剂的SPR芯片表面制备了以睾酮素为模板分子,甲基丙烯酸为功能单体,乙二醇二甲基丙烯酸...
关键词:表面等离子体共振 分子印迹膜 睾酮素 表面接枝 
Design and synthesis of hybrid solids based on the tetravanadate core toward improved catalytic properties被引量:2
《Chinese Chemical Letters》2016年第5期649-654,共6页Yan-Hong Niu Song Yang Ji-Kun Li Yan-Qing Xu Chang-Wen Hu 
financially supported by the National Natural Science Foundation of China (Nos. 21173021, 21231002, 21271025 and 21276026);973 Program (No. 2014CB932103);the 111 Project (No. B07012);Beijing Higher Education Youth Elite Teacher Project (No. 1209)
Five inorganic-organic hybrid vanadates based on tetravanadate cores, transition metals and N-donor ligands have been designed and synthesized under hydrothermal conditions, namely, [Zn(elM)312V4O12 (1), [Zn(plM...
关键词:Hybrid Tetrvanadate core Heterogeneous catalysts Olefin epoxidation 
Characterization of polyoxometalates by electrospray ionization mass spectrometry被引量:2
《Science China Chemistry》2015年第7期1206-1210,共5页Qiaodi Jia Yan Zhang Jie Cao 
financially supported by the National Natural Science Foundation of China(21371025);the 111 Project(B07012);a Fundamental Research Grant(20121942006)by the Beijing Institute of Technology
The electrospray behaviors of saturated, substituted, and lacunary polyoxometalates (POMs) with classic Keggin and Dawson structures were investigated systematically by electrospray mass spectrometry (ESI-MS). The...
关键词:saturated SUBSTITUTED and lacunary POMs electrospray ionization mass spectrometry cation-ion exchange process 
Reaction-path Dynamics and Theoretical Rate Constants for the Reaction of CH_3CH_2OCF_3 with HOOO Radical
《Chinese Journal of Structural Chemistry》2015年第2期167-178,共12页杨静 
supported by the the National Natural Science Foundation of China(No.21373025 and 20933001);the Research Foundation of Education Bureau of Hebei Province(No.Z2011115);the 111 Project of China(No.B07012);the Natural Science Foundation of Hebei Province(No.B2012105002);the Research Foundation of Tangshan Administration of Science&Technology(131302115b);the Research Foundation of Tangshan normal college(2013A04)
A dynamic method is employed to study the reaction mechanisms of CH3CH2OCF3 with the hydrogen trioxy (HOOO) radical. In our paper, the geometries and harmonic vibrational frequencies of all the stationary points and...
关键词:hydrogen abstraction hydrogen trioxy CH3CHzOCF3 rate constants ab initio 
基于分子印迹膜的表面等离子体共振传感器检测黄体酮被引量:1
《北京理工大学学报》2015年第2期208-212,共5页张庆文 任亚敏 韦天新 
国家自然科学基金资助项目(20771015);中国高等学校学科创新引智计划资助项目(B07012)
分别采用热聚合和光聚合的方法在金膜表面合成黄体酮分子印迹膜,并将其作为识别元件应用于表面等离子体共振传感器检测黄体酮.通过对其进行洗脱及吸附研究发现:采用乙腈/乙酸混合液可以快速将黄体酮洗脱下来,洗脱前后共振角分别移动了1...
关键词:分子印迹膜 表面等离子体共振传感器 黄体酮 
Investigation of multilevel ion-pairing effect of triferrocenylmethane in organic phase被引量:1
《Chinese Chemical Letters》2014年第10期1379-1381,共3页De-Bo Xiang Hui-Bo Shao 
the NSFC(No.21173023);the 111 Project(No.B07012) in China and the TriFcM provided from professor Hua-Zhong Yu at Simon Fraser University in Canada
The intramolecular electronic communication and multilevel ion-pairing effect of triferrocenylmethane(TriFcM) in organic phase was studied with the "thin-layer electrochemistry" approach.Three pairs of symmetric p...
关键词:Triferrocenylmethane Thin-layer electrochemistry Intramolecular electronic communication Multilevel ion-pairing effect 
基于分子印迹物薄膜的血红蛋白表面等离子共振传感器制备与检测被引量:2
《科学通报》2014年第9期779-786,共8页王洋 任亚敏 张庆文 景丽静 韦天新 
国家自然科学基金(20771015);高等学校学科创新引智计划(B07012)资助
以3-氨基苯硼酸为单体,通过化学沉积的方法在L-半胱氨酸修饰过的金膜表面合成了针对血红蛋白(hemoglobin,Hb)的分子印迹聚合物膜(molecularly imprinted polymer film,MIF),并作为表面等离子共振传感器(SPR)的识别单元.优化模板Hb同单...
关键词:分子印迹聚合物膜 表面等离子共振 血红蛋白 3-氨基苯硼酸 自组装 
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