国家自然科学基金(21136001)

作品数:31被引量:165H指数:7
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相关作者:杨祝红陆小华阳庆元刘大欢仲崇立更多>>
相关机构:南京工业大学北京化工大学浙江工业大学中国石油天然气集团公司更多>>
相关期刊:《化工学报》《Chinese Journal of Catalysis》《中国科学:化学》《Journal of Rare Earths》更多>>
相关主题:金属-有机骨架MOF催化剂团簇N更多>>
相关领域:理学化学工程一般工业技术石油与天然气工程更多>>
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Supported ionic liquid sorbents for CO_2 capture from simulated flue-gas被引量:1
《Chinese Journal of Chemical Engineering》2018年第11期2377-2384,共8页Jiajia Ren Zheng Li Yifeng Chen Zhuhong Yang Xiaohua Lu 
Supported by the National Basic Research Program of China(2013CB733503);the National Natural Science Foundation of China(21136001,21136004,21476106,21428601,21776123);the Top-notch Academic Programs Project of Jiangsu Higher Education Institutions(TAPP)and the Jiangsu Natural Science Foundation(BK20130062)
Supported ionic liquid(IL) sorbents for CO_2 capture were prepared by impregnating tetramethylammonium glycinate([N1111][Gly]) into four types of porous materials in this study. The CO_2 adsorption behavior was invest...
关键词:CO2 ADSORPTION AMINO acid IONIC LIQUID Supported IONIC LIQUID SORBENT ADSORPTION kinetics 
新型Zn^(2+)基金属有机框架结构的温度依赖的导电、发光性能及理论计算(英文)
《物理化学学报》2017年第1期242-248,共7页高义粉 庄桂林 柏家奇 钟兴 王建国 
supported by the National Key Basic Research Program of China(973)(2013CB733501);National Natural Science Foundation of China(21176221,21136001,21671172,21306169,91334013)~~
通过Zn^(2+)和1,3,5-三苯甲酸(H_3BTB)配体反应获得一种新型的四重互穿的金属有机框架结构(MOF)1。单晶体结构分析表明这是一种由中性N,N-二甲基甲酰胺(DMF)分子和H_2NMe_2^+阳离子沿b轴密封于通道的三维(10,3)网状阴离子框架结构。交...
关键词:MOFS 密度泛函理论计算 导电性 冷发光 
Nitrogen-rich porphyrinic metal-organic frameworks synthesized by postsynthetic metathesis: from inert material to active catalyst
《Science China Chemistry》2016年第8期975-979,共5页Dahuan Liu Xuan Wang Ying-Pin Chen Shuai Yuan Chongli Zhong Hong-Cai Zhou 
Financial support of the ligand and MOFs synthesis in part by the Center for Gas Separations Relevant to Clean Energy Technologies;an Energy Frontier Research Center funded by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences under Award Number DE-SC0001015;part of the U.S. Department of Energy (DOE), ARPA-e (DE-AR0000249);DOENational Energy Technology Laboratory Award (DE-FE0026472);the Welch Foundation under award number A-1725;the Welch Endowed Chair to HJZ (A-0030) for support of the structural analyses;The X-ray diffractometers, and crystallographic computing systems in the X-ray Diffraction Laboratory at the Department of Chemistry, Texas A & M University were purchased with funds provided by the National Science Foundation (CHE-9807975, CHE-0079822, CHE-0215838);The FESEM acquisition was supported by the NSF (DBI-0116835);the VP for Research Office, and the TX Eng. Exp. Station. D. Liu and C. Zhong thank the supports of Natural Science Foundation of China (21136001, 21276008);National Key Basic Research Program of China (2013CB733503);D.L. also thanks the support of China Scholarship Council (201208110375) ;Beijing Higher Education Young EliteTeacher Project (YETP0486)
With the aid of a postsynthetic metathesis method, an inert nitrogen-rich porphyrinic metal-organic framework can exhibit a high catalytic activity in one-pot deacetalization-Knoevenagel condensation reaction.
关键词:metal-organic frameworks porous coordination network post-synthetic metathesis CATALYSIS TETRAZOLATE 
Al_2O_3/Au(111)反相催化剂在CO氧化反应中界面作用的理论研究(英文)
《物理化学学报》2016年第7期1674-1680,共7页顾勇冰 蔡秋霞 陈先朗 庄镇展 周虎 庄桂林 钟兴 梅东海 王建国 
supported by the National Key Basic Research Program of China(973)(2013CB733501);National Natural Science Foundation of China(21176221,21136001,21101137,21306169,91334013)~~
氧化物负载的金催化剂具有温和条件下优异的CO催化氧化活性。实验与理论计算表明,金与氧化物两相界面在催化反应过程中具有重要地位。反相催化剂提供了全新的角度以探究界面的重要地位。本文以Au(111)表面负载Al_2O_3团簇为反相催化剂模...
关键词:反相催化剂 金催化剂 CO氧化 密度泛函理论 界面位 
吸附在TiO2(110)表面的Aun-1Ag(n=1-5)团簇的第一性原理研究被引量:2
《南京师大学报(自然科学版)》2016年第2期38-43,共6页杨广丽 岳瑞英 赵健 朱小蕾 
国家自然科学基金项目(21276122、21136001、91434109)
采用第一性原理对Au_(n-1)Ag(n=1-5)团簇所有异构体吸附在TiO_2(110)表面的负载构型进行了结构优化,并分析了负载团簇的最稳定结构的电子性质.研究结果表明:在较稳定的吸附构型中,团簇都与TiO_2表面的两配位的氧(O_(2c))相连接.将不稳定...
关键词:双金属团簇 Ti O2表面 吸附 密度泛函理论 态密度 
MOF作模板制备多孔Au/Cu_xO催化剂及其CO氧化性能被引量:8
《化工学报》2016年第6期2325-2331,共7页刘朋飞 张所瀛 杨祝红 陆小华 
国家自然科学基金项目(21136001);国家重点基础研究发展计划项目(2013CB733503);江苏高校优势学科建设工程资助项目~~
采用MOF材料作模板,通过在Cu-BTC材料表面预先负载贵金属Au再热解的方法,成功制备了具有正八面体结构的新型多孔Au/Cu_xO负载型催化剂。通过降低热解环境中的O_2浓度,调节氧化时间,实现了Au/Cu-BTC氧化产物组分的调节,分别制得了Au/Cu_2...
关键词:金属-有机骨架材料 催化剂 纳米结构 多孔材料 Cu-BTC Au/Cu2O 
Metal-organic framework MIL-53(Al): synthesis, catalytic performance for the Friedel-Crafts acylation, and reaction mechanism被引量:2
《Science China Chemistry》2015年第10期1544-1552,共9页Junlei Yan Sai Jiang Shengfu Ji Da Shi Hefei Cheng 
supported by the National Natural Science Foundation of China(21136001,21173018)
Metal-organic framework MIL-53(Al) was synthesized by a solvothermal method using aluminum nitrate as the aluminium source and 1,4-benzenedicarboxylic acid(H2BDC) as the organic ligand. The structure of samples was ch...
关键词:MIL-53(Al) CATALYST FRIEDEL-CRAFTS ACYLATION INDOLE 3-acylindoles 
Computational exploration of H_2S/CH_4 mixture separation using acid-functionalized UiO-66(Zr) membrane and composites被引量:1
《Chinese Journal of Chemical Engineering》2015年第8期1291-1299,共9页王舒萌 吴栋 黄宏亮 阳庆元 童敏曼 刘大欢 仲崇立 
Supported by the National Key Basic Research Program of China(2013CB733503);the National Natural Science Foundation of China(21136001,21276009 and 21322603);the Program for New Century Excellent Talents in University(NCET-12-0755)
A computational study was firstly performed in this work to examine the applicability of an acid-functionalized metal-organic framework(MOF), Ui O-66(Zr)-(COOH)2, in membrane-based H2S/CH4 separation. The results show...
关键词:Desulfurization Metal-organic framework Membranes Composites Molecular simulation 
金属-有机骨架材料在气体膜分离中的研究进展被引量:18
《化工进展》2015年第8期2907-2915,共9页侯丹丹 刘大欢 阳庆元 仲崇立 
国家重点基础研究发展计划(2013CB733503);国家自然科学基金重点项目(21136001);北京高等学校青年英才计划(YETP0486)项目
金属-有机骨架材料(metal-organic frameworks,MOF)由于具有高比表面积、大孔隙率、功能性孔道结构以及种类多样性等特征,在储气、分离、催化、载药和光学等领域受到重视。其中,制备纯MOF膜或基于MOF的混合基质膜(mixed matrix membrane...
关键词:金属-有机骨架材料膜 气体分离 计算化学 
Zn_3-MOF用于硝基苯的高效荧光识别被引量:2
《化工学报》2015年第8期3248-3254,共7页赵旭东 张玉田 黄宏亮 刘大欢 仲崇立 
国家重点基础研究发展计划项目(2013CB733503);国家自然科学基金项目(21136001);北京高等学校青年英才计划项目(YETP0486)~~
硝基苯(nitrobenzene,NB)可以对水体、土壤等生态系统及人体健康造成严重的危害。为了有效地识别和检测硝基苯,制备了一种微孔的荧光金属-有机骨架材料(metal-organic framework,MOF),Zn3-MOF。通过反应物浓度及比例的调节,反应时间相...
关键词:纳米材料 硝基苯 制备 荧光 再生 
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