financial support from the National Natural Science Foundation of China(Nos.21172213,21302109,21402184,and 21572217)
A simple and highly efficient one-pot method for the construction of α-hydroxyketone phosphates from terminal alkynes and H-phosphine oxides has been developed in the presence of PhI(OAc)2 and H20. The present prot...
The fnancial assistance provided by DST (under Fast Track scheme: SR/FT/CS-076/2009), New Delhi, India
A simple and efficient method has been developed for conversion of chalcone oximes to 3,5-diaryl isoxazoles in excellent yields under solvent-free conditions. The synthesized compounds were characterized by infrared s...
support by the Natural Science Foundation of China(Nos.20273021 and20173017);Province and Educational Department of Heilongjiang,China(Nos.11521068 and TB2005-16).
An ionic liquid material containing small size cation was synthesized and its composition and structure was determined by FT- IR, ^1H NMR, ^13C NMR and element analysis. However, its physical properties such as meltin...
Cobalt methanesulfonate in combination with acetic acid catalysed the chemoselective diacetylation of aldehyde with acetic anhydride at room temperature under solvent free conditions. After reaction, cobalt methanesul...
An efficient and environmental benign method is reported for the condensation of 3-methyl-1-phenyl-5-pyrazolone with carbonyl compounds in ionic liquids [Bmim]BF4 and [Bmim]PF6 catalyzed by ethylenediammonium diacetate.
We are grateful to the National Natural Science Foundation of China (No. 29932030);the NationalHigh Technology Development Project (No. 2001AA624030);the Natural Science Foundationof Guangdong Province (No. 04300569) for financial support for this work.
24-Methylenecholest-5-ene-7-oxo-3β,19-diacetate 5 was synthesized starting from stigmasterol via twelve step reactions in 4.1% overall yield. It can be served as a key intermediate for the synthesis of 24-methylenech...
We are grateful to the National Natural Science Foundation of China (No. 29932030) and Natural Science Foundation (No. 970154) of Guangdong Province for financial support for this work.
Cholest-5-en-24-oxo-3, 19-diacetate was synthesized starting from stigmasterol 3 via seven step reactions in 21.0% overall yield. It can be served as a key intermediate for the synthesis of many biologically active 1...