Financial support for this work was provided by the National Natural Science Foundation of China(nos.21673261 and 91745110);the Natural Science Foundation of Jiangsu Province(nos.BK20190002 and BK20181194);the Youth Innovation Promotion Association CAS(no.2018458);the Key Research Program of Frontier Sciences of CAS(no.QYZDJ-SSW-SLH051).
An unprecedented visible-light-induced transitionmetal-free alkynylation of alkyl pinacol boronates has been demonstrated with alkynyl phenylsulfones as the alkynylation reagents and 4CzIPN as the organic photocatalys...
supported by the China 111 Project(No. B07023, W. Wang);East China University of Science and Technology(startup funds, W. Wang);the National Natural Science Foundation of China(No. 21577037, K. Lou);the Fundamental Research Funds for the Central Universities(No. ECUST-WY1213013,K. Lou)
Hypochlorous acid (HOCI) is one of highly reactive oxygen species (ROS). It is involved in both immune defense against invading microbes and the progression of many diseases including cardiovascular disease and ne...
A shelf-stable gem-difluorinated reagent β-tosyloxy-γ,γ-difluroallylboronic acid pinacol ester has been prepared, which can be easily used for the preparation of gem-difluorinated homoallylic alcohols through Brons...
A colorimetric method for the direct determination of hydrogen peroxide in aqueous solution is described. H2O2 stoichiometrically converts 4-nitrophenyl boronic acid or 4-nitrophenyl boronic acid pinacol ester into 4-...
Asymmetric pinacol coupling of aromatic aldehydes with TiCl4-Zn in the presence of enantiopure squaric acid amidoalcohols afforded 1, 2-diols in excellent yields with high dl- diastereoselectivities and enantioselecti...
supported by the Natural Science Foundation of Hebei Province(203107);the Science Foundation of Hebei Langfang Normal College(200517).
Pinacol coupling reactions of aromatic aldehydes and ketones were carded out using Nd-36% HOAc-CH2Cl2 system with stirring at r. t. for 4 h (in 14-70% yield). The reactions in the same system gave pinacols in 10-93%...
the National Natural Science Foundation (No. 20172049) of China.
Asymmetric pinacol coupling of aromatic aldehydes mediated by low valent titanium complexes of chiral ligands derived from natural tartaric acid provided corresponding pinacols in good yields with excellent diastereo-...
ProjectsupportedbytheNationalNaturalScienceFoundationofChina (No .2 9872 0 3 5 )
Asymmetric pinacol coupling of aromatic aldehydes catalyzed by chiral diamines/low valent titanium complexes gave corresponding pinacols in good yields with high diastereoselectivity and moderate enantioselectivities.