supported by the National Key Research and Development Program of China(No.2021YFB3500700);the National Natural Science Foundation of China(No.51972024);the Natural Science Foundation of Guangdong Province(No.2022A1515010185).
Olefin hydrogenation under mild condition is crucial and challenging for industrial applications. Herein, defective UiO-66(Ce) was constructed by using cyanuric acid as the molecular etching “scissors” and further t...
supported by the National Key R&D Program of China(Grant No.2021YFB3500700);Beijing Natural Science Foundation(Grant No.L233011);Guangdong Basic and Applied Basic Research Foundation(Grant No.2022A1515010185).
Metal-organic frameworks(MOFs),renowned for structural diversity and design flexibility,exhibit potential in catalysis.However,the pursuit of higher catalytic activity through defects often compromises stability,requi...
Novel catalytic systems for the Rh‐catalyzed hydroformylation of dicyclopentadiene have been developed using tris‐H8‐binaphthyl monophosphite as ligands containing different ester substituents at the 2’‐binaphthy...
Supported by Fundamental Research Project of Commission of Science;Technology and Industry for National Defense of China(NoA1420060192)
Diels-Alder addition of dicyclopentadiene and cyclopentadiene in polar solvents has been studied to produce tricyclopentadiene(TCPD) that is a potential high-density fuel precursor. GC and MS analysis shows that the...
Constant demand growthThe global capacity of dicyclopen tadienewas around 480 thousand t/a in 2005.Major producers include Dow Chemical,Exxon Mobile, Shell and Texmark.China has abundant dicyclopentadieneresources. Th...
Endo-dicyclopentadiene was isomerized to exo-isomer by thermal treatment at evaluated temperature and pressure. The reaction temperature and pressure are key factors for this novel isomerization. This result may have ...
Supported by the National Natural Science Foundation of China(Nos 20674024 and 20374023)
The copolymerization of ethylene with dieyclopentadiene (DCP) in the presence of a constrained geometry tetramethylcyclopentadi-enyl-phenoxytitanium catalyst [ 2,4-' Bu2-6-( 2,3,4,5-Me4 -Cp ) -PhO ] TICl2, combin...
A novel novolac curing agent containing both naphthalene and dicyclopentadiene (DCPD) moieties was prepared to produce a highly heat-resistant cured polymer network. The chemical structure was characterized using Four...
Dicyclopentadiene was polymerized by reaction injection molding (RIM) using a catalyst system based on molybdenum (V) chloride and anhydrous aluminum chloride and triethylaluminum. The effect of the reaction temperatu...
Ligand effect of the catalytic system WCl6-Et2AlCl for ring opening metathesis polymerization (ROMP) of dicyclopentadiene (DCPD) was investigated. The experimental results show that adding sterically hindered phenol-2...