National Natural Science Foundation of China(51925206,U1932214,52302052,22301288);Strategic Priority Research Program of the Chinese Academy of Sciences(XDB0450301);Anhui Provincial Natural Science Foundation(2308085MB33,2308085MB31);Fundamental Research Funds for the Central Universities(20720220009,WK2060000051);National Synchrotron Radiation Laboratory(KY2060000240).
Metal−nitrogen double bonds have been commonly reported for conventional metal complexes,but the coexistence of both transition metal−nitrogen and lanthanide−nitrogen double bonds bridged by nitrogen within one compou...
supported by the National Natural Science Foundation of China(Nos.52022098 and 51972309);the Youth Innovation Promotion Association of Chinese Academy of Sciences(No.Y201910).
Spin-based interdisciplinary research has attracted considerable attention,and various applications in magnetic memory,quantum science,and precision measuring technology have been reported.In this study,we induced a f...
supported by the National Natural Science Foundation of China(51972309,52022098);the Youth Innovation Promotion Association of Chinese Academy of Sciences(Y201910);Zhejiang Provincial Natural Science Foundation of China(LR22B010001)。
Molecular machines have attracted extensive attention due to their fancy concept and their potential to influence the science and technology.The dynamic motion of encapsulated metallic clusters is a distinctive charac...
This work was supported by the National Natural Science Foundation of China(Nos.52022098,51672281,51972309,and 51832008);T.Wang particularly thanks the Youth Innovation Promotion Association of CAS(Y201910).
Paramagnetic endohedral metallofullerenes with well protected unpaired spin have potential applications in molecular-scale qubit processing and magnetoreception system. In this study, a paramagnetic metallofullerene S...
supported by the National Natural Science Foundation of China (Nos.51672281,61227902,5183200& and 51772195);Beijing Natural Science Foundation (No.2162050);the Youth Innovation Promotion Association of CAS (No.2015025);supported by High-performance Computing Platform of Peking University.We thank Dr.
Magneto-luminescent molecules have significant applications in data storage and quantum computing.However,design of these bi-functional molecules coupled with magnetic behavior and photoluminescence is still challengi...
Novel carbon nanohybrids based on unmodified metallofullerenes have been successfully fabricated for use as a new magnetic resonance imaging (MRI) contrast agent. The nanohybrids showed higher R1 relaxivity and bett...
the National Natural Science Foundation of China(Grant No.11004219);MOST of China(Grant No.2013CBA01600)
The coverage and temperature-dependent nucleation behaviors of the Gd@C82 metallofullerenes on Cu(111) have been studied by low-temperature scanning tunneling microscopy (LT-STM) in detail. Upon molecular depositi...
the Department of Education of Liaoning Province (No. 2024201057)
Density functional theory (DFT) calculations on two isomers of C68 with the minimal number of fused pentagon pairs, its anions and Sc3N as well as Sc3N@C68 (6140) metallofullerene were carded out at the B3LYP/6-3...
Project supported by the Department of Education of Liaoning Province (2024201057)
Density functional theory (DFT) was applied at the B3LYP/6-31G^* level to investigate the relative stability of the five fullerene isomers as well as the anions of C78. Full geometry optimization was carried out an...
Direct current arc discharge is used for the study on the synthesis of metallo-fullerenes (MFs) to discover whether there exist metallic silicide fullerenes and silicon fullerenes. The resultant components are isolate...