HYDROFORMYLATION

作品数:63被引量:60H指数:4
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相关作者:丁云杰李存耀姜淼刘佳严丽更多>>
相关机构:中国科学院中国科学院大学更多>>
相关期刊:《Science China Chemistry》《China Petroleum Processing & Petrochemical Technology》《Progress in Natural Science:Materials International》《Chinese Journal of Catalysis》更多>>
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Heterogeneous Co-based catalytic systems for alkene hydroformylation
《Chinese Journal of Catalysis》2025年第3期115-141,共27页Chao-an Liang Bo Zeng Baolin Feng Huibing Shi Fengqi Zhang Jianhua Liu Lin He Yuxiao Ding Chungu Xia 
国家自然科学基金(22202217,22072166,22472182);山东省科技厅支持项目(2023CXGC010607).
Hydroformylation of olefins is one of the highest-volume industrial reactions to meet the vast demands for aldehydes as well as their derivatives.Homogeneous Co complexes were the original catalysts industrialized sin...
关键词:Cobalt catalysts Alkene hydroformylation Heterogeneous catalysis Aldehyde derivatives Cobalt stabilization 
Carbon Monoxide as C1 Building Block in Fine Chemical Synthesis被引量:1
《Chinese Journal of Chemistry》2024年第2期199-221,共23页Rui M.B.Carrilho Mario J.F.Calvete Gabor Mikle Laszlo Kollar Mariette M.Pereira 
Portuguese Agency for Scientific Research"Fundacao para a Ciencia e a Tecnologia"(FCT)and COMPETE2020-UE,for funding through projects UIDB/00070/2020,UIDP/00070/2020,UIDB/00313/2020,UIDP/00313/2020 and UIDB/00285/2020 to Coimbra Chemistry Centre(CQC);NKFIH for funding through project TKP2021-EGA-17.
Carbon monoxide(CO)has become one of the most relevant and versatile renewable C1 building blocks for chemical synthesis,especially in the fine chemicals industry,due to the development of efficient and selective cata...
关键词:Carbon monoxide Fine chemicals CARBONYLATION HYDROFORMYLATION C-H functionalization 
Efficient Heterogeneous Hydroformylation over Zeolite-Encaged Isolated Rhodium Ions
《CCS Chemistry》2023年第7期1526-1539,共14页Weixiang Shang Bin Qin Mingyang Gao Xuetao Qin Yuchao Chai Guangjun Wu Naijia Guan Ding Ma Landong Li 
This work was supported by the National Natural Science Fund of China(grant nos.21872072 and 22025203);the Frontiers Science Center for New Organic Matter,Nankai University(grant no.63181206);Haihe Laboratory of Sustainable Chemical Transformations,Tianjin.
Alkene hydroformylation is an extremely important industry process currently accomplished via homogeneous catalysis.Heterogeneous hydroformylation is being avidly pursued as a more economical and sustainable process.H...
关键词:ZEOLITE isolated rhodium site heterogeneous catalysis HYDROFORMYLATION mechanism 
Examination of Milstein Ru-PNN and Rh-Tribi/Tetrabi dual metal catalyst for isomerization-linear-hydroformylation of C4 raffinate and internal olefins
《Green Synthesis and Catalysis》2022年第1期40-45,共6页Runtong Zhang Xin Yan Shao-Tao Bai Caiyou Chen Bozhao Nan Baode Ma Jialin Wen Xumu Zhang 
R.Zhang gratefully acknowledges the Free Exploration Fund from the Science and Technology Innovation Committee of Shenzhen(No.JCYJ20170817104824122);We are grateful for the financial support from the National Natural Science Foundation of China(No.22001113);the Guangdong Provincial Key Laboratory of Catalysis(No.2020B121201002).
Isomerization-linear-hydroformylation is demanding,however,not an addressed issue,for the production of value-added linear aldehydes by converting cheap and abundant internal alkenes available from bio-&petrochemical ...
关键词:Isomerization-linear-hydroformylation Ru-PNN Dual metal catalysis RAFFINATE Internal alkenes 
Enhancing the activity,selectivity,and recyclability of Rh/PPh_(3) system‐catalyzed hydroformylation reactions through the development of a PPh_(3)‐derived quasi‐porous organic cage as a ligand被引量:4
《Chinese Journal of Catalysis》2021年第7期1216-1226,共11页Wenlong Wang Cunyao Li Heng Zhang Jiangwei Zhang Lanlu Lu Zheng Jiang Lifeng Cui Hongguang Liu Li Yan Yunjie Ding 
中国科学院战略性先导科技专项(XDA21020300,XDB17020400);国家重点研发计划(2017YFB0602203);国家自然科学基金(21972018);东莞理工学院新能源材料研究中心(KCYCXPT2017005);东莞理工学院科研启动基金(KCYKYQD2017015).
In contrast to heterogeneous network frameworks(e.g.,covalent organic frameworks and metal‐organic frameworks)and porous organic polymers,porous organic cages(POCs)are soluble molecules in common organic solvents tha...
关键词:HYDROFORMYLATION TRIPHENYLPHOSPHINE Porous organic cages Chemical selectivity Linear‐regioselectivity 
Organic Ligand-Free Hydroformylation with Rh Particles as Catalyst被引量:1
《Chinese Journal of Chemistry》2020年第2期139-143,共5页Shujuan Liu Xingchao Dai Hongli Wang Xinzhi Wang Feng Shi 
Financial supports from the NSFC(No.21633013);the Cooperation Foundation of Dalian National Laboratory for Clean Energy of CAS(No.DNL201901);the"Light of West China"Program,Fujian Innovation Academy,Key Research Program of Frontier Sciences(No.Q.YZDJ-SSW-SLH051);Strategic Priority Research Program(No.XDA21020700)of the CAS are gratefully acknowledged.
Summary of main observation and conclusion An efficient and organic ligand-free heterogeneous catalytic system for hydroformylation of olefins is highly desirable for both academy and industry.In this study,simple Rh ...
关键词:CATALYST negligible ALDEHYDES 
The influence of different monodentate P-ligand mixtures on Rh-catalyzed 1-butene hydroformylation被引量:1
《Chinese Journal of Chemical Engineering》2018年第9期1943-1948,共6页Weili Jiang Jinxin Chu Jie Yang Pengyu Zang Lijie Gao Guanglin Zhou Hongjun Zhou Huibo Wei 
Supported by the National Natural Science Foundation of China(21306227);the Science Foundation of China University of Petroleum,Beijing(C201604)
Four monodentate P-ligands and their mixtures(six groups of double-ligand systems,four groups of triple-ligand systems and one group of tetra-ligand system)were used with Rh(acac)(CO)2(acac=acetylacetonate)or...
关键词:Homogeneous catalysis HYDROFORMYLATION SYNGAS 1 -Butene Rhodium catalyst 
Safe Hydroformylation of Aliphatic Alkene in a Flow Reactor
《International Journal of Organic Chemistry》2018年第1期135-141,共7页Hisashi Masui Eiki Honda Sakura Niitsu Mitsuru Shoji Takashi Takahashi 
Despite hydroformylation being a very efficient method for the transformation of alkenes, it is not commonly employed in laboratories owing to the flammable/toxic nature of hydrogen and carbon monoxide gases and the n...
关键词:HYDROFORMYLATION Flow Synthesis ALKENE Carbon MONOXIDE ALDEHYDE 
A mini review on strategies for heterogenization of rhodium-based hydroformylation catalysts被引量:5
《Frontiers of Chemical Science and Engineering》2018年第1期113-123,共11页Cunyao Li Wenlong Wang Li Yan Yunjie Ding 
Acknowledgements This work was supported by the National Natural Science Foundation of China (Grant Nos. 21273227 and 21403258) and the Strategic Priority Research Program of the Chinese Academy of Science (Grant Nos XDB 17020400).
Hydroformylation has been widely used in industry to manufacture high value-added aldehydes and alcohols, and is considered as the largest homogenously catalyzed process in industry. However, this process often suffer...
关键词:HYDROFORMYLATION porous organic ligand (POL)-supported catalysts heterogeneous catalysis high stability immobilization catalysts 
Highly regioselective hydroformylation of olefins with formic acid instead of toxic and flammable CO/H2
《Science China Chemistry》2017年第7期839-840,共2页Dongfang Xu Baoguo Zhao 
Hydroformylation is an atom-economic and highly efficient transformation from readily available olefins to various synthetically important carbonyl compounds[1].By using this transformation,the largest amount of fine ...
关键词:instead carbonyl chemicals readily Highly palladium catalyzed challenging aldehyde subsequent 
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