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Hydroformylation of olefins is one of the highest-volume industrial reactions to meet the vast demands for aldehydes as well as their derivatives.Homogeneous Co complexes were the original catalysts industrialized sin...
Portuguese Agency for Scientific Research"Fundacao para a Ciencia e a Tecnologia"(FCT)and COMPETE2020-UE,for funding through projects UIDB/00070/2020,UIDP/00070/2020,UIDB/00313/2020,UIDP/00313/2020 and UIDB/00285/2020 to Coimbra Chemistry Centre(CQC);NKFIH for funding through project TKP2021-EGA-17.
Carbon monoxide(CO)has become one of the most relevant and versatile renewable C1 building blocks for chemical synthesis,especially in the fine chemicals industry,due to the development of efficient and selective cata...
This work was supported by the National Natural Science Fund of China(grant nos.21872072 and 22025203);the Frontiers Science Center for New Organic Matter,Nankai University(grant no.63181206);Haihe Laboratory of Sustainable Chemical Transformations,Tianjin.
Alkene hydroformylation is an extremely important industry process currently accomplished via homogeneous catalysis.Heterogeneous hydroformylation is being avidly pursued as a more economical and sustainable process.H...
In contrast to heterogeneous network frameworks(e.g.,covalent organic frameworks and metal‐organic frameworks)and porous organic polymers,porous organic cages(POCs)are soluble molecules in common organic solvents tha...
Financial supports from the NSFC(No.21633013);the Cooperation Foundation of Dalian National Laboratory for Clean Energy of CAS(No.DNL201901);the"Light of West China"Program,Fujian Innovation Academy,Key Research Program of Frontier Sciences(No.Q.YZDJ-SSW-SLH051);Strategic Priority Research Program(No.XDA21020700)of the CAS are gratefully acknowledged.
Summary of main observation and conclusion An efficient and organic ligand-free heterogeneous catalytic system for hydroformylation of olefins is highly desirable for both academy and industry.In this study,simple Rh ...
Acknowledgements This work was supported by the National Natural Science Foundation of China (Grant Nos. 21273227 and 21403258) and the Strategic Priority Research Program of the Chinese Academy of Science (Grant Nos XDB 17020400).
Hydroformylation has been widely used in industry to manufacture high value-added aldehydes and alcohols, and is considered as the largest homogenously catalyzed process in industry. However, this process often suffer...
financial support from the National Natural Science Foundation of China (No. 201202108);from the Opening Project of Key Laboratory of Green Chemistry of Sichuan Institutes of Higher Education (No. LZJ1402);from the Sichuan university outstanding scholar research fund (No. 2015SCU04A05)
Rhodium catalyzed hydroformylation of α-methylstyrene was investigated in the presence of monodentate phosphine ligands L1-L6. We found that the phosphine with good n-acceptability could efficiently improve the activ...
in part supported by the National Natural Science Foundation of China (Nos. 21072018 and 21203006)
This paper studied the mechanism of the alkene insertion elementary step in the asymmetric hydroformylation (AHF) catalyzed by RhH(CO)2[(R,S)-Yanphos] using four alkene substrates (CH2=CH- Ph, CH2=CH-Ph-(p)-M...
The complex [Rh(CO)(Pz)(TPPMS)]2, (TPPMS = m-sulfonatophenyl-diphenylphosphine, Pz = Pirazolate) was evaluated as a catalyst precursor in the hydroformylation of allylbenzenes (eugenol and estragol) and terp...
Supported by the Ministry of Science and Technology of China(No.2009CB623503)
A phosphite ligand modified heterogeneous catalyst was developed for the hydroformylation of internal olefins to linear aldehydes, which showed a high activity and high regioselectivity and could be separated easily b...