O-CARBORANE

作品数：21被引量：6H指数：1
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相关领域：理学更多>>
相关作者：苗金玲聂永卞德乾更多>>
相关机构：济南大学福州大学更多>>
相关期刊：《聊城大学学报（自然科学版）》《Organic Chemistry Frontiers》《Science China Chemistry》《Chinese Journal of Structural Chemistry》更多>>
相关基金：国家自然科学基金高等学校学科创新引智计划国家重点基础研究发展计划山东省自然科学基金更多>>
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Nickel-catalyzed regioselective B(3,4,5,6)-H tetra-alkylation of o-carboranes
《Science China Chemistry》2023年第10期2836-2841,共6页Jianwei Zhao Zuowei Xie 
supported by the Research Grants Council of the Hong Kong Special Administration Region (SRFS20214S05)。
Though transition metal-catalyzed cage BH methylation has been well documented, catalytic alkylation of cage BH bonds remained elusive because transition metal alkyl complexes are prone to undergo β-H elimination. We...
关键词：nickel catalysis B-H activation CARBORANE ALKYLATION regioselectivity 
Comparison of luminescent properties of helicene-like bibenzothiophenes with o-carborane and 5,6-dicarba-nidodecaborane被引量：1
《Science China Chemistry》2018年第8期940-946,共7页Kenta Nishino Kazushi Hashimoto Kazuo Tanaka Yasuhiro Morisaki Yoshiki Chujo 
supported by Konica Minolta Science and Technology Foundation (for K.T.);a Grant-in-Aid for Scientific Research on Innovative Areas "New Polymeric Materials Based on Element-Blocks (No.2401)" (JP24102013)
This article describes comparison of the anchoring effect on electronic properties of the helicene-like bibenzothiophene between o-carborane and 5,6-dicarba-nido-decaborane. The o-carborane and nido-decaborane-fused b...
关键词：carborane helicene mechanochromism aggregation-induced emission 
Transition metal mediated functionalization of o-carboranes
《Science China Chemistry》2014年第8期1061-1063,共3页XIE ZuoWei 
Carboranes are a class of boron hydride clusters in which one or more of the BH vertices are replaced by CH units.Unlike small boranes, carboranes are kinetically and thermodynamically very stable as well as relativel...
关键词：过渡金属 碳硼烷 功能化 硼中子俘获治疗 介导 化学惰性 分子设计 纳米材料 
Reactions of a 16-electron Cp*Co half-sandwich complex containing a chelating 1,2-dicarba-closo-dodecaborane-1,2-dithiolate ligand with alkynones HC≡C-C(O)R (R=OMe,Me,Ph)被引量：2
《Science China Chemistry》2010年第10期2129-2138,共10页GUOYIQIBAYI Gulnisa 
the National Natural Science Foundation of China (20925104,90713023,20771055,20721002);the Major State Basic Research Development Program of China (2006CB806104);the National Basic Research Program of China (2007CB925101,2010CB923303)
The reaction of the 16e half-sandwich complex Cp*Co(S2C2B10H10) (1) (Cp* = pentamethylcyclopentadienyl) with excess methyl acetylene monocarboxylate, HC≡C-CO2Me, affords the 18e complexes 2-6. Compound 2 bears a B-CH...
关键词：ortho-carborane DITHIOLATE alkynone cobalt complex HALF-SANDWICH crystal structure 
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