HETEROGENIZATION

作品数:14被引量:58H指数:5
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相关领域:理学更多>>
相关期刊:《Science China Materials》《Journal of Chemistry and Chemical Engineering》《Journal of Energy Chemistry》《Science Bulletin》更多>>
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Heterogenization of a Dinuclear Cobalt Molecular Catalyst in Porous Polymers via Covalent Strategy for CO_(2)Photoreduction with Record CO Production Efficiency
《CCS Chemistry》2024年第12期3030-3040,共11页Yun-Nan Gong Si-Ya Lv Hao-Yu Yang Wen-Jie Shi Jing-Jing Wang Long Jiang Di-Chang Zhong Tong-Bu Lu 
supported by National Key R&D Program of China(grant no.2022YFA1502902);the National Natural Science Foundation of China(grant nos.22371208,22271218,22071182,and 21931007);the Science&Technology Development Fund of Tianjin Education Commission for Higher Education(grant no.2018KJ129).
Photocatalytic CO_(2)reduction into chemical fuels is a promising route for alleviating the energy crisis and environmental issues.However,reported catalysts still exhibit low catalytic efficiencies,which hinders the ...
关键词:molecular catalyst HETEROGENIZATION covalent strategy polymer photocatalysis CO_(2)reduction 
Dual roles of trifluoroborate in nickel-catalyzed ethylene polymerization:Electronic perturbation and anchoring for heterogenization被引量:1
《Chinese Chemical Letters》2023年第8期352-355,共4页Changwen Hong Zihao Wang Hui Jiang Guifu Si Maoping Song Changle Chen 
supported by National Key R&D Program of China(No.2021YFA1501700);National Natural Science Foundation of China(Nos.52025031,U19B6001 and U1904212);K.C.Wong Education Foundation.
Brookhart-typeα-diimine nickel and palladium catalysts have been extensively studied over the past several decades;however,the heterogenization of these metal complexes has received much less attention.In this contri...
关键词:Nickel catalysts Heterogeneous catalysts Olefin polymerization Polar monomer COPOLYMERIZATION 
Metallocorrole-based porous organic polymers as a heterogeneous catalytic nanoplatform for efficient carbon dioxide conversion
《Nano Research》2022年第2期1145-1152,共8页Yanming Zhao Yunlei Peng Chuan Shan Zhou Lu Lukasz Wojtas Zhenjie Zhang Bao Zhang Yaqing Feng Shengqian Ma 
supported by the National Natural Science foundation of China(NSFC)(22078241);China Scholarship Council(CSC)(No.201706250095).
Metallocorrole macrocycles that represent a burgeoning class of attractive metal-complexes from the porphyrinoid family,have attracted great interest in recent years owing to their unique structure and excellent perfo...
关键词:CORROLE porphyrinoid derivatives HETEROGENIZATION porous organic polymers(POPs) CO_(2)conversion heterogeneous catalysis 
Electroreduction of Carbon Dioxide by Heterogenized Cofacial Porphyrins被引量:1
《Transactions of Tianjin University》2022年第1期73-79,共7页Pengfei Tian Jianjun Su Yun Song Ruquan Ye Minghui Zhu 
sponsored by the Program for Professor of Special Appointment(Eastern Scholar)at Shanghai Institutions of Higher Learning and Shanghai Sailing Program(No.19YF1410600);the Young Scientists Fund of the National Natural Science Foundation of China(No.21905240);the State Key Laboratory of Marine Pollution(SKLMP)Seed Collaborative Research Fund。
Great attention has been paid to cofacial porphyrins due to their many unique advantages over their monomeric analogs.However,their synthesis is usually complicated.In this work,a facile impregnation method for prepar...
关键词:CO_(2)RR PORPHYRIN Cofacial HETEROGENIZATION 
A perspective on the electrocatalytic conversion of carbon dioxide to methanol with metallomacrocyclic catalysts被引量:6
《Journal of Energy Chemistry》2022年第1期263-275,I0008,共14页Xinyan Liu Bo-Quan Li Bing Ni Lei Wang Hong-Jie Peng 
financial support through the StartUp Fund for Outstanding Talent with grant number A1098531023601307;the National University of Singapore and Ministry of Education in Singapore for its financial support through Tier-1 projects with grant numbers R-279000-622-133 and R-279-000-622-731.
Electrocatalytic carb on dioxide reducti on(CO_(2)R)presents a promising route to establish zero-e mission carb on cycle and store in termittent ren ewable energy into chemical fuels for steady energy supply.Methanol ...
关键词:Carbon dioxide reduction METHANOL ELECTROCATALYSIS Molecular catalysts Single atom catalysts HETEROGENIZATION 
Mn-corrolazine-based 2D-nanocatalytic material with single Mn atoms for catalytic oxidation of alkane to alcohol被引量:2
《Chinese Journal of Catalysis》2021年第6期1030-1039,共10页Chun Zhu Jin-Xia Liang Yang Meng Jian Lin Zexing Cao 
国家自然科学基金(21663008,21763006,2193309,21963005,21878283,22022814);贵州省自然科学基金([2017]1029);中国科学院青年创新促进会(2017223).
Heterogenization of organic-macrocyclic metal catalysts is one of the simplest and most efficient methods for effective separation of products and cyclic application of a catalyst.By using an environmentally friendly ...
关键词:Single-atom catalyst HETEROGENIZATION Two-dimensional nanomaterials First-principles calculations C–H bond activation 
Pd1/CeO2 single-atom catalyst for alkoxycarbonylation of aryl iodides被引量:6
《Science China Materials》2020年第6期959-964,共6页Fang Chen Tianbo Li Xiaoli Pan Yalin Guo Bing H an Fei Liu Botao Qiao Aiqin W ang Tao Zhang 
financially supported by the National Natural Science Foundation of China (21776270);the Strategic Priority Research Program of the Chinese Academy of Sciences(XDB17020100);China Postdoctoral Science Foundation(2017M621170);DICP Outstanding Postdoctoral Foundation(2017YB02);Liaoning Revitalization Talents Program;dedicated funds for methanol conversion from DICP
Heterogenization of the homogeneous catalysis has been studied for almost 50 years.Single-atom catalysis has the advantages of both homo-and heterogeneous catalysis.It has been proposed,and subsequently experimentally...
关键词:single-atom catalyst ALKOXYCARBONYLATION Pd1/CeO2 heterogenization base-free 
Fabricating Pd isolated single atom sites on C3N4/rGO for heterogenization of homogeneous catalysis被引量:11
《Nano Research》2020年第4期947-951,共5页Ninghua Fu Xiao Liang Zhi Li Wenxing Chen Yu Wang Lirong Zheng Qinghua Zhang Chen Chen Dingsheng Wang Qing Peng Lin Gu Yadong Li 
This work was supported by the National Key R&D Program of China(No.2018YFA0702003);the National Natural Science Foundation of China(No.21890383,21971137);Beijing Municipal Science&Technology Commission(No.Z191100007219003)。
Metal isolated single atomic sites catalysts have attracted intensive attention in recent years owing to their maximized atom utilization and unique structure.Despite the success of single atom catalyst synthesis,dire...
关键词:heterogenization of hom ogeneous catalysis metal isolated single atoms carbon nitride reduced graphene oxide monolith catalyst 
Single-atom catalysis: Bridging the homo-and heterogeneous catalysis被引量:22
《Chinese Journal of Catalysis》2018年第5期893-898,共6页Fang Chen Xunzhu Jiang Leilei Zhang Rui Lang Botao Qiao 
supported by National Natural Science Foundation of China(21606222,21776270);Postdoctoral Science Foundation(2017M621170,2016M601350)~~
Single-atom catalysis,the catalysis by single-atom catalysts(SACs),has attracted considerable attention in recent years as a new frontier in the heterogeneous catalysis field.SACs have the advantages of both homogeneo...
关键词:Single-atom catalysis Heterogenization of homogeneous catalysts Hydroformation HYDROSILYLATION Activation of C–H bonds 
A mini review on strategies for heterogenization of rhodium-based hydroformylation catalysts被引量:5
《Frontiers of Chemical Science and Engineering》2018年第1期113-123,共11页Cunyao Li Wenlong Wang Li Yan Yunjie Ding 
Acknowledgements This work was supported by the National Natural Science Foundation of China (Grant Nos. 21273227 and 21403258) and the Strategic Priority Research Program of the Chinese Academy of Science (Grant Nos XDB 17020400).
Hydroformylation has been widely used in industry to manufacture high value-added aldehydes and alcohols, and is considered as the largest homogenously catalyzed process in industry. However, this process often suffer...
关键词:HYDROFORMYLATION porous organic ligand (POL)-supported catalysts heterogeneous catalysis high stability immobilization catalysts 
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