CYANOSILYLATION

作品数：9被引量：11H指数：2
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相关领域：理学更多>>
相关作者：朱红平吴翊乐李岩更多>>
相关机构：厦门大学大连理工大学更多>>
相关期刊：《有机化学》《Chinese Journal of Structural Chemistry》《Chinese Journal of Chemistry》《Green Energy & Environment》更多>>
相关基金：国家自然科学基金国家重点基础研究发展计划更多>>
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Recent advances in polyoxometalates acid-catalyzed organic reactions被引量：1
《Chinese Chemical Letters》2023年第5期143-154,共12页Yu-Feng Liu Chang-Wen Hu Guo-Ping Yang 
supported by the National Natural Science Foundation of China(No.22001034);Jiangxi Provincial Natural Science Foundation(No.20212BAB213001);the Open Fund of the Jiangxi Province Key Laboratory of Synthetic Chemistry(No.JXSC202008)。
Polyoxometalates(POMs)have conducive properties such as controlled Bronsted and Lewis acidity,high thermal stability,nontoxic nature,tunable solubility,and less corrosiveness.POMs have been extensively applied in cata...
关键词：POLYOXOMETALATES Acid catalysis C-C bond formation C-N bond formation C-O bond formation Heterocyclic synthesis Cyanosilylation and hydrolysis reactions 
Constructing Tertiary Alcohols with Vicinal Stereocenters:Highly Diastereo-and Enantioselective Cyanosilylation of α-Branched Acyclic Ketones and Their Kinetic Resolution被引量：3
《CCS Chemistry》2022年第6期2140-2152,共13页Wen-Biao Wu Xin Yu Jin-Sheng Yu Xin Wang Wen-Guang Wang Jian Zhou 
supported by the National Natural Science Foundation of China(grant no.21725203);the Ministry of Education(PCSIRT);The Fundamental Research Funds for the Central Universities is highly appreciated.
We report the first highly diastereo-and enantioselective C-C bond-forming reaction of racemic α-branched ketones to construct tertiary alcohols with adjacent stereocenters.Accordingly,a highly stereoselective cyanos...
关键词：tertiary alcohols with vicinal stereocenters ketone cyanosilylation kinetic resolution 
Dialkyl imidazolium acetate ionosilica as efficient and recyclable organocatalyst for cyanosilylation reactions of ketones被引量：1
《Green Energy & Environment》2020年第2期130-137,共8页Thanh Tran Duy Alysson Duarte Rodrigues Giang Vo-Thanh Peter Hesemann 
The authors thank the GDR LIPS#3585 for financial support.
We report new heterogeneous organocatalyst based on silica hybrid supported N-heterocyclic carbene(NHC-)species.The organocatalyst is formed from an imidazolium iodide based ionosilica material,followed by iodide/acet...
关键词：N-heterocyclic carbenes Ionosilica Heterogeneous organocatalysis CYANOSILYLATION Ionic liquids 
Temperature-induced Sn(Ⅱ) supramolecular isomeric frameworks as promising heterogeneous catalysts for cyanosilylation of aldehydes被引量：2
《Science China Chemistry》2020年第2期182-186,共5页Kai Sheng Li-Ming Fan Xue-Fei Tian Rakesh Kumar Gupta Linna Gao Chen-Ho Tung Di Sun 
supported by the National Natural Science Foundation of China(21822107,21571115,21827801,21671172);the Natural Science Foundation of Shandong Province(JQ201803,ZR2017MB061,ZR2017ZF003);the Taishan Scholar Project of Shandong Province of China(tsqn201812003);the Qilu Youth Scholar Funding of Shandong University and the Fundamental Research Funds of Shandong University(104.205.2.5);the State Key Laboratory of Pollution Control and Resource Reuse Foundation(PCRRF18019)
Two novel Sn(Ⅱ) supramolecular isomeric frameworks,with the identical formula of {(NH2Me2)2[Sn(BDC)(SO4)]}n,Sn-CP-1-α(1) and Sn-CP-1-β(2)(H2BDC=terephthalic acid) were synthesized under solvothermal condition and f...
关键词：supramolecular isomerism Sn(Ⅱ)coordination polymers CATALYSIS CYANOSILYLATION 
Syntheses,Structures,Fluorescence and Heterogeneous Catalysis of Coordination Polymers with 4-Benzoimidazol-1-yl-methyl Benzoic Acid and 2,2′-Dipyridine被引量：2
《Chinese Journal of Structural Chemistry》2016年第4期577-585,共9页夏莉 朱禹 王艳梅 刘盼 谢吉民 
supported by the National Natural Science Foundation of China(21171075/B010303,21103073/B030201,21306067/B060903);Innovation&Entrepreneurship Traning Program of China(201410299054Y)
Two coordination polymers called [Ni（L）2]n（1） and [Ni（2,2？-bpy）22（H2O）]n （2）（HL = 4-benzoimidazol-1-yl-methyl benzoic acid, 2,2？-bpy = 2,2＇-dipyridine） were synthesized by solvothermal reaction simultan...
关键词：coordination polymer benzimidazole catalysis cyanosilylation 
Perfectly Green Organocatalysis： Quaternary Ammonium Base Triggered Cyanosilylation of Aldehydes被引量：1
《Chinese Journal of Chemistry》2012年第9期2109-2114,共6页温叶倩 梁梦伟 王忆铭 任伟民 吕小兵 
Quaternary ammonium bases, such as aqueous （CH3）4NOH, were found to be an extraordinarily efficient cata-lyst for cyanosilylation of aldehydes. The addition reaction of trimethylsilyl cyanide （TMSCN） to equivalent...
关键词：ORGANOCATALYSIS green chemistry CYANOSILYLATION quaternary ammonium base SOLVENT-FREE 
Highly active bifunctional salenTi(Ⅳ) catalysts for asymmetric cyanosilylation of aldehydes and TMSCN
《Chinese Chemical Letters》2011年第11期1285-1288,共4页Ye Qian Wen Wei Min Ren Xiao Bing Lu 
support by a Foundation for the Author of National Excellent Doctoral Dissertation of China(No FANEDD,200759)
A novel enantiopure salen ligand bearing a diphenylphosphine oxide on the 3-position of one aromatic ring was synthesized and combined with Ti（Oi-Pr）_4 as a monometallic bifunctional catalyst for asymmetric cyanosil...
关键词：Cyanohydnn Bifunctional catalyst SALEN TMSCN Diphenylphosphine oxide 
Combined use of an alkene and a phosphine as a nucleophilic catalyst system for the cyanosilylation of carbonyl compounds被引量：1
《Chinese Science Bulletin》2010年第25期2820-2823,共4页WANG Xiu FANG Fan TIAN ShiKai 
supported by the National Natural Science Foundation of China (20732006 and 20672105) and the Chinese Academy of Sciences
The catalytic potential of carbon nucleophiles has seldom been disclosed due to their reactivity toward carbon electrophiles to form stable carbon-carbon bonds,which are too strong to be cleaved for the expected catal...
关键词：羰基化合物 亲核试剂 催化体系 烯烃 联合使用 磷化氢 甲基丙烯酸酯 三苯基膦 
Synthesis of New Bifunctional Bis(oxazolines) and Their Application in the Asymmetric Cyanosilylation of Aromatic Ketones
《有机化学》2004年第z1期3-,共1页LUO,Mei DU,Da-Ming 
Project supported by the National Natural Science Foundation of China (Nos. 20372001, 20172001).
　　Catalytic asymmetric synthesis of tertiary cyanohydrins by the addition of cyanide to a wide range of ketones has important synthetic utility, since the resulting optically active cyanohydrins are important interm...
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