ALKYNONES

作品数:5被引量:2H指数:1
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相关期刊:《Science China Chemistry》《International Journal of Organic Chemistry》《Chinese Journal of Chemistry》《Chinese Chemical Letters》更多>>
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Further Developments on the Regioselective Synthesis of 3-Aroylindole Derivatives from C-Nitrosoaromatics and Alkynones: A Novel Synthetic Approach to Pravadoline, JWH-073, Indothiazinone Analogues and Related Compounds
《International Journal of Organic Chemistry》2022年第3期127-142,共16页Luca Scapinello Federico Vavassori Gabriella Ieronimo Keshav L. Ameta Giancarlo Cravotto Marco Simonetti Stefano Tollari Giovanni Palmisano Kenneth M. Nicholas Andrea Penoni Angelo Maspero 
An uncatalyzed and easily accessible synthetic approach for the preparation of 3-aroylindoles was investigated using nitrosoarenes and aromatic terminal ethynyl ketones. Indole derivatives were produced in good yields...
关键词:NITROSOARENES ALKYNONES INDOLES Cycoaddition ANNULATION 
Nickel-catalyzed asymmetric arylative cyclization of N-alkynones:Efficient access to 1,2,3,6-tetrahydropyridines with a tertiary alcohol
《Chinese Chemical Letters》2021年第12期4038-4040,共3页Jiangyan Tian Wendian Li Ruihao Li Lin He Hui Lv 
financial support from the National Natural Science Foundation of China (Nos. 22071188, 21871212);the open foundation of CAS Key Laboratory of Molecular Recognition and Function, the "Double First-Class" Project of Shihezi University。
Nickel/(S)-t-Bu-PHOX complex catalyzed asymmetric arylative cyclization of N-alkynones has been achieved, delivering 1,2,3,6-tetrahydropyridines containing a chiral tertiary alcohol in high yields and excellent enanti...
关键词:Asymmetric catalysis ALKYNONES CYCLIZATION Nickel 
Reactions of a 16-electron Cp*Co half-sandwich complex containing a chelating 1,2-dicarba-closo-dodecaborane-1,2-dithiolate ligand with alkynones HC≡C-C(O)R (R=OMe,Me,Ph)被引量:2
《Science China Chemistry》2010年第10期2129-2138,共10页GUOYIQIBAYI Gulnisa 
the National Natural Science Foundation of China (20925104,90713023,20771055,20721002);the Major State Basic Research Development Program of China (2006CB806104);the National Basic Research Program of China (2007CB925101,2010CB923303)
The reaction of the 16e half-sandwich complex Cp*Co(S2C2B10H10) (1) (Cp* = pentamethylcyclopentadienyl) with excess methyl acetylene monocarboxylate, HC≡C-CO2Me, affords the 18e complexes 2-6. Compound 2 bears a B-CH...
关键词:ortho-carborane DITHIOLATE alkynone cobalt complex HALF-SANDWICH crystal structure 
Stereoselective Michael Addition and Michael-aldol Tandem Reaction of Diorganyl Diselenides or Disulfides with Conju-gated Alkynones Mediated by Samarium Diiodide
《Chinese Journal of Chemistry》2004年第9期958-965,共8页郑兴良 许孝良 张永敏 
the National Natural Science Foundation of China (No. 20072033) and the Specialized Research Fund for the Doctoral Program of Higher Education of China.
Stereoselective Michael addition and Michael-aldol tandem reaction of diorganyl diselenides and disulfides with conjugated alkynones mediated by samarium diiodide were studied. The reaction temperature was critical fo...
关键词:Michael addition Michael-aldol tandem reaction diorganyl diselenide or disulfide conjugated al-kynone samarium diiodide 
A New Synthetic Method of Highly Substituted Cyclopentadienes from α,β-Unsaturated Alkynones
《Chinese Journal of Chemistry》2003年第9期1203-1205,共3页郑兴良 张永敏 
theNationalNaturalScienceFoundationofChina (No .2 0 0 72 0 33)andtheSpecializedResearchFundfortheDoctoralProgramofHigherEducation
Promoted by samarium diiodide in THF, the α,β-unsaturated alkynones were reduced to afford intermolecular reductive coupling products. The multiply substituted cyclopentadienes were prepared conveniently in good yie...
关键词:samarium diiodide α β-unsaturated alkynone multiply substituted cyclopentadiene 
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