ALLYLIC

作品数：51被引量：38H指数：4
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相关领域：理学更多>>
相关作者：王刚伟张万斌杨尚东徐永强涂永强更多>>
相关机构：兰州大学上海交通大学华南理工大学更多>>
相关期刊：《有机化学》《Science Bulletin》《Green Synthesis and Catalysis》《Science China Chemistry》更多>>
相关基金：国家自然科学基金国家重点基础研究发展计划Scientific Research Foundation for the Returned Overseas Chinese Scholars, State Education Ministry更多>>
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Synthesis of chiral allylic phosphonates via asymmetric reductive cross-coupling of α-bromophosphonates and vinyl bromides
《Science China Chemistry》2023年第9期2621-2625,共5页Hepan Wang Xinxuan Li Tao XU 
supported by the National Natural Science Foundation of China (22071183);the Science and Technology Commission of Shanghai Municipality (19DZ2271500)。
Chiral phosphine-containing skeletons play a pivotal role in bioactive natural products, pharmaceuticals, chiral catalysts, and ligands. Despite considerable progress has been made in the synthesis of chiral phosphoru...
关键词：chiral phosphorus compound reductive cross-coupling α-alkenyl phosphonate nickel asymmetric reaction 
Access to chiral homoallylic vicinal diols from carbonyl allylation of aldehydes with allyl ethers via palladium-catalyzed allylic C-H borylation
《Science China Chemistry》2022年第2期298-303,共6页Tian-Ci Wang Pu-Sheng Wang Dian-Feng Chen Liu-Zhu Gong 
supported by the National Natural Science Foundation of China (21831007)。
Chiral homoallylic vicinal diols are found in many bioactive compounds and are among the most versatile functional groups in organic chemistry. Here, we describe an asymmetric carbonyl allylation of aldehydes with all...
关键词：asymmetric catalysis palladium allylic C–H borylation allyl ethers chiral phosphoric acid ALDEHYDES 
Palladium-catalyzed asymmetric allylic C–H alkylation of 1,4-dienes and glycine Schiff bases被引量：1
《Science China Chemistry》2020年第4期454-459,共6页Tian-Ci Wang Pu-Sheng Wang Liu-Zhu Gong 
Ministry of Science and Technology of China(2015CB856600);the National Natural Science Foundation of China(21672197,21602214);the Chinese Academy of Sciences(XDB20020000).
A highly regio-and enantioselective allylic C–H alkylation of 1,4-dienes with glycine Schiff bases has been established by chiral palladium-phosphoramidite catalysis. This reaction can proceed under mild conditions a...
关键词：ASYMMETRIC catalysis palladium ALLYLIC C–H ALKYLATION 1 4-diene GLYCINE Schiff base 
Advances and challenges in palladium-catalyzed intermolecular selective allylic C–H functionalization of alkenes被引量：2
《Science China Chemistry》2015年第8期1249-1251,共3页Xiaoxu Qi Pinhong Chen Guosheng Liu 
During the past decade, there was increased interest in the functionalization of the allylic C-H bond of alkenes. As opposed to traditional Trost-Tsuji reactions, this strategy avoids the prefunctionalization of the a...
关键词：AMINES Catalysis Ligands Palladium compounds 
Tandem Lewis acid catalyzed coupling/semipinacol rearrangement of allylic alcohol
《Science China Chemistry》2010年第1期147-150,共4页YUAN DaoYi,ZHANG YongQiang,TU YongQiang,CHEN ZhiHua & ZHAO Xiong State Key Laboratory of Applied Organic Chemistry Department of Chemistry,Lanzhou University,Lanzhou 730000,China 
supported by the National Natural Science Foundation of China (Grant Nos. 20621091,20672048,and 20732002);the "111" program of Chinese Education Ministry
Construction of the polyaryl quaternary unit through a ZnBr2 catalyzed tandem coupling/semipinacol rearrangement participated by allylic cations was reported for the first time.
关键词：COUPLING semipinacol REARRANGEMENT ALLYLIC CATION QUATERNARY center 
Enantioselective O-allylic alkylation of Morita-Baylis-Hillman carbonates with oxime被引量：1
《Science China Chemistry》2009年第9期1309-1313,共5页HU ZeKai CUI HaiLei JIANG Kun CHEN YingChun 
Supported by the National Natural Science Foundation of China (Grant No. 20772084)
The enantioselective O-allylic alkylation of acetophenone oxime with various Morita-Baylis-Hillman (MBH) carbonates has been accomplished by the catalysis of a commercially available cinchona alkaloid (DHQD)2PHAL. The...
关键词：asymmetric organocatalysis ALLYLIC alkylation OXIME Morita-Baylis-Hillman CARBONATES 
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