NITROXIDE

作品数:22被引量:16H指数:2
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相关领域:理学更多>>
相关作者:宋玉光刘阳平田海霞胡鹏李立存更多>>
相关机构:天津医科大学洛阳师范学院南开大学更多>>
相关期刊:《Chemical Research in Chinese Universities》《Chinese Journal of Chemistry》《Chinese Journal of Integrative Medicine》《Science China Chemistry》更多>>
相关基金:国家自然科学基金天津市自然科学基金国家重点基础研究发展计划河南省自然科学基金更多>>
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Elucidation of Acceleration Mechanisms by a Photosensitive Onium Salt for Nitroxide-Mediated Photocontrolled/Living Radical Polymerization
《Open Journal of Polymer Chemistry》2014年第3期47-55,共9页Eri Yoshida 
The acceleration mechanisms by a photosensitive onium salt for the nitroxide-mediated photocontrolled/living radical polymerization (photo-NMP) were determined. The photo-NMP of methyl methacrylate was performed by ir...
关键词:Photocontrolled/Living Radical Polymerization ACCELERATION MECHANISMS Electron Transfer (4-tert-Butylphenyl)Diphenylsulfonium TRIFLATE 4-Methoxy-2 2 6 6-Tetramethylpiperidine-1-Oxyl Oxoaminium Salt 
Synthesis, structures, and properties of two new binuclear complexes based on carboxyl-substituted nitronyl nitroxide: [M<sub>2</sub>(NITpBA)<sub>4</sub>(H<sub>2</sub>O)<sub>2</sub>] (M = Zn and Cu)
《Open Journal of Inorganic Chemistry》2013年第2期35-41,共7页Jing Chen You-Juan Zhang Kun-Tao Huang Qiang Huang Jun-Jie Wang 
Two new binuclear complexes, [M2(μ-NITpBA)4(H2O)2] (M = Zn 1 and Cu 2) [where NIpBA =?2-(4-carboxyl-phenyl)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazol-1-oxyl-3-oxide], were stylized and characterized. Magnetic susce...
关键词:Binuclear Complex Carboxyl-Substituted Nitronyl NITROXIDE Antiferromagnetic Exchange 
Nitroxide-Mediated Photo-Controlled/Living Radical Polymerization of Methacrylic Acid被引量:1
《Open Journal of Polymer Chemistry》2013年第1期16-22,共7页Eri Yoshida 
The photo-controlled/living radical polymerization of methacrylic acid (MAA) was performed at room temperature by irradiation with a high-pressure mercury lamp using azo initiators and 4-methoxy-2,2,6,6-tetramethylpip...
关键词:Photo-Controlled/Living Radical POLYMERIZATION Nitroxide-Mediated POLYMERIZATION Methacrylic Acid 4-Methoxy-2 2 6 6-Tetramethylpiperidine-1-Oxyl (4-Tert-butylphenyl)diphenylsulfonium TRIFLATE Molecular Weight Control 
Synthesis, Crystal Structure and Magnetic Properties of a Novel Azide-bridged Copper(Ⅱ) Coordination Polymers Containing Nitroxy Nitroxide被引量:1
《Chinese Journal of Structural Chemistry》2011年第9期1322-1326,共5页王玉芳 张永花 王利亚 
supported by the National Natural Science Foundations of China (Nos. 20771054 and 21071074)
A novel azide-bridged copper(Ⅱ) coordination polymer, [Cu3(NITpPy)4(N3)6]n (NITpPy = 4-pyridyl-4,4,5,5-tetramethylimidazline-3-oxide-1-oxyl), was structurally and magnetically characterized. It crystallizes i...
关键词:copper(Ⅱ) complex nitronyl nitroxide radical AZIDO magnetic properties 
SYNTHESIS AND CHARACTERIZATION OF GRAFT COPOLYMERS BASED ON POLY(p-PHENYLENE TEREPHTHALAMIDE) BACKBONE AND WELL-DEFINED POLYSTYRENE SIDE CHAINS被引量:1
《Chinese Journal of Polymer Science》2010年第2期257-267,共11页宛新华 
supported by the National Natural Science Foundation of China(No.20774001);the National Science Fund for Distinguished Young Scholars(No.20325415)
A novel dualfunctional monomer, 2-(2',2',6',6'-tetramethyl-piperidinyl-1'-oxy)methylbenzene-1,4-dioyl chloride hydrochloride, with two acid chloride groups for step-growth polymerization and a nitroxide group f...
关键词:Dualfunctional monomer Graft copolymer Nitroxide-mediated living free radical polymerization POLYCONDENSATION Wholly aromatic polyamide. 
Structure and magnetic properties of a novel heterospin 1-D chain complex containing both Cu(Ⅱ) and nitroxide radicals as spin branches被引量:2
《Science China Chemistry》2009年第9期1438-1443,共6页MA Yue, CHEN XiaoPing, CAO Dong, YAN ShiPing & LIAO DaiZheng Department of Chemistry, Nankai University, Tianjin 300071, China 
Supported by the National Natural Science Foundation of China (Grant No. 20631030);973 Project (Grant No. 2007CB815305);Natural Science Foundation of Tianjin (Grant No. 09JCYBJC05500);100 Projects of Creative Research for the Undergraduates of Nankai University in China (Grant No. BX7-207).
A novel heterospin one-dimensional (1-D) chain complex containing both Cu(Ⅱ) and nitroxide radical ligands, {[Cu(tcph)(H2O)4][Cu(tcph)(NIT3Py)2]·2H2O}n (1) (H2tcph = tetrachloro-phthalic acid, NIT3Py = 2-(3′-pyridy...
关键词:nitronyl NITROXIDE RADICAL Cu(Ⅱ) complex tetrachloro-phthalic acid crystal STRUCTURE MAGNETIC properties 
Controlled Radical Photopolymerization of n-Butyl Methacrylate in Bluk Mediated by HTEMPO
《Chinese Chemical Letters》2006年第8期1109-1112,共4页Xiao Xuan LIU Mei HAN Lun Yong DUAN Guang Guo WU 
Financially supports from the National Natural Science Foundation of China(No.20274023 and 20474036);Guangdong Province Natural Science Foundation(No.021241)are gratefully acknowledged.
Controlled radical photopolymerization of n-butyl methacrylate(n-BMA) mediated by 4-hydroxy-2,2,6,6-tetramethyl-1-piperidinyloxy(HTEMPO) was carried out in bulk at ambient temperature. It was found that obtained n...
关键词:PHOTOPOLYMERIZATION NITROXIDE n-butyl methacrylate HTEMPO. 
Synthesis of Poly(styrene-b-isoprene-b-styrene)viaNitroxide-mediated Radical Polymerization by a Novel Alkoxyamine
《Chemical Research in Chinese Universities》2005年第5期615-618,共4页GAO Long-cheng PAN Qi-wei FAN Xing-he CHEN Xiao-fang WAN Xin-hua ZHOU Qi-feng 
Supported by the National Natural Science Foundation of China(No. 20134010) ;the Science Research Fund of the Minis-try of Education of P. R. China(No. 104005).
Bifunctional alkoxyamine bis-TIPNO derived from 2,2,5-trimethyl-4-phenyl-3-azahexane-3-oxyl (TIPNO) and α, ω-alkyl bromide by atom transfer radical addition(ATRA) was employed as “biradical initiator” for nitr...
关键词:Radical polymerization Block copolymer NITROXIDE ISOPRENE 
Electrocatalytic Oxidation of Vitamin B6 by 4-Hydroxy- 2,2,6,6-tetramethylpiperidine-N-oxyl被引量:3
《Chinese Journal of Chemistry》2004年第11期1356-1358,共3页李燕 文小林 刘中立 
Project supported by the National Natural Science Foundation of China (Nos. 20172025 and 20332020).
The electrochemistry of pyridoxine (vitamin B6, VB6) was studied by cyclic voltammetry at a glassy carbon electrode. The electrochemical response of VB6 could be significantly enhanced by using 4-hydroxy-2,2,6,6-tetra...
关键词:cyclic voltammetry catalytic electrooxidation vitamin B6 NITROXIDE 
SYNTHESIS OF TRIBLOCK COPOLYMERS OF STYRENE AND ISOPRENE BY A NITROXIDE-MEDIATED LIVING FREE RADICAL POLYMERIZATION被引量:2
《Chinese Journal of Polymer Science》2004年第1期55-61,共7页P. Najafi Mogaddam A. Entezami 
The controlled free radical polymerization of styrene and isoprene initiated with benzoyl peroxide (BPO) in the presence of 2,2,6,6-tetramethyl piperidine-N-oxyl (TEMPO) at 125 'C were performed. The obtained polyisop...
关键词:Diblock and triblock copolymer Controlled radical polymerization TEMPO Polystyrene POLYISOPRENE 
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