CYCLOPROPANOLS

作品数：4被引量：2H指数：1
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Synthesis of C2-Spiroindolines Based on the Cascade Reaction of 2-Aryl-3H-indoles with Cyclopropanols
《有机化学》2025年第2期694-706,共13页Xueying Yang Yuanshuang Xu Xinying Zhang Xuesen Fan 
国家自然科学基金(U2004189);中原科技创新领军人才项目(224200510009);河南省博士后基金(HN2022041)。
A novel synthesis of C2-spiroindoline derivatives based on the cascade reaction of 2-aryl-3H-indoles with cyclo- propanols is presented. The formation of product involves Rh(III)-catalyzed aryl C(sp2)—H bond alkylati...
关键词：C2-spiroindolines SYNTHESIS C-H bond activation cascade reaction 2-aryl-3H-indoles CYCLOPROPANOLS 
Facile access to β-hydroxyl ketones via a cobalt-catalyzed ring-opening/hydroxylation cascade of cyclopropanols被引量：1
《Chinese Chemical Letters》2023年第3期322-325,共4页Shengxian Zhai Shuxian Qiu Shuangtao Yang Xingyuan Gao Xinyu Feng Chenzhe Yun Ning Han Yongsheng Niu Jing Wang Hongbin Zhai 
State Key Basic Research Program of the People's Republic of China(No.2018YFC0310900);National Natural Science Foundation of China(Nos.21871018,21732001);Shenzhen Science and Technology Innovation Committee(Nos.KQTD20190929174023858,JCYJ20180504165454447);Industry and Information Technology Bureau of Shenzhen Municipality(No.201806151622209330);Guangdong Science and Technology Program(No.2017B030314002);Shenzhen-Hong Kong Institute of Brain Science-Shenzhen Fundamental Research Institutions(No.2019SHIBS0004);the National Ten Thousand Talent Program(the Leading Talent Tier)for the financial support;the Science and Technology Project of Henan Province(No.202102310328);the PhD Start-up Program of Anyang Institute of Technology(No.BSJ 2021042);Guangzhou Basic and Applied Basic Research Project in China(Nos.202102020134,202102020690);Youth Innovation Talents Project of Guangdong Universities(natural science)in China(No.2019KQNCX098);the Henan Postdoctoral Foundation and the Postdoctoral Innovation Base of Anyang Institute of Technology for financial support。
A cobalt-catalyzed ring-opening/hydroxylation cascade of highly strained cyclopropanols has been developed for the first time. The reaction was conducted under open-air atmosphere to afford a broad series of structura...
关键词：Cobalt catalysis RING-OPENING Cyclopropanol β-Hydroxy ketone Cascade reaction 
Recent advances using cyclopropanols and cyclobutanols in ring-openingasymmetric synthesis被引量：1
《Green Synthesis and Catalysis》2022年第3期219-226,共8页Hong Yan Gregory S.Smith Fen-Er Chen 
Financial support from the Fuzhou University(No.0041/511095)is gratefully acknowledged.We also thank Liuhui Xu for drawing many chemical structures.
Due to high ring strain energies,cyclopropanols and cyclobutanols have a strong tendency of breaking theendocyclic C–C bonds to participate in versatile organic transformations.With an inherent three-dimensionalstruc...
关键词：Cyclopropanol Cyclobutanol RING-OPENING C–C bond cleavage Asymmetric synthesis 
Cobalt-catalyzed atom-economical, diastereo-and enantioselective coupling of aldimines and cyclopropanols
《Science China Chemistry》2021年第10期1750-1755,共6页Zhikun Liang Qinglei Chong Fanke Meng 
the National Natural Science Foundation of China (21702222, 21821002, 92056103);Shanghai Rising-Star Program (19QA1411000)。
Catalytic generation of cobalt enolates through ring-opening of easily accessible cyclopropanols, subsequent β-hydride elimination and site-selective reinsertion followed by diastereo-and enantioselective additions t...
关键词：COBALT enantioselective catalysis HOMOENOLATE Mannich reaction cyclopropanol 
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