HALOCYCLIZATION

作品数:4被引量:3H指数:1
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相关期刊:《Organic Chemistry Frontiers》《Science China Chemistry》《Chinese Journal of Chemistry》《Chinese Chemical Letters》更多>>
相关基金:国家自然科学基金更多>>
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The applications of catalytic asymmetric halocyclization in natural product synthesis
《Organic Chemistry Frontiers》2022年第2期499-516,共18页Jiahang Yan Zhiqiang Zhou Qiaoqiao He Guzhou Chen Hongbo Wei Weiqing Xie 
grateful for financial support from the National Natural Science Foundation of China(grants 21722206,21672171);Financial support from the Scientific Fund of Northwest A&F University is also acknowledged.
Halocyclization of olefinic substrate enables the establishment of cyclic skeletons via intramolecular halonium-induced nucleophilic addition,which has been well utilized as a practical strategy for constructing cycli...
关键词:synthesis. CYCLIZATION ASYMMETRIC 
Pd-catalyzed halocyclizations of unactivated 1,6-diynes through a formal anti-carbopalladation/bromide radical cascade
《Chinese Chemical Letters》2021年第9期2756-2760,共5页Zhihua Wang Li Wei Zhendong Cheng Jianhui Xia Zhiyuan Chen 
National Natural Science Foundation of China(No.21961015);the Natural Science Foundation of Jiangxi Province(No.20202ACBL203005)for financial support;the Open Project Program of Polymer Engineering Research Center,Jiangxi Science&Technology Normal University(No.KFGJ18014)。
We report a Pd-catalyzed halocyclization of unactivated 1,6-diynes with N-bromosuccinimide(NBS).This approach produces stereo-defined dibromo substituted dihydropyrans,tetrahydropyridines,and 3-methylene cyclohexenes ...
关键词:Palladium catalysis HALOCYCLIZATION Unactivated diyne anti-Carbopalladation Bromide radical 1 3-Diene 
Electrochemical Dearomative Halocyclization of Tryptamine and Tryptophol Derivatives被引量:1
《Chinese Journal of Chemistry》2020年第10期1070-1074,共5页Kun Liu Yuqi Deng Wenxu Song Chunlan Song Aiwen Lei 
This work was supported by the National Natural Science Foundation of China(No.21520102003);the Hubei Province Natural Science Foundation of China(No,2017CFA010);The Pro-gram of Introducing Talents of Discipline to Universities of China(111 Program)is also appreciated.
Summary of main observation and conclusion Owing to the easy functionalization of 3-haloindolines to many biologically active compounds,extensive efforts have been made for their efficient preparation.Herein,an electr...
关键词:conditions. CYCLIZATION SUBSTITUTED 
Synthesis of bromoallenyl pyrrolidines via 1,4-addition to 1,3-enynes被引量:2
《Science China Chemistry》2011年第1期56-60,共5页WERNESS Jenny B. TANG WeiPing 
the University of Wisconsin-Madison and the American Chemical Society Petroleum Research Fund (48092-G) for funding
The discovery of the novel reactivity of conjugated enynes,mediated by readily available halogenation reagents,opens a broad range of mechanistically unique pathways for the synthesis of highly functionalized chiral a...
关键词:HALOCYCLIZATION HALOGENATION conjugated enynes ALLENE bromoallene PYRROLIDINE 
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