supported by the National Natural Science Foundation of China(22171206);the Natural Science Foundation of Zhejiang Province(Z23B020002,LY22B020003,);the Open Foundation of Hunan Provincial Key Laboratory of Controllable Preparation and Functional Application of Fine Polymers(E22307);the Open Research Fund of School of Chemistry and Chemical Engineering,Henan Normal University(2020ZD04)。
β-Chiral sulfones are structural motifs widely found in natural products and bioactive molecules, while also serving as important intermediates for the synthesis of valuable chiral scaffolds. In contrast to the rapid...
This work was supported by the National Natural Science Foundation of China(22071267);the Open Project of State Key Laboratory of Natural Medicines(SKLNMZZ202023);the Innovation Team of“the Double-First Class”Disciplines(CPU2018GY35).
An unprecedented palladium-catalyzed asymmetric carbamoyl-carbonylation of tethered alkenes with CO and alcohols has been developed.This reaction provided an efficient route to access oxindoles andγ-lactams bearingβ...
the National Natural Science Foundation of China(21532006,21690074);Chinese Academy of Sciences(XDB17020300,SSW-SLH035)。
A Ru-catalyzed hydrogenative desymmetrization of 2,2,5-trisubstituted cyclohexane-1,3-diones was developed for construction of three stereocenters including two coherent and discontiguous chiral centers and a chiral q...