STEREOCENTERS

作品数:17被引量:15H指数:3
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相关领域:理学更多>>
相关作者:张勇健更多>>
相关机构:上海交通大学更多>>
相关期刊:《Science China Chemistry》《Chinese Journal of Catalysis》《Chinese Journal of Chemistry》《Organic Chemistry Frontiers》更多>>
相关基金:国家自然科学基金湖北省自然科学基金更多>>
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  • 期刊=Science China Chemistryx
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SO_(2)-Insertion induced enantioselective oxysulfonylation to access β-chiral sulfones with quaternary carbon stereocenters被引量:1
《Science China Chemistry》2024年第3期908-913,共6页Jun Zhang Xuefeng Wang Peiqi Wang Jiayuan Fang Shaoyu Li Jie Wu 
supported by the National Natural Science Foundation of China(22171206);the Natural Science Foundation of Zhejiang Province(Z23B020002,LY22B020003,);the Open Foundation of Hunan Provincial Key Laboratory of Controllable Preparation and Functional Application of Fine Polymers(E22307);the Open Research Fund of School of Chemistry and Chemical Engineering,Henan Normal University(2020ZD04)。
β-Chiral sulfones are structural motifs widely found in natural products and bioactive molecules, while also serving as important intermediates for the synthesis of valuable chiral scaffolds. In contrast to the rapid...
关键词:β-chiral sulfones sulfur dioxide insertion oxysulfonylation copper catalysis ENANTIOSELECTIVITY 
Palladium-catalyzed asymmetric carbamoyl-carbonylation of alkenes
《Science China Chemistry》2021年第8期1367-1371,共5页Ziwen Feng Qiuyu Li Long Chen Hequan Yao Aijun Lin 
This work was supported by the National Natural Science Foundation of China(22071267);the Open Project of State Key Laboratory of Natural Medicines(SKLNMZZ202023);the Innovation Team of“the Double-First Class”Disciplines(CPU2018GY35).
An unprecedented palladium-catalyzed asymmetric carbamoyl-carbonylation of tethered alkenes with CO and alcohols has been developed.This reaction provided an efficient route to access oxindoles andγ-lactams bearingβ...
关键词:CARBONYLATION OXINDOLES γ-lactams asymmetric catalytic synthesis quaternary carbon stereocenters 
Construction of three stereocenters via hydrogenative desymmetrization of 2,2,5-trisubstituted cyclohexane-1,3-diones被引量:4
《Science China Chemistry》2021年第2期232-237,共6页Yi-Xuan Ding Zhou-Hao Zhu Han Wang Chang-Bin Yu Yong-Gui Zhou 
the National Natural Science Foundation of China(21532006,21690074);Chinese Academy of Sciences(XDB17020300,SSW-SLH035)。
A Ru-catalyzed hydrogenative desymmetrization of 2,2,5-trisubstituted cyclohexane-1,3-diones was developed for construction of three stereocenters including two coherent and discontiguous chiral centers and a chiral q...
关键词:DESYMMETRIZATION HYDROGENATION 1 3-cyclohexanediones three stereocenters chiral quaternary carbon 
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