AMINOLYSIS

作品数:18被引量:7H指数:1
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相关领域:理学化学工程更多>>
相关作者:付阳王秀丽尚玉俊姜磊任志勇更多>>
相关机构:河南省科学院更多>>
相关期刊:《Chinese Journal of Structural Chemistry》《Chinese Journal of Chemical Engineering》《Open Journal of Physical Chemistry》《Science China Chemistry》更多>>
相关基金:国家自然科学基金国家重点基础研究发展计划中国博士后科学基金高等学校学科创新引智计划更多>>
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Semi-synthesis of biotin-bearing activity-based ubiquitin probes through sequential enzymatic ligation,N-S acyl transfer and aminolysis reaction
《Chinese Chemical Letters》2023年第6期362-365,共4页Yu Wang Qiong Xia Xiao Hua Yanyan Guo Jing Shi Yi-Ming Li 
supported by the National Key R&D Program of China(No.2017YFA0505400);the National Natural Science Foundation of China(Nos.21877024,21972214 and 22277020)。
Activity-based Ubiquitin probes(Ub-ABPs)carrying a reporter group have emerged as effective tools for the investigation of deubiquitinating enzymes(DUBs),such as studying the molecular mechanism of DUBs,profiling new ...
关键词:UBIQUITINATION Deubiquitinating enzyme Activity-based ubiquitin probes Biotin tag Protein semi-synthesis 
Constructing Versatile Hydrophilic Surfaces via in-situ Aminolysis
《Chinese Journal of Structural Chemistry》2021年第11期1525-1534,1409,共11页CHEN Shuo HUANG Wei YANG Ke XU Yan-Lian WANG Dong-Hui HUANG Wei-Guo 
supported by the funding(E055AJ0101)from FJIRSM-CAS;National Natural Science foundation of China(51803214)。
Surface hydrophilization is required for numbers of applications such as biosensor,biomedical implants and marine coating.However,the preparation of hydrophilic surface from a solid substrate still suffers from limite...
关键词:surface hydrophilization in-situ aminolysis antifogging SELF-CLEANING ANTIFOULING regeneration 
Aminolysis of ethyl acetate in continuous flow and its reaction kinetics被引量:1
《Chinese Journal of Chemical Engineering》2019年第12期2948-2952,共5页Tao Shen Bo Ouyang Chao Qian Xinzhi Chen 
financial support from the National Natural Science Foundation of China(21476194);the National Key Research and Development Program of China(2016YFB0301800).
The aminolysis of ethyl acetate was promoted significantly via continuous reaction in a tubular reactor.Npropylacetamide was thus synthesized without presence of solvent and catalyst.The optimum conditions were obtain...
关键词:TUBULAR REACTOR Reaction KINETICS ETHYL ACETATE AMINOLYSIS 
Theoretical Studies on the Aminolysis of Ester: Effects of the Catalysis and Substituent to the Reaction of Methyl Indole-3-acetate with Ammonia被引量:1
《Chinese Journal of Structural Chemistry》2019年第6期855-866,共12页ZHANG Liang CHEN Rong LIANG Guo-Ming 
supported by the Special Funds of the National Natural Science Foundation of China(No.11347161)
A comprehensive exploration of the aminolysis mechanism for methyl indole-3-acetate with ammonia is carried out by employing the B3 LYP/6-311++G(d,p), M06-2 X/6-311++G(d,p) and MP2/6-311++G(d,p)//M06-2 X/6-311++G(d,p)...
关键词:AMINOLYSIS METHYL indole-3-acetate mechanism catalytic EFFECT SUBSTITUENT EFFECT 
Mechanism for acetic acid-catalyzed ester aminolysis
《Chinese Chemical Letters》2018年第8期1233-1236,共4页Chang Xiao Song-Lin Zhang 
supported by the National Natural Science Foundation of China (No. 21472068);Financial support from MOE & SAFEA for the 111 Project (No. B13025)is also gratefully acknowledged
This paper reports a computational study elucidating reaction mechanism for amide bond formation from esters and amines catalyzed by acetic acid. Two optional mechanisms(namely, classic stepwise and concerted acyl su...
关键词:Amide bond formation AMINOLYSIS MECHANISM ESTER Concerted acyl substitution Acid catalyzed amidation 
Glycopeptide ligation via direct aminolysis of selenoester
《Chinese Chemical Letters》2018年第7期1127-1130,共4页Jing-Jing Du Ling-Ming Xin Ze Lei Shi-Yao Zou Wen-Bo Xu Chang-Wei Wang Lian Zhang Xiao-Fei Gao Jun Guo 
supported by the National Key Research and Development Program of China (No. 2017YFA0505200);the National Natural Science Foundation of China (No. 21772056);Jiangxi Key Laboratory for Mass Spectrometry and Instrumentation Open Foundation (No. JXMS201701);the self-determined research funds of CCNU from the colleges' basic research and operation of MOE (No. CCNU18TS011);the Program of Introducing Talents of Discipline to Universities of China(111 program, No. B17019)
Direct aminolysis of selenoester in aqueous media was investigated as a glycopeptide ligation strategy.This strategy allows the peptide and glycopeptide ligation to proceed smoothly(even with hindered amino acids) wit...
关键词:Glycolpeptide AMINOLYSIS Selenoester Additive-free MUC1 mucin 
Facile synthesis of CF_3-substituted dienamides via one-pot tandem reactions
《Chinese Chemical Letters》2017年第7期1469-1472,共4页Zhe-Zhe Yuan Xiang-Wen Kong Li-Hua Liu Hui-Xia Zhu Hua Xiao 
supported by the National Natural Science Foundation of China (No. 21302034);the Fundamental Research Funds for the Central Universities (No. 2013HGQC0028)
A one-pot reaction sequence of sequential phosphine-promoted tandem annulations of aryl trifluoromethyl ketones and MBH(Morita-Baylis-Hillman) carbonates and DBU-mediated aminolysis was developed. This method provid...
关键词:Dienamides Aminolysis Butenolide Phosphine catalysis One-pot 
Solution-processable graphenes by covalent functionalization of graphene oxide with polymeric monoamines被引量:2
《Science China Chemistry》2016年第8期1018-1024,共7页Jing Wang Ke Feng Nan Xie Zhi-Jun Li Qing-Yuan Meng Bin Chen Chen-Ho Tung Li-Zhu WU 
supported by the Ministry of Science and Technology of China (2014CB239402, 2013CB834505, 2013CB834804);the National Natural Science Foundation of China (91427303, 21372232, 21204052);the Key Research Programme of the Chinese Academy of Sciences (KGZD-EW-T05);the Foundation of Director of TIPC
We develop here a simple wet chemistry to prepare covalent functionalized graphenes (FGs) through epoxide aminolysis espe- cially under alkaline aqueous condition. Remarkably, a series of typical monoamines, such as...
关键词:epoxide aminolysis polymeric monoamines hydrophilic and hydrophobic graphenes solution-processable 
Novel Concise Synthesis of (-)-Clausenamide1被引量:1
《Chinese Journal of Chemistry》2013年第3期344-348,共5页Di Liu Xiaoming Yu Liang Huang 
A six-step synthesis of (-)-clausenamide is described. Optically pure (R,E)-1,3-diphenylallylic alcohol was ac-etylated and then subjected to an Ireland-Claisen rearrangement, giving the γ,δ-unsaturated acid, wh...
关键词:(-)-clausenamide diastereoselective synthesis Ireland-Claisen rearrangement diastereoselectivebromo|actonization bromo-c^-lactone aminolysis 
In-depth study on aminolysis of poly(ε-caprolactone): Back to the fundamentals被引量:1
《Science China Chemistry》2012年第11期2419-2427,共9页ZHU Yang MAO ZhengWei SHI HuaYu GAO ChangYou 
financially supported by the National Natural Science Foundation of China (20934003);the National Basic Research Program of China (2011CB606203)
The aminolysis can effectively introduce primary amine (- quent surface fiiofunctionalization reactions. However, less NH2) groups onto polyester materials, enabling a variety of subse- attention has been paid to th...
关键词:poly(ε-caprolactone) AMINOLYSIS surface modification BIOMATERIALS 
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