the National Natural Science Foundation of China(21773243,21973095);the Strategic Priority Research Program of the Chinese Academy of Sciences(XDB20010200)。
Three dinuclear cyanide-bridged complexes[Fe^(Ⅱ)(PY_(5)OMe_(2))CNM^(Ⅱ)(PY_(5)OMe_(2))](OTf)_(3) (M=Fe1,M=Co 2,M=Mn 3)(PY_(5)OMe_(2)=2,6-bis-((2-pyridyl)methoxymethane)pyridine OTf=CF_(3)SO_(3)^(-)) have been synthes...
Supported by the Science and Technology Research Project of Hubei Provincial Department of Education(China,No.Q20174302);the Scientific Research Foundation of Jingchu University of Technology(No.QN201602);National college students innovation and entrepreneurship training program(No.201811336003,China)
Tricyanide building block K[Ru(ttpy)(CN)3] and [MnⅢ(salen)](ClO4) have been used to design and synthesize a heterobimetallic one-dimensional(1D) zigzag chain complex 1,[RuⅡ(ttpy)(CN)3 MnⅢ(salen)](ttpy = 4′-(p-toly...
partly supported by the NNSFC(Nos.21301023,21501021,11474045);the 2014 Program for Liaoning Excellent Talents in University(No.LJQ2014138);the Program for Dalian Excellent Talents(No.2017RQ148);the Fundamental Research Funds for the Central Universities(wd01157);the 2017 Training Program of Innovation and Entrepreneurship for Undergraduates in Dalian Minzu University(201712026150 and 201812026150)
The reaction of tricyanometallate precursor, Bu_4N[Fe(Tp)(CN)_3] and(Bu_4N)[(pzTp)Fe(CN)_3](Tp = tris(pyrazolyl)hydroborate, pzTp = tetrakis(pyrazolyl)borate) with Ni(ClO_4).26 H_2O in the presence of the monodentate ...
Supported by the Project of Hubei Provincial Department of Education(No.Q20144302 and Q20164302);the Natural Science Foundation of Hubei Province(No.2013CFA015);the Doctoral Scientific Research Foundation of Jingchu University of Technology(No.QDB201603);the Open Project Program of Hubei Key Laboratory of Drug Synthesis and Optimization,Jingchu University of Technology(No.OPP2016ZD02)
Dicyanide building block cis-Fe(phen)2(CN)2 and [MnⅢ(salen)](ClO4) have been used to design and synthesize a cyanide-bridged complex, resulting in a heterobimetallic one-dimensional(1D) zigzag chain complex...
supported by the 973 Program(2012CB821702,2014CB845603);the National Natural Science Foundation of China(21233009,21203194 and 21173223)
A new mixed-valence cyanide-bridged complex, Br3Fe(p-NC)RuBr(dppm)2 (dppm = bis(diphenylphosphino)methane), was obtained through the reaction between trans-(dppm)2C1- RuCN and FeBr3. Its crystal structure wa...
Composite materials composed of LiMnO2, a typical electrode material for lithium ion battery, and a chiral cyanide-bridged Ni(Ⅱ)-Fe(Ⅲ) coordination polymer [NiL2][Fe(CN)6]·4H2O (Ni-Fe, H-form) (L = (1R,2R...
supported by grants from the 973 Program(2012CB821700);the National Natural Science Foundation of China(21073192,20871114 and 21173223);the Science Foundation of CAS(KJCX2-YW-H20)and of Fujian Province(2009HZ0006-1)
A new tetranuclear cyanide-bridged complex [PPh4]2[NiⅡ(CN)4CuⅠ(PPh3)2]2·2CH3OH ([PPh4]+ = tetraphenylphosphine cation, PPh3 = triphenylphosphine) 1 has been synthesized and characterized by IR spectroscopy, ...
financially supported by the National Natural Science Foundation of China;Ministry of Education of China;Beijing Municipal Commission of Education;Fundamental Research Funds for the Central Universities
supported by the National Research Foundation of Korea Funded by the Korean Government (2011-0003264);by the Priority Research Centers Program through the National Research Foundation of Korea (NRF) Funded by the Ministry of Education, Science and Technology (NRF20110018396)
Reaction of unique [W(CN)6(phen)]- with a magnetically anisotropic Mn Schiff base yielded a wv(5d)-Mnm(3d) bimetallic compound with a linear chain structure. The magnetic properties of the chain complex featur...
financial support from the National Natural Science Foundation of China (21101021, 91122031)
Using Bu4N[Fe(Tp*)(CN)3]- (Tp* = hydrotris(3,5-dimethylpyrazol-l-yl)borate) as the building block to react with Cun and N-methylimidazole, we obtained a one-dimensional (1D) beterobimetallic cyano-bridged chain, [Fe(T...