HETEROCYCLIC

作品数:164被引量:182H指数:6
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相关领域:理学更多>>
相关作者:杨鹰朱红平惠新平刘艳红赵娜更多>>
相关机构:厦门大学兰州大学云南烟草科学研究院江苏师范大学更多>>
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相关基金:国家自然科学基金中国博士后科学基金国家重点基础研究发展计划泰国研究基金更多>>
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Rhodium-Catalyzed Asymmetric Transfer Hydrogenation of Heterocyclic Diaryl Ketones:Facile Access to Key Intermediate of Baloxavir
《Chinese Journal of Chemistry》2024年第1期43-47,共5页Li Wang Renwei Xiao Jingyuan Song Long-Sheng Zheng Qiwei Lang Gen-Qiang Chen Xumu Zhang 
the Southern University of Science and Technology(start-up fund),Shenzhen Science and Technology Innovation Committee(No.KQTD20150717103157174);Stable Support Plan Program of Shenzhen Natural Science Fund(Program Contract No.20200925161222002);Key-Area Research and DevelopmentPt rogramofGuangdong Province((No.2020B010188001);Innovative Team of Universities in Guangdong Province(No.2020KCXTD016);National Natural Science Foundation of China(No.21991113);the National Natural Science Foundation of China(No.22171129);Shenzhen Science and Technology Innovation Committee(JCYJ20210324104202007)for financial support.
Transition metal-catalyzed asymmetric transfer hydrogenation has been proven to be a powerful approach for the synthesis of chiral alcohols.Herein,a highly efficient and enantioselective transfer hydrogenation of dibe...
关键词:Asymmetric transfer hydrogenation Baloxavir Chiral alcohol ENANTIOSELECTIVITY Heterocyclic diaryl ketone Rhodium(Ⅱ) 
A New Polynitrogen-Heterocyclic Scaffold 2,4,6,8-Tetraazanoradamantane Skeleton:Synthesis and Conversion of Its Functionalities
《Chinese Journal of Chemistry》2023年第7期783-789,共7页ongbin Cai Bing Li Tianjiao Hou Qi Zhou Yunzhi Liu Huan Li Yuan Gao Longyi Zhu Jun Luo 
financial support from the National Natural Science Foundation of China(22075144);the Natural ScienceFoundationof Jiangsu Province(BK20200459).
Comprehensive Summary 2,4,6,8-Tetraazanoradamantane skeleton is a unique rigid cage-like organic structure that has not been established.In this article,a facile protocol to build all-bridge-position-functionalized 2,...
关键词:Cage compounds Tetraazanoradamantane Multicomponent reactions Nitrogen heterocycles CONDENSATION 
Phosphorescent Zwitterionic Pt(Ⅱ) N-Heterocyclic Allenylidene Complexes: IVletallophilicity and Ionic Self-Assembly被引量:1
《Chinese Journal of Chemistry》2021年第5期1159-1167,共9页Qin Gao Fei Peng Chuanfei Wang Jinqiang Lin Xiaoyong Chang Chao Zou Wei Lu 
the National Natural Science Foundation of China(Nos.21873044 and 21901109);Science and Technology Innovation Commission of Shenzhen Municipality(No.JCYJ 20170817104715174);the Guangdong Major Project of Basic and Applied Basic Research(No.2019B030302009).
Three zwitterionic and one cationic N-heterocyclic allenylidene(NHA)platinum(Ⅱ)complexes were prepared and characterized via NMR,HR-MS;and FT-IR,etc.Single crystal structure analyses revealed the various intermolecul...
关键词:Luminescence PLATINUM N-Heterocyclic ALLENYLIDENE Noncovalent interactions Polymorphism 
Synthesis of N-Heterocyclic Carbine Silver(Ⅰ)and Palladium(Ⅱ)Complexes with Acylated Piperazine Linker and Catalytic Activity in Three Types of C-C Coupling Reactions
《Chinese Journal of Chemistry》2021年第3期605-613,共9页Qingxiang Liu Xiantao Zhang Zhixiang Zhao Xinying Li Wei Zhang 
the Tianjin Natural Science Foundation(No.18JCZDJC99600);the National Natural Science Foundation of China(No.21572159);the Program for Innovative Research Team in University of Tianjin(TD13-5074).
Main observation and conclusion Two bis-imidazolium salts LH_(2)·Cl_(2) and LH_(2)·(PF_(6))_(2) with acylated piperazine linker and two N-heterocyclic carbene(NHC)silver(Ⅰ)and palladium(Ⅱ)complexes[L_(2)Ag_(2)](PF...
关键词:SILVER PALLADIUM N-Heterocyclic carbine Catalytic actity C-C coupling reaction 
N-Heterocyclic Carbene Organocatalysis: Activation Modes and Typical Reactive Intermediates被引量:7
《Chinese Journal of Chemistry》2020年第10期1167-1202,共36页Xingkuan Chen Hongling Wang Zhichao Jin Yonggui Robin Chi 
We acknowledge finantlal suppart by the Natlorial Nalural Science Foundation of China(No.21772029);the National Key Technologies R&D Program(No.2014BAD23B01);The 10 Talent Plan(Shicengci)of Guizhou Province([2016]5649);the Natural Science Foundation of Guizhou Province([2018]2802);the Gui-zhou Province First-Class Disciplines Project(GNYL(2017)008);Jinan University(Guangzhou),Guizhou University of Traditional Chinese Medicine(China)and Guizhou University(China)。
N-Heterocyclic carbene(NHC)organocatalysis has been developed as an important approach in modern organic synthesis.Versatile activation modes within NHC organocatalysis have been established with countless transformat...
关键词:synthesis. CATALYSIS HETEROCYCLIC 
Recent Advances in the Catalytic Functionalization of “Electrophilic” Indoles被引量:9
《Chinese Journal of Chemistry》2020年第3期287-294,共8页Alessandro Cerveri Marco Bandini 
When "dark"is bright:the scarcely explored electrophilic profile of the indolyl core(dark side)continues to inspire developments in organic synthesis by means of new catalytic methodologies.Recent advancements in the ...
关键词:chemistry. CATALYTIC HETEROCYCLIC 
Heterocyclic Carbene-Catalyzed Hydride Transfer in the Hydroboration of Carbonyl Compounds被引量:1
《Chinese Journal of Chemistry》2019年第7期679-683,共5页Tianhao Li Jianying Zhang Chunming Cui 
This work was supported by the National Natural Science Foundation of China (Nos. 21632006 and 21472098).
N-Heterocyclic carbene (NHC) enabled the highly efficient catalytic hydroboration of a wide range of ketones and aldehydes under mild conditions,and a new mechanism of catalytic hydroboration reaction which involves d...
关键词:HYDRIDE Transfer CARBONYL Compounds 
Asymmetric Synthesis of Chiral Trifluoromethyl Containing Heterocyclic Amino Acids被引量:2
《Chinese Journal of Chemistry》2017年第10期1540-1548,共9页Liang Zhao Shengbin Zhou Junhua Tong Jiang Wang Hong Liu 
An operationally convenient, asymmetric synthesis of cbiral trifluoromethyl containing heterocyclic amino ac- ids has been developed via Michael addition reaction of chiral equivalent of Ni(II)-complex of glycine an...
关键词:trifluoromethyl containing heterocyclic amino acids Ni(II)-complex of glycine asymmetric Michaeladdition α β-unsaturated ketones 
Chemoselective Synthesis of Novel Heterocyclic [3.3.3]Pro- pellane Derivatives via a One-pot Three-component Reaction被引量:1
《Chinese Journal of Chemistry》2017年第9期1463-1468,共6页Jing Wang Hongzhi Liu Ren Wen Jie Li Songlei Zhu 
A highly chemoselective method for the synthesis of heterocyclic [3.3.3]propellane derivatives was developed via sequential three-component reactions of acenaphthenequinone, malononitrile/cyanoacetate and a variety of...
关键词:ACENAPHTHENEQUINONE oxa-aza[3.3.3]propellane CHEMOSELECTIVITY multi-component reaction 
Direct Double Electrophilic Fluorination of Allenoic Acids and Tosylamides to Give 1,1-Difluoroallylic Heterocyclic Compounds被引量:1
《Chinese Journal of Chemistry》2011年第12期2744-2748,共5页崔海峰 柴卓 陆颖鹏 李鹏 赵刚 朱士正 
Project supported by the National Natural Science Foundation of China (Nos. 21032006, 20172064), and the QT Program, Shanghai Natural Science Council.
A novel and facile preparation of l,l-difluoroallyl substituted five-membered lactones or pyrrolidines in mod- erate yields through direct double electrophilic fluorination of 4,5-allenoic acids or tosylamides with Se...
关键词:SELECTFLUOR electrophilic fluorination 4 5-allenoic acid 4 5-allenoic tosylamide allyl difluoride 
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