the Southern University of Science and Technology(start-up fund),Shenzhen Science and Technology Innovation Committee(No.KQTD20150717103157174);Stable Support Plan Program of Shenzhen Natural Science Fund(Program Contract No.20200925161222002);Key-Area Research and DevelopmentPt rogramofGuangdong Province((No.2020B010188001);Innovative Team of Universities in Guangdong Province(No.2020KCXTD016);National Natural Science Foundation of China(No.21991113);the National Natural Science Foundation of China(No.22171129);Shenzhen Science and Technology Innovation Committee(JCYJ20210324104202007)for financial support.
Transition metal-catalyzed asymmetric transfer hydrogenation has been proven to be a powerful approach for the synthesis of chiral alcohols.Herein,a highly efficient and enantioselective transfer hydrogenation of dibe...
financial support from the National Natural Science Foundation of China(22075144);the Natural ScienceFoundationof Jiangsu Province(BK20200459).
Comprehensive Summary 2,4,6,8-Tetraazanoradamantane skeleton is a unique rigid cage-like organic structure that has not been established.In this article,a facile protocol to build all-bridge-position-functionalized 2,...
the National Natural Science Foundation of China(Nos.21873044 and 21901109);Science and Technology Innovation Commission of Shenzhen Municipality(No.JCYJ 20170817104715174);the Guangdong Major Project of Basic and Applied Basic Research(No.2019B030302009).
Three zwitterionic and one cationic N-heterocyclic allenylidene(NHA)platinum(Ⅱ)complexes were prepared and characterized via NMR,HR-MS;and FT-IR,etc.Single crystal structure analyses revealed the various intermolecul...
the Tianjin Natural Science Foundation(No.18JCZDJC99600);the National Natural Science Foundation of China(No.21572159);the Program for Innovative Research Team in University of Tianjin(TD13-5074).
Main observation and conclusion Two bis-imidazolium salts LH_(2)·Cl_(2) and LH_(2)·(PF_(6))_(2) with acylated piperazine linker and two N-heterocyclic carbene(NHC)silver(Ⅰ)and palladium(Ⅱ)complexes[L_(2)Ag_(2)](PF...
We acknowledge finantlal suppart by the Natlorial Nalural Science Foundation of China(No.21772029);the National Key Technologies R&D Program(No.2014BAD23B01);The 10 Talent Plan(Shicengci)of Guizhou Province([2016]5649);the Natural Science Foundation of Guizhou Province([2018]2802);the Gui-zhou Province First-Class Disciplines Project(GNYL(2017)008);Jinan University(Guangzhou),Guizhou University of Traditional Chinese Medicine(China)and Guizhou University(China)。
N-Heterocyclic carbene(NHC)organocatalysis has been developed as an important approach in modern organic synthesis.Versatile activation modes within NHC organocatalysis have been established with countless transformat...
When "dark"is bright:the scarcely explored electrophilic profile of the indolyl core(dark side)continues to inspire developments in organic synthesis by means of new catalytic methodologies.Recent advancements in the ...
This work was supported by the National Natural Science Foundation of China (Nos. 21632006 and 21472098).
N-Heterocyclic carbene (NHC) enabled the highly efficient catalytic hydroboration of a wide range of ketones and aldehydes under mild conditions,and a new mechanism of catalytic hydroboration reaction which involves d...
An operationally convenient, asymmetric synthesis of cbiral trifluoromethyl containing heterocyclic amino ac- ids has been developed via Michael addition reaction of chiral equivalent of Ni(II)-complex of glycine an...
A highly chemoselective method for the synthesis of heterocyclic [3.3.3]propellane derivatives was developed via sequential three-component reactions of acenaphthenequinone, malononitrile/cyanoacetate and a variety of...
Project supported by the National Natural Science Foundation of China (Nos. 21032006, 20172064), and the QT Program, Shanghai Natural Science Council.
A novel and facile preparation of l,l-difluoroallyl substituted five-membered lactones or pyrrolidines in mod- erate yields through direct double electrophilic fluorination of 4,5-allenoic acids or tosylamides with Se...