Supported by the National Natural Science Foundation of China (21701120);the Science and Technology Innovation Project of Colleges and Universities in Shanxi Province (2020L0334);the Innovation and Entrepreneurship Training Program for College Students in Shanxi Province(20240778)。
The ruthenium multi-substituted polyoxotungstate,K_(7)[Si W_(9)O_(37)Ru_(4)(H_(2)O)_(3)Cl_(3)]·15H_(2)O(S1),was synthesized by a conventional aqueous solution containing the trilacunary Keggin-anionsβ-Na_(9)HSi W_(9...
Supported by theNNSFC(No.51108122);Open Project of State Key Laboratory of Urban Water Resource and Environment,Harbin Institute of Technology(No.QA201025);Fundamental Research Funds for the Central Universities(No.HIT.NSRIF.2010053);Science and Technology Innovation Talents Special Foundation of Harbin(2010RFQXG035 and 2007RFXXG018)
A new sandwiched polyoxometalate [HK11Cd4Cl2(PW9034)2]·18H2O (1), incor- porating a unique hybrid tetranuclear cadmium cluster (abbreviated to {Cd4}) with two trivacant polyanions [B-α-PW9O34]9-, has been hydr...
supported by the national natural science foundation of China (No 20771034);Henan Innovation Project for University Prominent Research Talents;the Natural Science Foundation of Henan Province (No 0524480020)
A new sandwich transition metal substituted polyoxotungstate, [NH3(CH2)4NH3]6[Co4(H2O)2(B-α-GeW9O34)2]}·7H2O 1, was hydrothermaUy synthesized and characterized by IR spectra and single-crystal X-ray diffractio...
Supported by the National Natural Science Foundation of China(No.39970 82 4 )
The effect of the functionallization of POMs on their properties was examined by the comparison between both titanium and its corresponding cyclopentadienyl subsituted polyoxocomplexes. The polarographic half wave po...