supported by the National Natural Science Foundation of China(nos.21925108 and 21901203);the Key Science and Technology Innovation Team of Shaanxi(no.2017KCT-37);the Key Laboratory Project of Xi’an(no.201805058ZD9CG42);the Education Department of Shaanxi Province(nos.18JS108 and 20JK0934).
An enantioselective[4+1]spiroannulation ofαbromo-β-naphthols with azoalkenes has been developed for the one-step construction of a new class of pyrazoline-based spirocyclic molecules.Using chiral Cu(II)/Box catalyst...
supported by the National Natural Science Foundation of China(21525729,21590811,21521062,2177168);the "Strategic Priority Research Program" of the Chinese Academy of Sciences(XDA09030200);the "CAS Interdisciplinary Innovation Team Program"~~
The consecutive two‐photon photocatalytic behavior of perylene diimide(PDI)enables it to catalyze photoreduction reactions that are thermodynamically unfavorable via single‐photon processes.In this work,we developed...
The experiments of two-stage pyrolysis and catalytic reforming of high impact polystyrene (HIPS) containing brominated flame retardants and antimony trioxide (Sb2O3) were conducted in the presence of four zeolite cata...
supported by the National Natural Science Foundation of China(21107073,20920102034,21137004);the Natural Science Foundation of Zhejiang Province(Y5110347)
The graphitic carbon nitride(g-C3N4) is found to be an efficient photocatalyst for the reductive degradation of decabromodiphenyl ether(BDE209) under UV irradiation(>360 nm).g-C3N4 was prepared by heating dicyandiamid...
Supported by the National Natural Science Foundation of China(No.2 0 372 0 2 4 ;2 0 172 0 18) ;the Excellent ScientistFoundation of Anhui Province;China(No.2 0 0 10 4 0 ) ;the Natural Science Foundation of the Educational Departm entof AnhuiProvince
Carbon-carbon double bond functional groups are often protected through a popular bromination/debromination method because of their reactivity. An ultrasonic-enhanced stereoselective debromination of vic-dibromides wi...
Project supported by the National Natural Science Foundation of China (Nos. 20372024 and 20172018); the Excellent Scientist Foundation of AnhuiProvince (No. 2001040); the Natural Science Foundation of the Education Department of Anhui Province (No. 2
A novel debromination of vic-dibromides to alkenes with InCl3(cat.)/Sm system in aqueous media has been de- veloped. The reaction gives the E-isomers with excellent yields.
Project supported by the National Natural Science Foundation of China(No.29872010);the Natural Science Foundation of Zhejiang Province(No.298067)
The ? ?vicinal dibromo carboxylic acid and its derivatives were debrominated with Sm/HOAc system to afford the corresponding cinnamic acid and its derivatives in good yields under mild conditions.
Reductive debromination of anhydro-6-(R)-hydroxycthyl-6-(R) 7 by zinc in ammonium acetate gave 9 in 81% yield with high stcreosclectivity of 6-(α):6-(β)= 13: 1
The active intermediate'carbon radical' was detected by the spin—trapping reagent (POBN) during the debromination of Ph_2CHBr in the presence of viologen derivatives as electron—transfer catalysts(ETC).