support from the Natural Science Foundation of Henan Province(grant no.212300410152);the Key Scientific and Technological Project of Henan Province(grant no.212102110439);Henan University of Animal Husbandry and Economy(grant no.2019HNUAHEDF011 and XKYCXJJ2020006);the Key Scientific Research Project for Colleges and Universities of Henan Province(grant no.22B150005)。
A novel and efficient[3+2]annulation of 2-substituted aziridines and N-tosyl cyanamides via a dominoregioselective ring-opening/5-exo-dig cyclization procedure has been developed,allowing the directpreparation of N_(2...
the National Natural Science Foundation of China (Nos. 21625205 and 21332003);the National Program for Support of Top-Notch Young Professionals for financial support
Chiral organobases occupy a significant position in asymmetric organocatalysis. The general types of chiral organobases include tertiary amines, amidines, guanidines, cyclopropenimines, and iminophosphoranes, etc. The...
Nucleophilic addition of primary aromatic amines to carbodiimides in the presence of catalytic amount of the mono-indenyl-ligated rare earth metal bis(silylamide) complexes (C9H6CMe2CHzCsH4N-a)Ln[N(SiHMe2)2]2 at...
supported by the National Natural Science Foundation of China (20972107,20872106);the Department of National Education PhD Foundation;the Priority Academic Program Development of Jiangsu Higher Education Institutions
A catalytic addition of amine N H bonds to carbodiimides using aluminum chloride as a Lewis acid catalyst is developed.The reaction proceeds under mild conditions without solvent to afford a series of substituted guan...