ENOL

作品数:54被引量:86H指数:6
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相关领域:理学更多>>
相关作者:刘刚齐曼冯卫生翟俊宜林元华更多>>
相关机构:吉林农业大学清华大学河南中医药大学中国农业科学院更多>>
相关期刊:《Chinese Journal of Structural Chemistry》《Science Bulletin》《南开大学学报(自然科学版)》《Journal of Biomaterials and Nanobiotechnology》更多>>
相关基金:国家自然科学基金国家重点基础研究发展计划国家教育部博士点基金高等学校学科创新引智计划更多>>
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Facile Blinking Dyes with Spontaneous Enol-Keto Tautomerism for Super-Resolution Imaging of Subcellular Targets
《CCS Chemistry》2024年第11期2770-2782,共13页Ji Gao Weijun Wu Lulu Zhou Shaokuan Gong Chong Li Xihan Chen Yiming Li Kai Li 
supported by the Ministry of Science and Technology of China(grant no.2020YFA0908900);the National Natural Science Foundation of China(grant no.U21A2097);Key Technology Research and Development Program of Shandong(grant no.2021CXGC010212);Guangdong Provincial Key Laboratory of Advanced Biomaterials(grant no.2022B1212010003);Guangdong Natural Science Foundation Joint Fund(grant no.2020A1515110380);the Shenzhen Science and Technology Program(grant nos.KQTD20200820113012029 and JCYJ20220818100416036);the start-up fund provided by SUSTech for financial support;The authors acknowledge the Center for Computational Science and Engineering at SUSTech for theoretical calculation support,and SUSTech Core Research Facilities for technical support.
Fluorophores with controlled on–off switching properties and subcellular targeting abilities are essential for modern super-resolution microscopy techniques.However,the effective design strategies of blinking fluorop...
关键词:spontaneous enol-keto tautomerism fluorophore proton transfer fluorescence imaging subcellular target 
A New Approach to the Synthesis of Bergapten
《Chemical Research in Chinese Universities》2022年第6期1492-1496,共5页CAI Xiaoqing JI Dongxin LIU Jiageng HU Maolin JIN Zhimin 
supported by the Project of Department of Science and Technology of Zhejiang Province, China (No.2021C04021).
In this study, bergapten was synthesized in a yield of 55% from phloroglucinol as starting material, via a novel approach including monomethylation, Hoesch reaction, acetylation, deacetoxylation, Pechmann condensation...
关键词:BERGAPTEN Enol tautomerism Acetylation Deacetoxylation 2 3-Dichloro-5 6-dicyano-1 4-benzoquinone (DDQ)dehydrogenation 
Synthesis of 4-Desmethyl-Rippertenol and 7-Epi-Rippertenol via Photoinduced Cyclization of Dienones
《CCS Chemistry》2021年第9期2074-2083,共10页Zi-Chun Zhang Dan-Dan Zhao Zhong-Chao Zhang Xin-Yu Tan Jian-Xian Gong Jun-Kai Fu Zhen Yang 
supported by the National Key Research and Development Program of China(grant no.2018YFC0310905);the National Science Foundation of China(grant nos.21632002,21871012,and 21801123);the Shenzhen Basic Research Program(grant nos.JCYJ20180302180215524 and JCYJ20170818091450164).
The synthesis of cycloheptanoid-based fused polycyclic frameworks is a challenge for organic chemists due to unfavorable entropic factors and ring strains.Herein,a concise synthesis of 4-desmethyl-rippertenol and 7-ep...
关键词:seven-memberedring photoinduced cycli-zation DIENONE rippertenol 1 5-hydrogenmigration 
Effect of Phenolation, Lignin-Type and Degree of Substitution on the Properties of Lignin-Modified Phenol-Formaldehyde Impregnation Resins: Molecular Weight Distribution, Wetting Behavior, Rheological Properties and Thermal Curing Profiles被引量:5
《Journal of Renewable Materials》2020年第6期603-630,共28页Marion Thébault Larysa Kutuzova Sandra Jury Iris Eicher Edith-Martha Zikulnig-Rusch Andreas Kandelbauer 
Here,the effects of substituting portions of fossil-based phenol in phenol formaldehyde resin by renewable lignin from two different sources are investigated using a factorial screening experimental design.Among the r...
关键词:LIGNIN lignin-phenol-formaldehyde resin(PF) surface energy viscosity thermal characterization design of experiments 
Selective O-difluoromethylation of 1,3-diones using S-(difluoromethyl) sulfonium salt被引量:2
《Chinese Chemical Letters》2019年第8期1515-1518,共4页Guo-Kai Liu Xin Li Wen-Bing Qin Wei-Feng Lin Li-Ting Lin Jia-Yi Chen Jian-Jian Liu 
supported by the Science and Technology Foundation of Shenzhen, Shenzhen Science and Technology Innovation Committee (No. JCYJ20170818143001461)
A facile and highly efficient approach for selective O-difluoromethylation of 1,3-diones by recently developed bench-stable S-(difluoromethyl)sulfonium salt was described.And a broad range of difluoromthyl enol ethers...
关键词:DIFLUOROCARBENE Difluoromethyl ENOL ethers 1 3-Diones O-Difluoromethylation S-(Difluoromethy)sulfonium salt 
Enantioselective Conjugate Addition-Protonation of 5H-Oxazol-4-ones and 5-Methylene 1,3-Oxazolidine-2,4-diones: 2,2'-Biphenol-lnduced Diastereoselectivity Switch
《Chinese Journal of Chemistry》2019年第7期689-694,共6页Bohua Lu Shuang Xin BO Zhu Junbiao Chang 
This work was supported by the National Natural Science Foundation of China (U1804283);the National Postdoctoral Pro-gram for Innovative Talents (No. BX201700071);a project funded by the China Postdoctoral Science Foundation (No. 2017M622348);the 111 project (D17007).
A synthetic strategy for catalytic asymmetric conjugate addition-protonation and diastereoselective switch between 5H-oxazol-4-ones and 5-methylene 1,3-oxazolidine-2,4-diones was established.An array of chiral conjuga...
关键词:Conjugate Addition DIASTEREOSELECTIVITY 
Synthesis,Structure and Characterization of a 3D Chiral Carboxylate and Phosphonate Metalorganic Framework Based on 1,1?-Biphenol Ligand被引量:2
《Chinese Journal of Structural Chemistry》2018年第9期1509-1515,共7页焦静静 李子建 郑发鲲 刘百战 崔勇 
Supported by NSFC(No.21431004,21522104 and 21620102001);“973”Program(No.2014CB932102 and 2016YFA0203400);the Shanghai“Eastern Scholar”Program SSTC-14YF1401300;the Key Project of Basic Research of Shanghai(17JC1403100)
A novel phosphonate-based chiral metal-organic framework 1 was synthesized from C2-symmetric 1,1?-biphenol-based ligand and structurally characterized by single-crystal and powder X-ray diffraction, Fourier-transform...
关键词:BIPHENOL PHOSPHONATE manganese chiral metal-organic framework photoluminescence 
Total Synthesis of Marine Cyclic Enol-Phosphotriester Salinipostin Compounds
《Journal of Ocean University of China》2018年第3期683-689,共7页ZHAO Mingliang WEI Xianfeng LIU Xuemeng DONG Xueyang YU Rilei WAN Shengbiao JIANG Tao 
supported by the National Natural Science Foundation of China (No. 81373322);the Innovation Project from Qingdao National Laboratory for Marine Science and Technology (No. 2015ASKJ02);the Taishan Scholar Project Fund of Shandong Province
Due to their structural diversity and variety of biological activities, marine natural products have been the subject of extensive study. These compounds, especially phospholipid polycyclic aromatic hydrocarbons, have...
关键词:total synthesis Salinipostin enolphosphate trimester 
Synthesis,Structure and Characterization of a 3D Chiral Indium Carboxylate Metal-organic Framework Based on 1,1'-Biphenol Ligand被引量:1
《Chinese Journal of Structural Chemistry》2017年第12期2081-2086,共6页MENG Chun-Long  LI Zi-Jian LIU Yan LIU Bai-Zhan CUI Yong 
Supported by the NNSFC(No.21371119,21431004,21401128,21522104,and 21620102001);the National Key Basic Research Program of China(Nos.2014CB932102 and 2016YFA0203400);the Shanghai“Eastern Scholar”Program SSTC-14YF1401300
A novel indium-based chiral metal organic-framework 1 {In2L(μ2-O)(H2O)3}n was synthesized from C2-symmetric 1,1?-biphenol-based ligand H4 L and structurally characterized by single-crystal and powder X-ray diffr...
关键词:1 1?-biphenol INDIUM chiral metal-organic framework photoluminescence 
Substituent, Temperature and Solvent Effects on the Keto-Enol EQUILIBRIUM in <i>β</i>-Ketoamides: A Nuclear Magnetic Resonance Study
《Open Journal of Physical Chemistry》2013年第4期138-149,共12页Sergio L. Laurella Manuel González Sierra Jorge J. P. Furlong Patricia E. Allegretti 
Substituent, temperature and solvent effects on tautomeric equilibria in several β-ketoamides have been investigated by means of nuclear magnetic resonance spectroscopy (NMR). Keto-enol equilibrium predominates over ...
关键词:β-Ketoamides Keto-Enol EQUILIBRIUM Nuclear Magnetic Resonance Spectroscopy 
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