supported by the Ministry of Science and Technology of China(grant no.2020YFA0908900);the National Natural Science Foundation of China(grant no.U21A2097);Key Technology Research and Development Program of Shandong(grant no.2021CXGC010212);Guangdong Provincial Key Laboratory of Advanced Biomaterials(grant no.2022B1212010003);Guangdong Natural Science Foundation Joint Fund(grant no.2020A1515110380);the Shenzhen Science and Technology Program(grant nos.KQTD20200820113012029 and JCYJ20220818100416036);the start-up fund provided by SUSTech for financial support;The authors acknowledge the Center for Computational Science and Engineering at SUSTech for theoretical calculation support,and SUSTech Core Research Facilities for technical support.
Fluorophores with controlled on–off switching properties and subcellular targeting abilities are essential for modern super-resolution microscopy techniques.However,the effective design strategies of blinking fluorop...
supported by the Project of Department of Science and Technology of Zhejiang Province, China (No.2021C04021).
In this study, bergapten was synthesized in a yield of 55% from phloroglucinol as starting material, via a novel approach including monomethylation, Hoesch reaction, acetylation, deacetoxylation, Pechmann condensation...
supported by the National Key Research and Development Program of China(grant no.2018YFC0310905);the National Science Foundation of China(grant nos.21632002,21871012,and 21801123);the Shenzhen Basic Research Program(grant nos.JCYJ20180302180215524 and JCYJ20170818091450164).
The synthesis of cycloheptanoid-based fused polycyclic frameworks is a challenge for organic chemists due to unfavorable entropic factors and ring strains.Herein,a concise synthesis of 4-desmethyl-rippertenol and 7-ep...
Here,the effects of substituting portions of fossil-based phenol in phenol formaldehyde resin by renewable lignin from two different sources are investigated using a factorial screening experimental design.Among the r...
supported by the Science and Technology Foundation of Shenzhen, Shenzhen Science and Technology Innovation Committee (No. JCYJ20170818143001461)
A facile and highly efficient approach for selective O-difluoromethylation of 1,3-diones by recently developed bench-stable S-(difluoromethyl)sulfonium salt was described.And a broad range of difluoromthyl enol ethers...
This work was supported by the National Natural Science Foundation of China (U1804283);the National Postdoctoral Pro-gram for Innovative Talents (No. BX201700071);a project funded by the China Postdoctoral Science Foundation (No. 2017M622348);the 111 project (D17007).
A synthetic strategy for catalytic asymmetric conjugate addition-protonation and diastereoselective switch between 5H-oxazol-4-ones and 5-methylene 1,3-oxazolidine-2,4-diones was established.An array of chiral conjuga...
Supported by NSFC(No.21431004,21522104 and 21620102001);“973”Program(No.2014CB932102 and 2016YFA0203400);the Shanghai“Eastern Scholar”Program SSTC-14YF1401300;the Key Project of Basic Research of Shanghai(17JC1403100)
A novel phosphonate-based chiral metal-organic framework 1 was synthesized from C2-symmetric 1,1?-biphenol-based ligand and structurally characterized by single-crystal and powder X-ray diffraction, Fourier-transform...
supported by the National Natural Science Foundation of China (No. 81373322);the Innovation Project from Qingdao National Laboratory for Marine Science and Technology (No. 2015ASKJ02);the Taishan Scholar Project Fund of Shandong Province
Due to their structural diversity and variety of biological activities, marine natural products have been the subject of extensive study. These compounds, especially phospholipid polycyclic aromatic hydrocarbons, have...
Supported by the NNSFC(No.21371119,21431004,21401128,21522104,and 21620102001);the National Key Basic Research Program of China(Nos.2014CB932102 and 2016YFA0203400);the Shanghai“Eastern Scholar”Program SSTC-14YF1401300
A novel indium-based chiral metal organic-framework 1 {In2L(μ2-O)(H2O)3}n was synthesized from C2-symmetric 1,1?-biphenol-based ligand H4 L and structurally characterized by single-crystal and powder X-ray diffr...
Substituent, temperature and solvent effects on tautomeric equilibria in several β-ketoamides have been investigated by means of nuclear magnetic resonance spectroscopy (NMR). Keto-enol equilibrium predominates over ...