FLUOROALKYL

作品数：26被引量：13H指数：2
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相关领域：理学更多>>
相关作者：宋适更多>>
相关机构：上海大学上海交通大学南京理工大学更多>>
相关期刊：《Emerging Contaminants》《Science China Chemistry》《Open Journal of Composite Materials》《Eco-Environment & Health》更多>>
相关基金：国家自然科学基金更多>>
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Modular three-component radical fluoroalkyl-sulfuration of unactivated alkenes
《Chinese Journal of Catalysis》2025年第2期249-258,共10页Gao-feng Yang Zhi Liu Kai Liu Xiaopeng Wu Chengjian Zhu Weipeng Li Jin Xie 
国家重点研发项目(2022YFA1503200,2021YFC2101901);国家自然科学基金(22122103,22101130,22001117,22271144);中央高校基本科研业务费(020514380304,020514380252,020514380272).
The accompanied forge of C(sp^(3))–S and C(sp^(3))–C(sp^(3))bonds across alkene frameworks serves as a potent strategy to construct biologically important compounds.Here,we report a metal-free,photochemically mediat...
关键词：C(sp^(3))-S bond Unactivated alkenes Photoredox catalysis FLUOROALKYLATION Unsymmetrical thioethers 
Diastereoselective Construction of α-Fluoroalkyl Cycloalkanols via Radical Alkylation of α-Fluoroalkyl Ketones
《Chinese Journal of Chemistry》2023年第23期3275-3280,共6页Yi Liu Ji Li Yulu Zhou Hanliang Zheng Zhenlu Shen Gangguo Zhu 
supported by the National Natural Science Foundation of China(22071218 and 22203076);the Natural Science Foundation of Zhejiang Province(LZ20B020001 and LY23B020004);the Ten Thousand Talents Plan of Zhejiang Province(2020R52021);the Leading Innovative and Entrepreneur Team Introduction Program of Zhejiang Province(2022R01007);Key Laboratory of Green Pesticides and Cleaner Production Technology of Zhejiang Province.
α-Fluoroalkyl (Rf) alcohols are privileged motifs in drugs and pharmaceutically active compounds.As such,it is highly desirable to develop efficient methods for assembling these scaffolds.Herein,a visible-light-induc...
关键词：Radical reactions CYCLIZATION ALKYLATION α-Fluoroalkyl ketones Fluorine effect ALCOHOLS 
Emerging contaminants in biosolids:Presence,fate and analytical techniques
《Emerging Contaminants》2022年第1期162-194,共33页Ravinder Kumar Arun K.Vuppaladadiyam Elsa Antunes Anna Whelan Rob Fearon Madoc Sheehan Louise Reeves 
Emerging contaminants(ECs)represent a small fraction of the large chemical pollution puzzle where a wide variety of potentially hazardous chemicals reach the environment,and new compounds are continuously synthesized ...
关键词：BIOSOLIDS Endocrine-disrupting chemicals Emerging contaminants Flame retardants Microplastics Per-and poly-fluoroalkyl substances Pharmaceutical and personal care products 
Recent advances in the synthesis of fluoroalkylated compounds using fluoroalkyl anhydrides
《Chinese Chemical Letters》2022年第10期4517-4530,共14页Wei Wu Yi You Zhiqiang Weng 
supported by the National Natural Science Foundation of China(Nos.21772022,and 22171124);Minjiang University(No.MJY21041);Fuzhou University.
Fluoroalkyl-containing organic compounds have exhibited wide applications in the field of pharmaceuticals,agrochemicals and materials science due to their outstanding properties such as biological activity,metabolic s...
关键词：Trifluoroacetic anhydride(TFAA) Fluoroalkyl anhydride Fluoroalkyl-containing organic compound Fluoroalkl Fluoroalkanoyl Cyclization reaction Coupling reaction 
Next generation per-and poly-fluoroalkyl substances:Status and trends,aquatic toxicity,and risk assessment被引量：4
《Eco-Environment & Health》2022年第2期117-131,共15页Hannah Mahoney Yuwei Xie Markus Brinkmann John P.Giesy 
was supported by a Discovery Grant(Project#326415-07)from the Natural Sciences and Engineering Research Council of Canada.Prof;Giesy was supported by the Canada Research Chair Program,and a Distinguished Visiting Professorship in the Department of Environmental Sciences,Baylor University in Waco,TX,USA.Prof.;Brinkmann is currently a faculty member of the Global Water Futures(GWF)program,which was funded in part with financial support from the Canada First Research Excellence Funds(CFREF).
Widespread application of poly-and per-fluoroalkyl substances(PFAS)has resulted in some substances being ubiquitous in environmental matrices.That and their resistance to degradation have allowed them to accumulate in...
关键词：PFAS Replacement PFAS Emerging contaminants Aquatic toxicity Chemical scoring 
Intermolecular Radical Fluoroalkylative Olefination of Unactivated Alkenes
《CCS Chemistry》2022年第4期1190-1198,共9页Jiajia Yu Huihui Zhang Xinxin Wu Chen Zhu 
the financial support from the National Natural Science Foundation of China(grant no.21971173);the Project of Scientific and Technologic Infrastructure of Suzhou(grant no.SZS201905);the Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD).
We have disclosed a novel,efficient radicalmediated intermolecular fluoroalkylative olefination of unactivated alkenes.The transformation proceeded through a radical docking-migration cascade,in which a portfolio of s...
关键词：alkene difunctionalization OLEFINATION MIGRATION FLUOROALKYL radical reactions 
Wettability Control between Oleophobic/Superhydrophilic and Superoleophilic/Superhydrophobic Characteristics on the Modified Surface Treated with Fluoroalkyl End-Capped Oligomers/Micro-Sized Polystyrene Particle Composites
《Open Journal of Composite Materials》2022年第1期41-55,共15页Hideo Sawada Koki Arakawa Yuta Aomi 
Fluoroalkyl end-capped vinyltrimethoxysilane-N,N
《Open Journal of Composite Materials》2022年第1期56-71,共16页Hideo Sawada Kako Tono Katsumi Yamashita 
Fluoroalkyl end-capped vinyltrimethoxysilane oligomer
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关键词：Fluorinated Oligomeric Composite Micro-Sized Ottawa Sand Particle Superoleophilic/Superhydrophobic Property Smooth Separation of Oil and Water Selective Removal of Fluorinated Aromatic Compound 
Fluoroalkyl N-sulfonyl hydrazones:An efficient reagent for the synthesis of fluoroalkylated compounds被引量：1
《Science China Chemistry》2021年第10期1614-1629,共16页Paramasivam Sivagur Xihe Bi 
the National Natural Science Foundation of China(21871043,21961130376);Department of Science and Technology of Jilin Province(20180101185JC,20190701012GH,20200801065GH);the Fundamental Research Funds for the Central Universities(2412019ZD001,2412019FZ006)。
Fluoroalkyl N-sulfonyl hydrazones are versatile reagents that can be used to synthesize a wide range of diverse fluoroalkylated organic molecules.Although it has been known since 1975,the chemistry of fluoroalkyl N-su...
关键词：An efficient reagent for the synthesis of fluoroalkylated compounds Fluoroalkyl N-sulfonyl hydrazones 
Screening of textile finishing agents available on the Chinese market: An important source of per-and polyfluoroalkyl substances to the environmentpolyfluoroalkyl substances to the environment被引量：2
《Frontiers of Environmental Science & Engineering》2019年第5期29-38,共10页Mehvish Mumtaz Yixiang Bao Wenchao Li Lingxiao Kong Jun Huang Gang Yu 
Organofluorinated surfactants are widely employed in textile finishing agents (TFAs) to achieve oil, water, and stain repellency. This has been regarded as an important emission source of per-and polyfluoroalkyl subst...
关键词：Textile FINISHING agents Kendrick mass defect Total oxidizable PRECURSOR ASSAY 
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