IMIDAZOLATE

作品数：119被引量：233H指数：7
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相关机构：北京化工大学厦门大学更多>>
相关期刊：《Chinese Journal of Structural Chemistry》《Journal of Energy Chemistry》《Advanced Powder Materials》《Energy & Environmental Materials》更多>>
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Stable copper boron-imidazolate cage as Cu-riched enzyme for highly efficient electrocatalytic CO_(2)reduction to ethylene
《Science China Chemistry》2025年第3期943-950,共8页Jun-Qiang Chen Qiao-Hong Li Qin-Long Hong Ping Shao Hai-Xia Zhang Jian Zhang 
the support from the National Key Research and Development Program of China (2021YFA1501500);the National Natural Science Foundation of China (22275192,92161105);the STS Project of Fujian-CAS (2023T3054)。
Single-atom catalyst has garnered widespread attention to mimic mature enzymes due to its well-defined atomic structure and coordination environments.However,since the carbon-carbon(C-C)coupling reactions require syne...
关键词：metal-organic cages CO_(2)reduction single-metal-site catalyst boron-imidazolate cages 
Atomically precise Pd_(8)nanocluster encapsulated in a hierarchically engineered nanoreactor towards enhanced catalysis
《Nano Research》2025年第3期187-193,共7页Hui Yang Yi-Ming Li Jinhui Hu Dongxia Shi Yongkang Ge Jiwei Feng Hongting Sheng Manzhou Zhu 
financial support by the National Natural Science Foundation of China(Nos.22305003 and 21972001);the China Postdoctoral Science Foundation(No.2023M740009).
Metal-organic frameworks(MOFs)have emerged as superior hosting matrices for atomically precise nanoclusters(NCs)encapsulation,offering excellent physical and chemical protections for advanced catalysis.Nevertheless,th...
关键词：metal nanoclusters metal-organic frameworks zeolitic imidazolate framework-8(ZIF-8) hierarchical pores NANOREACTOR 
A Structural Mimic of Carbonic Anhydrase in Zeolitic Imidazolate Frameworks via Trans-functionalization for Enhancing Hydrolytic Activity
《Research》2025年第1期966-974,共9页Fanchen Meng Cheng Xu Linghai Zhang Xiaohan Huang Xinglong Zhang Wenlei Zhang Yongqi Luo Weina Zhang Wei Huang Fengwei Huo Suoying Zhang 
supported by the National Natural Science Foundation of China(62288102,22305116,21908105,21727808,and 21971114);the Jiangsu Provincial Funds for Natural Science Foundation(BK20230308 and BK20200090).
Metal-organic frameworks(MOFs)have been widely considered as ideal platforms for the preparation of biomimetic catalysts,but it remains challenging to fabricate MOF-based enzyme-like catalysts with optimal activity.He...
关键词：structural transformationthe biomimetic catalystsbut metal organic frameworks structural mimic carbonic anhydrase carbonic anhydrase ca mimic trans functionalization 
A rapid-response smart nanoplatform with dual T_(1)-T_(2) activation for acidic microenvironment imaging
《Science China Materials》2024年第12期4101-4110,共10页Meng Luo Jiajing Guo Yi Zhu Jiali Deng Hongwei Lu Lei Li Zhongling Wang 
supported by the National Natural Science Foundation of China (82272057 and 32301160)。
Acidity-activatable magnetic resonance imaging(MRI)nanoprobes offer great potential for in vivo cancer imaging by targeting the acidic tumor microenvironment(TME).However,their effectiveness is limited by the delayed ...
关键词：rapid response zeolitic imidazolate framework-8 dual T_(1)-T_(2)activation acidic tumor microenvironment 
Facilitating sulfur species capture and bi-directional redox in Li-S batteries with single-atomic Co-O_(2)N_(2) coordination structure
《Journal of Energy Chemistry》2024年第12期604-614,共11页Yunqiang Zhang Huaming Yuan Enyan Guo Shunwei Chen Manman Ren Jingyun Ma Jiaxi Cui Mei Li Laiying Jing Li Li 
supported financially by the National Natural Science Foundation of China(NSFC)(Grant No.22208174 and 52272221);the New Colleges and Universities Twenty Foundational Projects of Jinan City(2021GXRC068);the Universities Youth Innovation Team Development Plan of Shandong Province(2023KJ140);the Natural Science Foundation of Shandong Province(ZR2022MB143);the Basic Research Projects of Science,Education,Industry Integration Pilot Engineering of Qilu University of Technology(Shandong Academy of Sciences)(2023PY002)。
Lithium-sulfur(Li-S)batteries suffer from the shuttle effect of soluble lithium polysulfides(LiPSs)and slow redox kinetics,significantly limiting their practical application.Although single-atom catalysts(SACs)offer a...
关键词：Asymmetrically coordinated Co-O_(2)N_(2) Zeolitic imidazolate framework-67 Melamine resin Carbon nanoflakes Shuttle effect 
Post-synthetic modifications(PSM)-induced defects in hybrid metal-organic frameworks(MOFs)to unleash potential in gas separation membrane applications
《Journal of Materials Science & Technology》2024年第34期95-118,共24页Gyeong Min Choi Manas Mandal Ho Jin Jung Jagannath Panda Young Je Kwon Kaiyun Zhang E.Vivek MinYoung Shon Krishnan Ravi Kyung-Youl Baek Hyuk Taek Kwon Jeong-Gu Yeo Kie Yong Cho 
support through the National Research Foundation of Korea(NRF)grant funded by the Ko-rean government(MSIT)(Nos.NRF-2022R1C1C1003313 and NRF-2020M3H4A3106356);supported by the Technology Innovation Program(No.20010846);funded by the Ministry of Trade,Industry&Energy(MOTIE,Korea);supported by the“Regional Innovation Strategy(RIS)”through the National Research Foundation of Korea(NRF)funded by the Ministry of Education(MOE)(No.2023RIS-007);support through the Korea Environ-ment Industry&Technology Institute,funded by the Korea Ministry。
Metal-organic frameworks(MOFs)are a subclass of porous materials that have gained considerable at-tention recently due to their unique properties and potential applications.However,MOFs may exhibit defects affecting t...
关键词：Metal-organic frameworks Post-synthetic modifications Defect engineering Zeolitic imidazolate frameworks Mixed-matrix membranes Gas separation 
A customized zeolitic imidazolate framework enabling bionic preconcentration of ultralow CO_(2)
《Science China Materials》2024年第10期3401-3407,共7页Hongyang Jin Ziyang Wang Guangli Yu Junchao Dong Shuai Zhao Fengchao Cui Hao Zhang Guolong Lu Xiaoqin Zou Zhiyong Chang 
supported by the National Natural Science Foundation of China(22375031,22131004,U21A20330,U22A20184 and 22208224);National Key R&D Program of China(2022YFB3805902 and 2023YFC2812603);“111”Program(B18012);Jilin Natural Science Fund for Excellent Young Scholars(20230508116RC);Science&Technology Department of Jilin Province(20230101023JC);Fundamental Research Funds for the Central Universities(JGPY202103 and 2412023YQ001);Excellent Youth Lift Plan from Shenyang University of Chemical Technology(2022YQ003)。
Advancing our understanding of global climate,particularly in polar regions,requires accurate detection of carbon dioxide(CO_(2))in ice cores and deep sea environments.However,detecting trace levels of CO_(2)in these ...
关键词：zeolitic imidazolate frameworks selective CO_(2)adsorption gas preconcentration MOF films 
Effects of zeolite imidazole frameworks on rice seedlings (Oryza sativa L.): Phytotoxicity, transformation, and bioaccumulation
《Journal of Environmental Sciences》2024年第10期15-25,共11页Chaofa Chen Yongqi Yao Chenghua Xing Yunyu Guo Luyi Cai Jianfang Yan Xi-Lin Wu Miaozhen Cai 
This work was supported by the National Natural Science Foundation of China(Nos.30800705 and 31101599);the Provincial Natural Science Foundation of Zhejiang(Nos.LY15C150004 and LY18C150007);the Key Research and Devel opment Projects of Social Development of Jinhua Science and Technology Program(No.2021C22750).
Zeolite imidazole frameworks(ZIFs),a class of the metal organic framework,have been extensively studied in environmental applications.However,their environmental fate and potential ecological impact on plants remain u...
关键词：Zeolitic imidazolate frameworks (ZIFs) Rice(Oryza sativa L.) PHYTOTOXICITY Transformed ZIFs ZIFs bioaccumulation 
Bimetallic reduced graphene oxide/zeolitic imidazolate framework hybrid aerogels for efficient heavy metals removal
《Frontiers of Chemical Science and Engineering》2024年第8期49-66,共18页Nurul A.Mazlan Allana Lewis Fraz Saeed Butt Rajakumari Krishnamoorthi Siyu Chen Yi Huang 
funded by Jiangsu Dingying New Materials Co.,Ltd.under Grant Number(C-00005685);the School of Engineering,the University of Edinburgh.N.A.M.acknowledges the Malaysian Government for awarding a Ph.D.scholarship;the use of the Zeiss Crossbeam Cryo FIB/SEM bought with the EPSRC grant EP/P030564/1 and Fraser Laidlaw for help with image acquisition.
Graphene oxide is a promising adsorption material.However,it has been difficult to recycle and separate graphene oxide in the solution.To alleviate this problem,graphene oxide was thermally reduced to produce porous h...
关键词：rGO Co-doped ZIF-8 heavy metals adsorption AEROGEL 
High-precision colorimetric-fluorescent dual-mode biosensor for detecting acetylcholinesterase based on a trimetallic nanozyme for efficient peroxidase-mimicking
《Journal of Materials Science & Technology》2024年第24期168-180,共13页Meie Zheng Mingxing Liu Zichen Song Fei Ma Hongda Zhu Huiling Guo Hongmei Sun 
supported by the Hubei University of Technology Graduate Research Innovation Project(No.2022048);the Natural Science Foundation Project of Hubei Province(grant No.2022CFB533);the Scientific Research Plan of Education Department of Hubei Province(grant No.D20222702);the Natural Science Project of Xiaogan city(grant No.XGKJ20210100014).
Highly sensitive and stable acetylcholinesterase detection is critical for diagnosing and treating various neurotransmission-related diseases.In this study,a novel colorimetric-fluorescent dual-mode biosensor based on...
关键词：Graphitic carbon nitride Zeolitic imidazolate framework-8 Colorimetric-fluorescent dual-mode sensor Density functional theory calculations ACETYLCHOLINESTERASE 
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