the Research Grants Council of the Hong Kong Special Administrative Region,China(PolyU 15302821,15300220,and 25301819);the National Natural Science Foundation of China(21972122)for their financial support.
Comprehensive Summary This paper presents the first general examples of palladium-catalyzed desulfinative cross-coupling reaction of polyhalogenated aryl triflates with aryl sulfinate salts showing an inversion of the...
An iodine-PPh3 mediated sulfenylation of indoles in water with stable and odorless sodium sulfinates as the sulfur source is described. The reaction could afford monosulfenylated indoles in moderate to excellent yield...
Acknowledgement This work was supported by the National Key Research and Development Program of China (2015CB931900, 2016YFB0101200), the National Natural Science Foundation of China (21632009, 21421002, 21472221, 21372246, 21302206), the Key Programs of the Chinese Academy of Sciences (KGZD-EW- TO8), the Key Research Program of Frontier Sciences of CAS (O.YZDJ-SSW-SLH049), Shanghai Science and Technology program (15XD1504400), and Youth Innovation Promotion Association CAS (2014231).
A copper-mediated di- and monoffuoromethanesulfonylation of arenediazonium tetrafluoroborates using di- and monofluoromethanesul- finate reagents provides aryl difluoromethyl (or monofluoromethyl) sulfones in 8ood y...
A new and convenient procedure is developed for the preparation of N-sulfonylbenzotriazoles from sodium sulfinates and benzotriazoles using molecular iodine as catalyst via the S-N bond formation reaction. This cataly...
Supporting intbrmation tbr this article is available on the WWW under http://dx.doi.org/10.1002/cjoc.201200028 or from the author.Acknowledgement This work was supported by the National Natural Science Foundation of China (Nos. 21102105 and 21072153).
A highly practical method to access unsymmetrical and symmetrical thiosulfonates in moderate to excellent yields has been developed through NBS-promoted sulfenylation of sulfinates with disulfides. The present process...
The reaction of 3-nitro-4-chlorobenzenesulfinic acid and ethylene oxide to obtain 2-nitro-4-(β-hydroxyethylsulfonyl)chlorobenzene had been studied. Except hydroxyethylation on the sulfur atom of 3-nitro-4-chloroben...
Objective.To study the change of taurine transport,and taurine transporter(TAUT)and cysteine sulfinate decarboxylase(CSD)mRNA contents in hypertension and hypertensive cardiomegaly.Methods.Taurine content was determin...
Since its introduction in 1997, tert-butanesulfinamide (1) has proven to an extremely versatile chiral ammonia equivalent for the asymmetric synthesis of amines[1]. However, practical methods for the preparation of en...
β-Ketosulfoxides were synthesized by the reaction of acetone with aryl sulfinate esters in the presence of hydrochloric acid and the structure of title compounds were finally confirmed by IR.~1HNMR and ^(13)CNMR spec...