grateful to the National Natural Science Foundation of China(Nos.21961045 and 22061048);the Basic Research Project of Chongqing Academy of Chinese Materia Medica(No.jbky20190028);the Fund Project of Yunnan Key Laboratory of Pharmacology for Natural Products(No.YKLPNP-K2303);Yunnan Provincial Key Laboratory Construction Plan Funding of Universities;Yunnan Provincial Engineering Research Center Construction Plan Funding of Universities for their financial support.
The nitrile compounds are present in a variety of biologically active natural products and pharmaceuticals,and the nitrile groups are versatile synthetic intermediates to other functionalized compounds.Herein,the asym...
supported by the National Natural Science Foundation of China (Nos. 81573269, 21572015, 21877007, 91753202 and 21702007);and the open funding of the State Key Laboratory of Phytochemistry and Plant Resources in West China
Oleanolic acid(OA) and echinocystic acid(EA), two naturally occurring pentacyclic oleanane triterpenes,are gaining increasing attention due to their promising pharmacological activities. Conjugation with amphiphilic ...
Financial support of this study from CNRS is gratefully acknowledged
Diisobutylaluminium hydride (DIBAL-H) promotes secondary rim regioselective bis-de-O-methylation of permethylated β- cyclodextrin (β-CD) to give diol 2. To gain an insight into the mechanism of this remarkable r...
1,7β- Dimethyl-7α- hydroxy-8aα-carboxymethyl-9β-carbomethoxy-4bα, 5, 6, 7, 8, 8α-hexahydrofluorene lactone(2) is converted to 8, 12-epoxyallogibberic acid methyl ester(4) by the action of diisobutyl aluminum hy...