grateful to the National Natural Science Foundation of China(Nos.21961045 and 22061048);the Basic Research Project of Chongqing Academy of Chinese Materia Medica(No.jbky20190028);the Fund Project of Yunnan Key Laboratory of Pharmacology for Natural Products(No.YKLPNP-K2303);Yunnan Provincial Key Laboratory Construction Plan Funding of Universities;Yunnan Provincial Engineering Research Center Construction Plan Funding of Universities for their financial support.
The nitrile compounds are present in a variety of biologically active natural products and pharmaceuticals,and the nitrile groups are versatile synthetic intermediates to other functionalized compounds.Herein,the asym...
Supported by the National Key Research and Development Program of China(2017YFA0700100);the NSFC(21520102001,51572260 and 21571177);Strategic Priority Research Program of the Chinese Academy of Sciences(XDB20000000);Key Research Program of the Chinese Academy of Sciences(QYZDJ-SSW-SLH045)。
This work presents a highly active and reusable heterogeneous film catalytic assembly for hydrogenation reduction of aromatic nitro compounds. The multilayer structures of PEI-(K2PdCl4-P1)n-film(PEI = polyethylenmine,...
ProjectsupportedbytheNationalNaturalScienceFoundationofChina (No .20076019)andtheNaturalScienceFoundationofGuang dongProvince (No .0 0 0 44 4)
The enantioselective synthesis of ( R ) 2 trimethylsilyl 2 hydroxyl propionitrile by ( R ) oxynitrilase contained in defatted apple seed meal in a biphasic system was successfully performed. The influences o...
Project supported by the National Natural Science Foundation of Jiangxi Province.
MINDO/3 MO method has been used to study the mechanism of the consecutive addition of HCN to propionitrile. The results obtained for the first five steps show that the reaction is exothermic, and step 1 is the rate d...