HYDROGENASES

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Synthesis, structure and electrocatalytic H2-evoluting activity of a dinickel model complex related to the active site of [NiFe]-hydrogenases
《Chinese Chemical Letters》2020年第9期2483-2486,共4页Dengmeng Song Xuyun Gao Bo Li Jun Li Xuzhuo Sun Chengbo Li Jiale Zhao Lin Chen Ning Wang 
supported by National Natural Science Foundation of China(Nos.21773184,21671158 and 21601164);Natural Science Foundation of Henan(No.162300410052);Key Science and Technology Project of Henan(No.172102310137)。
Structural and functional biomimicking of the active site of [NiFe]-hydrogenases can provide helpful hints for designing bioinspired catalysts to replace the expensive noble metal catalysts for H2 generation and uptak...
关键词：HYDROGENASE ELECTROCATALYSIS Hydrogen evolution Nickel complex Metallothiolate ligand 
Synthesis, Characterization and Electrochemistry of 1,2-Bis(diphenylphosphino)benzene-chelated Diiron Ethane-1,2-dithiolate Tetracarbonyl Complex
《Chinese Journal of Structural Chemistry》2020年第5期927-932,共6页LIN Hui-Min LI Ao IAO Qi-Min LIU Xu-Feng LI Yu-Long LIU Xing-Hai JIANG Zhong-Qing 
supported by the Natural Science Foundation of Zhejiang Province(LY19B020002);National Natural Science Foundation of China(21501124);Science&Technology Department of Sichuan Province(2018JY0235);Education Department of Sichuan Province(18ZA0337);Sichuan University of Science&Engineering(S201910622022)。
In this paper,a novel diiron ethane-1,2-dithiolate complex[Fe2(CO)4{κ2-(Ph2P)2(1,2-C6H4)}(μ-SCH2CH2S)]has been prepared and structurally characterized.Treatment of the parent complex[Fe2(CO)6(μ-SCH2CH2S)]with 1 equ...
关键词：diiron ethane-1 2-dithiolate [FeFe]-hydrogenases diphosphine ligand X-ray crystallography ELECTROCHEMISTRY 
Syntheses and Characterization of Two Diiron Dithiolate Complexes with Electron-withdrawing and Electron-donating Substitution
《Chinese Journal of Structural Chemistry》2016年第8期1195-1203,共9页高娴静 刘海雄 陈惠 马成丙 陈昌能 
supported by the National Natural Science Foundation of China(Nos.21231003 and 21203195)
Two diiron dithiolate complexes [Fe2（CO）6（1,8-S2-2-CH2OOCPhC（10）H5）] 1 and[Fe2（CO）6（1,8-S2-2-CH2OOCPh-4-NO2C（10）H5）]2 were synthesized in high yield. The complexes have been confirmed by single-crystal X-r...
关键词：[Fe-Fe]-hydrogenases electrochemistry naphthalene thiolate electron-withdrawing 
Syntheses, Characterization and X-ray Crystal Structures of Diiron Ethanedithiolate Complexes Fe_2(S_2C_2H_4 )(CO)_5 (2-Ph_2PC_6H_4NH_2 ) and Fe_2 (S_2C_2H_4 )(CO)_5 (2-Ph_2PC_6H_4CH_2NH_2)
《Chinese Journal of Structural Chemistry》2013年第7期1105-1109,共5页李玉龙 谢斌 邹立科 林肖 王伦 
supported by Science & Technology Department of Sichuan Province (2011JY0052,2012JY0115, 2010GZ0130);Sichuan University of Science & Engineering (2011RC06, 2012PY04, 2012PY14)
Two new diiron ethanedithiolate complexes Fe2（S2C2H4）（CO）5（2-Ph2PC6H4NH2） （1） and Fez（S2CzH4）（CO）5（2-PhzPC6H4CHzNH2） （2） as active site models of [FeFe] hydrogenases have been prepared by the treatment...
关键词：diiron ethanedithiolate [FeFe] hydrogenases synthesis crystal structure 
Genomic Analysis of <i>Anabaena variabilis</i>Mutants PK17 and PK84 That Are Characterised by High Production of Molecular Hydrogen
《Advances in Microbiology》2013年第4期350-365,共16页Sergey V. Shestakov Lidia E. Mikheeva Andrey V. Mardanov Nikolai V. Ravin Konstantin G. Skryabin 
The use of cyanobacteria for producing molecular hydrogen is one of the desirable tasks of photobiotechnology. Some years ago, we isolated several chemically induced mutants of the cyanobacterium Anabaena variabilis A...
关键词：Cyanobacteria Hydrogen Metabolism HYDROGENASES PYROSEQUENCING MUTANTS ANABAENA 
Functional analysis of hydrogenases and their effects on cell growth and magnetosome synthesis in Magnetospirillum gryphiswaldense
《Chinese Science Bulletin》2010年第13期1271-1277,共7页BAN Jia JIANG Wei LI Ying ZHANG YaoPing LI JiLun 
supported by the National Natural Science Foundation of China (Grant Nos. 30570023 and 30870043);National High Technol-ogy Research and Development Program of China (Grant No2007AA021805)
This study addressed the effect of hydrogen metabolism on cell growth and magnetosome synthesis in Magnetospirillum gryphiswaldense strain MSR-1. Two deletion mutants were generated: L206, with single deletion of the ...
关键词：诱导合成 细胞生长 氢化酶 电子显微镜观察 氢气生产 螺 吸收能力 缺失突变体 
Challenge of new biological energy resources——Arguments on structure of active site of NiFe hydrogenase
《Chinese Science Bulletin》1998年第20期1673-1681,共9页Qi Zhang Daizheng Liao Genglin Wang 
Hydrogenases are enzymes that can reversibly split molecular hydrogen. Study on the structure of the active site and the mechanism of catalysis has drawn great attention because the results may be useful for the desig...
关键词：HYDROGENASES nickel_iron COMPLEXES HETERODINUCLEAR cluster active SITE fuel cells. 
THE SEPARATION AND PROPERTIES OF TWO MEMBRANE-BOUND HYDROGENASES IN——Rhodopseudomonas capsulata
《Chinese Science Bulletin》1984年第8期1102-1106,共5页朱长喜 陈秉险 宋鸿遇 
Hydrogenase is an enzyme widely distributed in nature, being found in bacteria, algae and plants. It catalyzes the reversible oxidation of the simplest molecule H2, as represented by the
关键词：reversible duets METHYLENE ALGAE uptake latter AMMONIUM instead nitrate REMAINING 
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