MIXED-VALENCE

作品数：46被引量：19H指数：2
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Bandgap engineering of tetragonal phase CuFeS_(2)quantum dots via mixed-valence single-atomic Ag decoration for synergistic Cr(VI)reduction and RhB degradation被引量：1
《Chinese Chemical Letters》2021年第11期3450-3456,共7页Yangzi Shangguan Yuanhao Zhou Renji Zheng Xuezhen Feng Qiuyue Ge Ranhao Wang Dazhong Yang Wenfei Wei Xiaoyong Wu Jia Lin Hong Chen 
financially supported by the National Natural Science Foundation of China(Nos.21777045,61875119);Distinguished Young Scholar Fund from Natural Science Funds of Guangdong Province,China(No.2020B151502094);the program for Professor of Special Appointment(Eastern Scholar)at Shanghai Institutions of Higher Learning,Shanghai Rising-Star Program(No.19QA1404000);Shanghai Talent Development Fund.
Bandgap engineering through single-atom site binding on semiconducting photocatalyst can boost the intrinsic activity,selectivity,carrier separation,and electron transport.Here,we report a mixed-valence Ag(0)and Ag(I)...
关键词：Single-atom catalysts Bandgap engineering Cr(VI)reduction Organic pollutants degradation Dyeing wastewater treatment 
Synthetic[FeFe]-H_2ase models bearing phosphino thioether chelating ligands
《Chinese Chemical Letters》2018年第11期1651-1655,共5页Yingjie Zhao Xin Yu Huilan Hu Xinlong Hu Sakthi Raje Raja Angamuthu Chen-Ho Tung Wenguang Wang 
financial support from the "1000 Youth Talents Plan"; the Natural Science Foundation of China (Nos. 21402107, 91427303);IIT Kanpur for funding
A series of {2Fe3S} complexes bearing phosphino thioether chelating ligand were synthesized on the basis of Fe2（Me2pdt）（1,2-Cy2PC6H4SMe）（CO）4 （Me2pdt= Me2C（CH2S ）2, 1）. The disubstituted Fe（1）Fe（1） compo...
关键词：[FeFe]-H2ases models Mixed-valence Fe（Ⅰ）Fe（Ⅱ） Phosphino thioether ligand Diiron bridging hydride Lewis-acid basicity 
Studies on A Novel Mixed-Valence Complex of Copper(Ⅰ,Ⅱ)α-Methacrylate with Imidazole and Aqua
《Chinese Chemical Letters》1999年第2期187-188,共2页Yao Yu WANG Xin WANG Qian SHI Qi Zhen SHI Yi Ci GAO(Department of Chemistry, Northwest University, Xian, 710069)(Department of Chemistry, Lanzhou University, Lanzhou. 730000) 
A novel mixed-valence copper (Ⅰ,Ⅱ) complex Cu3 [CH2=C(CH3) COO]5 (imH)3 (H2O)has been synthesized and characterized by XPS spectra and single crystal X-ray structural analysis.The title complex crystallized in monoc...
关键词：Mixed-valence copper (Ⅰ Ⅱ) complex synthesis crystal structure 
Electrochemical and Spectroelectrochemical studies of Mixed-Valence Heteropolyanion VMo_(12)O_(40)^(n-)(n=4,5,6) in Aprotic Media
《Chinese Chemical Letters》1997年第10期909-912,共4页Shu Yan ZHANG Hao Ran SUN Ji Qing XU Tong Shun SHl(Department of Chemistry, Jilin University, Changchun 130023) 
The mixed-valence heteropolyanion VMo12O40 n-(where n=4,5,6) in aprotic media wasinvestigated by cyclic voltammatry and in-situ FTIR and UV-visible-near-lRspectroelectrochemical methods. The results indicate that the...
关键词：Media n=4 5 6 VM Figure N in Aprotic Media Electrochemical and Spectroelectrochemical studies of Mixed-Valence Heteropolyanion VMo 
THE SYNTHESIS AND CHARACTERIZATION OF A NOVELMIXED-VALENCE ISOPOLYVANADATE
《Chinese Chemical Letters》1996年第6期565-566,共2页Xu, JN Yang, GY Ma, WY Sun, ZZ Xu, JQ Huang, XY 
The present paper covers the synthesis and characterization of a mixed valence vanadate, (H(2)En) V4O10(Compound I, H(2)En = H3NCH2CH2NH3), in which the V-N/V-V ratio is unity. The X-Ray diffraction pattern and DTA-TG...
IN－SITU　FTIR　AND　UV－VISIBLE－NEAR－IR　SPECTROELECTROOHEMICAL　STUDIES　OF　MIXED－VALENCE　ISOPOLYANION　Mo＿6O＿（19）￣（3－）　IN　APROTIC　MEDIA
《Chinese Chemical Letters》1995年第12期1059-1060,共2页Hao Ran SUN Gou Yu YANG Jia Ning XU Ji Qing XU (Department of Chemistry,Chemistry, Jilin University, Changchan, 130023) 
In the paper, we have studied the mixed-valence isopolyanion by cyclic voltammogram, in-situ UV-Visible-Near-IR and FTIR spectroelectrochemical methods in aprotic medium,such as methylene chloride.A number of hetero-...
关键词：FTIR SITU VISIBLE APROTIC AND MO UV 
SYNTHESIS AND STRUCTURE OF A MIXED-VALENCE HEXAMOLYBDENUM COMPLEX [Et_4N]_2[Mo_6O_(19)H_4]
《Chinese Chemical Letters》1992年第6期459-462,共4页Shu Jia LI Heng Bin ZHANG Shu Yun NIU Guang Di YANG Fu NIE Department of Chemistry, Institute of Theoretic Chemistry, Jilin University, Changchun, 130023 
A hexamolybdenum complex, [Et_4N]_2[Mo_6O_(19)H_4] crystal, with pentavalent and hexavalent molybdenum has been obtained in the solution of DMF and CH_3OH as organic solvents using MoCl_5 as a starting material. The c...
关键词：Mo6O SYNTHESIS AND STRUCTURE OF A MIXED-VALENCE HEXAMOLYBDENUM COMPLEX H4 ET4N 
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