云南高校图书馆联盟文献共享服务平台- MIXED-VALENCE

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Syntheses and Characterizations of Cyanido-bridged Dinuclear Ru-complexes and Their MMCT Properties in the One-electron Oxidation State: 《Chinese Journal of Structural Chemistry》2021年第10期1253-1264,共12页LIU Yang ZHU Xiao-Quan WU Xin-Tao SHENG Tian-Lu; the National Science Foundation of China(21773243,21973095);the Strategic Priority Research Program of Chinese Academy of Sciences(XDB20010200)for financial support。; We have designed and synthesized a family of dinuclear cyanido-bridged complexes[PY5Me_(2)Ru(μ-CN)Ru(dppe)CpMe_(n)][PF_(6)]_(2) (PY5Me_(2)=2,6-bis (1,1-bis(2-pyridyl)ethyl) pyridine,Cp=cyclopentadienyl,n=0,2[PF6]_(2)...; 关键词：electron transfer MIXED-VALENCE metal to metal charge transfer(MMCT) cyanide bridge

Self-assembly of a Mixed-valence Cu(Ⅰ)/Cu(Ⅱ)Coordination Polymer Derived from a Conformationally Flexible Tripodal Phosphoric Trimide Ligand被引量：1: 《Chinese Journal of Structural Chemistry》2016年第5期747-752,共6页弓亚琼高金伟米陶清; supported by the Natural Science Foundation of Shanxi province(2012021005-2);Technology Foundation for Selected Overseas of Shanxi; Reaction of a tripodal ligand, N,N＇,N＇＇-tris（3-pyridinyl） phosphoric trimide（TPPA） and CuBr_2·2H_2O result in the assembly of a new polymeric copper coordination polymer, which was characterized by single-crys...; 关键词：copper phosphoric trimide mixed-valence complex crystal structure

Mo8^ⅤW2^ⅥO26（C5H5N）8·2H2O： A Novel Mixed-valence Heterometal Polyoxometalate: 《Chinese Journal of Structural Chemistry》2014年第11期1697-1702,共6页仪晓凤杨环王义王璐璐桑瑞利徐立; supported by the National Natural Science Foundation of China(No.21003125,21073190); A new mixed-valence heterometal cluster Mo8VW2VIO26（C5H5N）8·2H2O has been synthesized under solvothermal conditions and characterized by X-ray single-crystal diffraction, IR, UV-vis and XPS spectroscopy. The title ...; 关键词：molybdenum-tungsten metal-metal bond MIXED-VALENCE POLYOXOMETALATE solvothermal synthesis

Synthesis,Crystal Structure and MMCT Property of a New Mixed-valence Cyanide-bridged Binuclear Complex: 《Chinese Journal of Structural Chemistry》2014年第9期1305-1310,共6页孙志豪王勇马骁王艳龙胡胜民盛天录吴新涛; supported by the 973 Program(2012CB821702,2014CB845603);the National Natural Science Foundation of China(21233009,21203194 and 21173223); A new mixed-valence cyanide-bridged complex, Br3Fe（p-NC）RuBr（dppm）2 （dppm = bis（diphenylphosphino）methane）, was obtained through the reaction between trans-（dppm）2C1- RuCN and FeBr3. Its crystal structure wa...; 关键词：CYANIDE-BRIDGED MIXED-VALENCE BINUCLEAR MMCT crystal structure

A Novel Mixed-valence and Capped-keggin Structural Polyoxometal Complex:{[Co(dien)]_4-[(PO_4)Mo_8~Ⅴ(W_(0.56)^(Ⅵ)Mo_(0.44)^(Ⅵ))_4O_(33)(OH)_3 ]}·nH_2O(n≈1)被引量：2: 《Chinese Journal of Structural Chemistry》2013年第11期1653-1662,共10页胡志彪陈武华宓锦校; Foundation of Education Department of Fujian Province(Nos.JA11245 and JB12199);National Natural Science Foundation of China(No.40972035); A novel inorganic-organic hybrid compound, {[Co（dien）]4[0aO4）MoV8（wV10.56MoV10.44）4- O33（OH）3]}＇nH20 （1, n = 1, dien = diethylenetriamine）, has been synthesized hydrothermally and characterized by single-cry...; 关键词：inorganic-organic hybrid compound e-Keggin-structure hydrothermal synthesis MIXED-VALENCE mixed-distribution

Synthesis,Crystal Structure and Characterization of a New Mixed-valence Cu(Ⅰ)/Cu(Ⅱ) Complex [Cu(bipy)(Me_2dtc)CuI_2]_n: 《Chinese Journal of Structural Chemistry》2011年第3期340-345,共6页范乐庆吴季怀黄昀昉林建明; Supported by the National High Technology Research and Development Program of China (863 Program, No. 2009AA03Z217);the National Natural Science Foundation of China (No. 90922028);the Young Talent Program of Fujian Province (No. 2007F3060);the Fund of Fujian Provincial Key Laboratory of Nanomaterials (No. NM10-5); A new one-dimensional mixed-valence Cu（Ⅰ）/Cu（Ⅱ） complex [Cu（bipy）（Me2dtc）CuI2]n 1 （bipy = 2,2′-bipyridine and Me2dtc = N,N-dimethyldithiocarbamate） has been synthesized under solution condition, and chara...; 关键词：Cu（I）/Cu（II） N N-dimethyldithiocarbamate 2 2＇-bipyridine crystal structure π-π packing interactions magnetic study

Hydrothermal Synthesis and Structure of a Mixed-valence Polyoxotungstate Decorated by Copper(I) Coordination Group, [Cu(en)_2H_2O]_2[{Cu(en)_2}HPW_(12)O_(40)]·2H_2O被引量：2: 《Chinese Journal of Structural Chemistry》2005年第5期608-614,494,共8页李真林碧洲韩国华耿凤刘培德; This work was supported by the Natural Science Foundation of Fujian Province (No. E0420001) and the Science Foundation of Huaqiao University (No. 03HZR9); A complex [Cu(en)2H2O]2[{Cu(en)2}HPW12O40]?2H2O (C12H57Cu3N12O44PW12, Mr = 3501.49) has been synthesized under hydrothermal conditions and its crystal structure was determined by X-ray diffraction. It crystallizes in ...; 关键词：hydrothermal synthesis crystal structure POLYOXOTUNGSTATE copper complexes bimetallic oxide clusters

Solvothermal Synthesis and Structure Studies of a Mixed-valence Oxochloromolybdenum Complex: 《Chinese Journal of Structural Chemistry》2003年第4期395-398,共4页宋立军曾卉一蔡丽珍董振超郭国聪黄锦顺; the Innovative Project (No. IP01007);the Introduction of Overseas Elitists Program (No. IB990168);the Chinese Academy of Sciences; Emerald green crystals of a new mixed-valence oxochloromolybdenum complex, Mo(OH)2(2,2-bipy)Cl2[MoO(2,2-bipy)Cl3]2, were obtained in an attempt to synthesize the MoS cluster compounds under solvothermal conditions. Th...; 关键词：oxochloromolybdenum solvothermal synthesis STRUCTURE

Crystal Structure of La_4V_5Si_4O_(22)──A Mixed-Valence Lanthanum Vanadium (Ⅲ/Ⅳ) Oxosilicate: 《Chinese Journal of Structural Chemistry》1995年第4期314-317,共4页陈久桐黄锦顺等; The title compound was prepared by solid state reaction of LaCl_3/V inan evacuated silica tube where the silicon came from the reaction tube. The compoundcrystallizes in monoclinic space group C2/m with cell dimension...; 关键词：lanthanum vanadium oxosilicate crystal structure MIXED-VALENCE

Synthesis and Crystal Structure of a Mixed-Valence Trinuclear Manganese Complex: Mn_3O(O_2CPh)_6(Py)_3被引量：1: 《Chinese Journal of Structural Chemistry》1994年第4期272-275,共4页徐皓郁开北等; A new mixed-valence oxo-centered trinuclear manganese complex Mn3O(O2CPh)6 (Py)3 was prepared in pyridine solvent and its crystal structure has been determined. C57H45O13N3Mn3, Mr =1144. 81, trigonal, space group R3,...; 关键词：mixed-valence manganese complex crystal structure SYNTHESIS

MIXED-VALENCE