supported by the National Natural Science Foundation of China(Nos.21971223 and 21772178)。
Trifluoroacetic acid(TFA)catalyzed condensation reaction between tetraaminooxacalix[4]arene and N-alkylcarbazole-3,6-dicarbaldehyde in CH_(2)Cl2afforded a single product in 87%–89%yield.Well-defined yet undissolvable...
the National Natural Science Foundation of China(No.21772027 to B.-G.Wei and 21702032 to C.-M.Si)for financial support.
An efficient approach to functionalized 4,6-disubstituted-and 4,6,6-trisubstituted-1,3-oxazinan-2-ones skeleton has been developed through the reaction of semicyclic N,O-acetals 4a and 4b with 1,1-disubstituted ethyle...
the financial support from the National Natural Science Foundation of China(Nos.21572026,21702019);Advanced Catalysis and Green Manufacturing Collaborative Innovation Center,Changzhou University。
Metal-free direct α-C(sp^(3))-H intramolecular cyclization of 2-alkylthiobenzoic acid in the presence of Selectfluor is described.This novel strategy provides a facile and efficient method to access important 1,3-ben...
Financial support from the National Natural Science Foundation of China(Nos.21071053,21002031,61078071);Shanghai Commission for Science and Technology(Nos.10ZR1409700, 09ZR1422500);"Strategic Priority Research Program"of Chinese Academy of Sciences(No.XDA01020304)are acknowledged
Oxacalixcrowns 1, 2 and 3 were synthesized via reactions of dihydroxyoxacalix[2]arene[2]pyrazine S with ortho-, meta- and para-bis(bromomethyl)benzenes in a 1:1 fashion. The structures and conformations of 1, 2 and...
An effective route to 5-vinylated and N-vinylated benzo[d]oxazole-2(3H)-thiones and benzo[d]thiazole-2(3H)-thiones is described via reaction of acetylenic esters and benzo[d]oxazole-2-thiol and benzo[d]thiazole-2-...
Synthesis of novel 3-aryl-5-(3,5-dimethylisoxazol-4-yl)-2,3,5,6-tetrahydrobenzo[g][1,3,5],oxadiazocine-4-thiones 5 has been accomplished from 3,5-dimethylisoxazol-4-amine 1 by condensation with salicylaldehydes, fol...
Novel 1, 3, 4-thia(oxa)diazoles containing thienyl groups were synthesized. Analogous to the naturally-occurring compound, a-terthienyl, they can be photosensitized by ultraviolet light and showed phototoxicities agai...
A bisphosphate-bridged tetrahomodioxacalix[6]arene with a C2v symmetry at the ambient temperature was obtained by the reaction of tetrahomodioxacalix[6]arene with POCl3.
This work was supported by the National Natural Science Foundation of China (No. 29725410 and 29992530) and Chinese Academy of Sciences (KJ951-A1-501-01).
A novel bipolar conjugated polymer containing triphenylamine and 1, 3, 4-oxadiazole units was synthesized by Suzuki reaction. Its structure and properties were characterized by NMR, IR, UV-Vis, PL spectroscopy and el...