supported by the National Natural Science Foundation of China(22361003);Jiangxi Provincial Science Foundation for Distinguished Young Scholars(20212ACB216002);the Youth JinggangScholars Program in JiangxiProvince(QNJG2019089);the Jiangxi Provincial Natural Science Foundation(20224BAB216005,20242BAB25591);the Yunnan Revitalization Talent Support Program“Young Talent”Project and the Research Foundation of Zhaoqing University(ZD202413).
Indolizine is a nitrogen-containing heterocycle with strong aromaticity,possessing a delocalized 10π-electron system.Based on the indolizine scaffolds,numerous molecules with biological activity and organic functiona...
supported by the National Natural Science Foundation of China(U23A2095,22371278);Funding of the Fujian Provincial Chemistry Discipline Alliance,Natural Science Foundation of Fujian Province(2021J06035);Youth Innovation Promotion Association of the Chinese Academy of Sciences(Y2018081).
Macrocyclic compounds are of great interest for their ability to capture guest molecules into their cavities.In particular,host-guest interaction plays a crucial role in the formation of supramolecular compounds.Herei...
the financial support fromtheNSFC(21975055,U2001222,52103352,52120105006,and 51925306);National Key R&D Program of China(2018FYA 0305800);Key Research Program of Chinese Academy of Sciences(XDPB08-2);the Youth Innovation Promotion Association of Chinese Academy of Sciences(2022165);the Fundamental Research Funds for the Central Universities.DFT results described in this article were obtained from the National Supercomputing Centre in Shenzhen(Shenzhen Cloud Computing Centre).
By employing the asymmetric end-group engineering,an asymmetric nonfused-ring electron acceptor(NFREA)was designed and synthesized.Compared with the symmetric analogs(NoCA-17 and NoCA-18),NoCA-19 possesses broader lig...
the NSFC(Nos.22071098,21931002 and 22101123);the Guangdong Provincial Key Laboratory of Catalysis(No.2020B121201002);the Shenzhen Science and Technology Innovation Committee(No.JCYJ20200109140812302);Introduction of Major Talent Projects in Guangdong Province(No.2019CX01C079);Outstanding Talents Training Fund in Shenzhen,for their financial support.
Metallacyclopentadienes are important metallacycles and regarded as intermediates in many reactions,therefore,new methods to achieve them are anticipated.In this study,a formal[3+2]method,through the reactions of an o...
the National Natural Science Foundation of China((52120105006,52103352,and 51925306);National Key R&D Program of China(2018FYA 0305800);Key Research Program of Chinese Academy of Sciences(XDPB08-2);the Strategic Priority Research Program of Chinese Academy of Sciences(XDB28000000);the Youth Innovation Promotion Association of Chinese Academy of Sciences(2022165);the Fundamental Research Funds for the Central Universities.DFT results described in this report were obtained from the National Supercomputing Center in Shenzhen(Shenzhen CloudComputing Center).
Comprehensive Summary By employing thiazole and 4-chlorothiazole as the A′units,two A-D-A′-D-A type nonfused-ring electron acceptors(NFREAs)Tz-H and Tz-Cl were designed and synthesized.Replacing thiazole in Tz-H wit...
We propose a strategy to improve performance of unidirectionally extended fused-ring electron acceptors by using pyrrolo[3,2-b]pyrrole to replace pyrrole ring, and design two asymmetric nonfullerene acceptors 1PIC and...
This work is supported by the National Natural Science Foundation of China(U21A20101).
Fullerene derivatives are classic electron acceptor materials for organic solar cells (Oscs) but possess some intrinsic drawbacks such as weak visiblelightabsorption,limitedoptoelectronic property tunability,dificult ...
supported financially by grants from NSFC(81874295);Top Young Talent of the Ten Thousand Talents Program of Yunnan(to Y.Zhang).
Comprehensive Summary Tabernaesine J(1),an unprecedented vincamine-type indole alkaloid with 6/5/6/6/6/5/5 heptacyclic-ring system,as well as one new biogenetically related vincamine-type indole alkaloid(2),were isola...
supported by the National Natural Science Foundation of China(NSFC)(Nos.51773142 and 51973146);the Jiangsu Provincial Natural Science Foundation(Grant No.BK20190099);the Collaborative Innovation Center of Suzhou Nano Science&Technology;the Priority Academic Program Development of Jiangsu Higher Education Institutions.
Main observation and conclusion Recently,the asymmetric nonfullerene acceptors(NFAs)with acceptor-donor-acceptor(A-D-A)structure have been developed rapidly,especially for the modification of asymmetric core,asymmetri...
support from the National Natural Science Foundation of China(Nos.21875184,21978311);the Youth Talent of Shaanxi"TeZhi"Program;project sponsored by Xi’an Modern Chemistry Research Institute(WDZCKYXM20190101).
Main observation and conclusion Important progress has been made in the development of energetic molecules with high performance by computer-aided molecular design in recent years,but structural novelty of organic sca...