SOLVENT-FREE

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Design and preparation of a crosslinkable,oil-resistant,and bio-based elastomer from fumarate
《Science China Chemistry》2024年第2期622-631,共10页Hui Yang Haijun Ji Xinxin Zhou Shihan Yang Liwei Li Chaoying Sun Weiwei Lei Runguo Wang Liqun Zhang 
supported by the National Key Research and Development Program of China (2022YFC2104700);the National Natural Science Foundation of China (52273003,51988102)。
Poly(diethyl fumarate-co-methoxyethyl acrylate-co-vinyl chloroacetate)(PDEFMV),a novel bio-based elastomer with a saturated structure,was synthesized via redox emulsion polymerization.The glass-transition temperatures...
关键词：diethyl fumarate molecular design bio-based elastomer solvent-free synthetic route high-temperature oil resistance 
Theoretical design for zeolite synthesis被引量：7
《Science China Chemistry》2022年第9期1683-1690,共8页Qinming Wu Huimin Luan Feng-Shou Xiao 
supported by the National Natural Science Foundation of China(22172141,21802121,21835002,and 92045303);the Fundamental Research Funds for the Central Universities(2021QNA4028)。
Zeolites,an important class of microporous crystals,have been widely utilized in the fields of catalysis,ion-exchange,separation,and sorption for a long time.In general,zeolites are synthesized in the presence of cost...
关键词：ZEOLITE organic template organotemplate-free SOLVENT-FREE interzeolite transformation morphology control 
Catalyst-and solvent-free,thermal generation of microporous polymer networks
《Science China Chemistry》2017年第8期1103-1106,共4页christian widling michael forster venkata m.suresh ullrich scherf 
Multifunctional iodoaryl monomers were used for the catalyst- and solvent-free generation of microporous polymer networks of high surface areas up to 732mEg-1. The thermal conversion of the monomers relies on the homo...
关键词：microporous polymer networks thermal generation gas uptake 
Solvent-free synthesis of zeolite catalysts被引量：7
《Science China Chemistry》2015年第1期6-13,共8页Xiangju Meng Qinming Wu Fang Chen Feng-Shou Xiao 
supported by the National Natural Science Foundation of China(21273197,21333009,21203165);Fundamental Research Funds for the Central Universities(2013XZZX001);the National High Technology Research and Development Program of China(2013AA065301);the Science and Technology Innovative Team of Zhejiang Province(2012R10014-02)
The most used method for preparation of zeolites is hydrothermal synthesis from silicate or aluminosilicate gels at temperatures in the range of 60-200 ℃. Excess water used in the industrial process results in severa...
关键词：zeolites SOLVENT-FREE SUSTAINABLE 
Environmentally benign chemical fixation of CO_(2) catalyzed by the functionalized ion-exchange resins被引量：2
《Science China Chemistry》2010年第7期1578-1585,共8页LIU AnHua HE LiangNian PENG ShiYong PAN ZhongDa WANG JingLun GAO Jian 
supported by the National Natural Science Foundation of China (20672054 & 20872073);the 111 Project of the Ministry of Education of China (B06005)
Basic ion-exchange resins,one kind of polystyryl-supported tertiary amine,were demonstrated to be highly efficient and recyclable catalysts for the fixation of carbon dioxide with aziridines under mild conditions,lead...
关键词：CYCLOADDITION carbon dioxide AZIRIDINE ion-exchange resin solvent-free process 
New observation on a class of old reactions:Chemoselectivity for the solvent-free reaction of aromatic aldehydes with alkylketones catalyzed by a double-component inorganic base system被引量：2
《Science China Chemistry》2010年第5期1094-1100,共7页Shan, ZiXing  Luo, XinXiang  Hu, Lin  Hu, XiaoYun 
supported by the National Natural Science Foundation of China(20372053,20672083 and 20872115)
Solvent-free reactions of aromatic aldehydes with three representative ketones,including acetophenone,acetone and cyclohexanone,have been examined under the catalysis of a low-cost inorganic base system consisting of ...
关键词：SOLVENT-FREE REACTION solid base mixture catalysis CHEMOSELECTIVITY aldehyde-ketone REACTION 
A new series of two-photon polymerization initiators:Synthesis and nonlinear optical properties
《Science China Chemistry》2009年第12期2180-2185,共6页GAN XiaoPing ZHOU HongPing SHI PengFei WANG Peng WU JieYing TIAN YuPeng YANG JiaXiang XU GuiBao ZHOU YuFang JIANG MinHua 
Supported by the National Natural Science Foundation of China (Grant Nos. 50532030, 50703001 & 20771001);the National Natural Science Foundation of Anhui Province (Grant No. 070414188);Doctoral Program Foundation of the Minis-try of Education of China, Education Committee of Anhui Province (Grant No. 2006KJ032A & KJ2009A52);Team for Scientific Innovation Foundation of Anhui Province (Grant No. 2006KJ007TD);Young Teacher Foundation of Institution of High Education of Anhui Province (Grant No. 2007jq1019);Ministry of Education and Person with Ability Foundation of Anhui University
Four photopolymerization initiators with D-π-D (D,donor; π,conjugation system) structure have been synthesized by solvent-free reaction and characterized by 1H NMR spectroscopy,IR and elemental analysis. The one-pho...
关键词：TWO-PHOTON ABSORPTION MICRO-FABRICATION POLYMERIZATION SOLVENT-FREE 
Highly efficient heterogeneous procedure for the conjugate addition of amines to electron deficient alkenes
《Science China Chemistry》2009年第7期874-878,共5页XueZheng Liang  NanNan Quan  Jian Wang JianGuo Yang 
Supported by the National Key Project of Scientific and Technical Supporting Programs Funded by Ministry of Science and Technology of China (Grant No. 2006BAE03B06);Shanghai Leading Academic Discipline Project (Grant No. B409);Shanghai International Cooperation of Science and Technology Project (Grant No. 06SR07101)
The novel efficient procedure has been developed for the conjugate addition of amines to electron deficient alkenes. K2CO3 supported on different carriers have been synthesized for the conjugate ...
关键词：heterogeneity CONJUGATE addition CHEMOSELECTIVITY catalysis SOLVENT-FREE 
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