financially supported by the National Natural Science Foundation of China(Nos.22135007,21875244 and 52073281);Jilin Scientific and Technological Development Program(No.YDZJ202101ZYTS138)。
The development of donor-acceptor(D-A)type conjugated polymers depends largely on the design of novel A building blocks.Herein,we report a novel A building block based on the cyano-substituted organoboron unit(SBN-3)....
financially supported by the National Basic Research Program of China(No.2015CB654700);the National Natural Science Foundation of China(No.U1462124);the National Key Technology R&D Program(No.2014BAE14B00)
Half-titanocene complexes bearing dibenzhydryl-substituted aryloxide ligands (2a-2d) were prepared. Among them, 2e adopted a three-legged distorted tetrahedral geometry evidenced by X-ray crystallography. The poly-1...
financially supported by the National Natural Science Foundation of China(Nos.51473074 and 31400044);the General and Special Program of the Postdoctoral Science Foundation China(Nos.2013M530397 and 2014T70861);the Postgraduate Innovation Project of China University of Petroleum(East China)(No.YCX2015022);the Fundamental Research Funds for the Central Universities(No.15CX06049A)
Two novel decyloxyphenylquinoxaline-based donor-acceptor (D-A) electroactive monomers bearing dialkoxythiophene as the donor unit are synthesized using Stille coupling reaction. The corresponding polymers, poly[2,3-...
financially supported by the National Natural Science Foundation of China(Nos.51163003 and 21264005);the fund of Guangxi Natural Science Foundation(Nos.2014GXNSFAA118040 and 2013GXNSFDA019008);Guangxi Funds for Specially-appointed Expert
A novel non-coplanar aromatic diamine monomer, 3,3'-ditertbutyl-4,4'-diaminodiphenyl-4"-naphthylmethane (TAPN) was synthesized by a condensation reaction of 2-tertbutylaniline and 1-naphthaldehyde under catalyst ...
financially supported by the National Natural Science Foundation of China(Nos.21134004,21201108 and 51363016);the National 973 Project(No.2011CB935700);China Postdoctoral Science Foundation(Nos.2012M520243,2013T60100)
A cyano-substituted diarylethlene derivative aggregation-induced emission (ALE) dye with two amino end-groups and 4,4'-(hexafluoroisopropylidene)diphthalic anhydride were facilely incorporated into red fluorescen...
supported by the National Natural Science Foundation of China (No. 21234006)
The ethylene/cyclopentadiene (CPD) copolymerization behavior by using fluoro-substituted bis(fl- enaminoketonato) titanium complexes [FC6H4NC(CH3)CHCO(CF3)]2TiC12 (la-lc) has been investigated in detail. Upo...
supported by the National Natural Science Foundation of China (Nos. 21174010, 20974007);the Fundamental Research Funds for the Central Universities (ZZ1117)
The "sergeants and soldiers rule" occurring in helical copolymer emulsions derived from an achiral monomer (M1) and a chiral monomer (M2) was observed. TEM, GPC, and 1H-NMR techniques in combination demonstrate ...
supported by the Natural Science Foundation of Shanxi Province(No.2006011069);the Opening Foundation of Key Laboratory of Shanxi Province(No.2009011059-7)
Rare earth aryloxides substituted by various alkyl groups [Ln(OAr)3] such as methyl, isopropyl and tertbutyl, were used as single component catalysts to affect ring-opening polymerization of L-lactide (LLA). The c...
This work was supported by the Scientific and Technological Agreement, China-France.
A substituted polyacetylene bearing a furan ring, poly(2-propynyl 2-furoate) (PPF), was synthesized for the first time with palladium acetylide complex catalysts in CHCl3 at 60°C to give a soluble and stable polymer ...