AMINATION

作品数:151被引量:183H指数:7
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相关领域:理学更多>>
相关作者:朱成建王建伟何小伟李江涛钱浩然更多>>
相关机构:南京大学浙江大学医学院附属第二医院东北电力大学中国科学院大学更多>>
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相关基金:国家自然科学基金中国博士后科学基金王宽诚敎育基金国家重点基础研究发展计划更多>>
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Tandem asymmetric propargylic amination/carboxylative cyclization reaction to chiral 5-methylidene-2-oxazolidinones using CO_(2) as C1 synthon
《Science China Chemistry》2025年第4期1402-1411,共10页Zheng Zhang Zhi-Hao Zhang Ying Sun Yun-Hao Tang Yi-Zhuo Yang Feng Zhou Jian Zhou 
supported by the National Natural Science Foundation of China(21871090,21725203);the National Key Research and Development Program of China(2020YFA0710200);the Shanghai Science and Technology Innovation Action Plan(20JC1416900);the Innovation Program of Shanghai Municipal Education Commission(2023ZKZD37);the Fundamental Research Funds for the Central Universities.
We report a tandem asymmetric Cu-catalyzed propargylic amination(ACPA)/Ag-catalyzed carboxylative cyclization(SCC)with CO_(2) to 5-methylidene-2-oxazolidinones;even with tetrasubstituted stereocenters.By varying pyrid...
关键词:CO_(2) 2-oxazolidinone tandem sequence propargylic amination carboxylative cyclization 
Upcycling of polyphenylene oxide into 2,6-dimethyl aniline via depolymerization and amination over a Pt/CeO_(2) catalyst
《Science China Chemistry》2025年第2期520-525,共6页Shengchao Jia Wenke Zhao Xiaohui Liu Yong Guo Yanqin Wang 
supported by the National Natural Science Foundation of China(22172048,22072042).
Upcycling of plastic waste into N-containing compound is a novel and attractive strategy for its disposal and will opens up a promising direction for the production of value-added amines.Herein,an efficient strategy f...
关键词:PPO depolymerization-amination 2 6-dimethyl aniline Pt/CeO_(2) 
Copper-catalyzed asymmetric dearomatizing amination of 2-naphthols:Csp^(2)–N coupling via 1,3-reductive elimination
《Science China Chemistry》2024年第8期2694-2700,共7页Aying Yihuo Maoping Pu Zheng Tan Jibang Liao Jiuqi Tan Qi-Lin Zhou Xiaohua Liu Xiaoming Feng 
supported by the National Natural Science Foundation of China(22188101);Sichuan Science and Technology Program(2021YJ0561)。
An efficient catalytic asymmetric dearomatizing amination of 2-naphthols and phenols catalyzed by N,N′-dioxide-copper(I)complex as a chiral catalyst was presented.A variety of optically activeβ-naphthalenone compoun...
关键词:asymmetric catalysis AMINATION DEAROMATIZATION copper catalysis coupling reaction 
Acceptorless dehydrogenative amination of alkenes for the synthesis of N-heterocycles
《Science China Chemistry》2022年第7期1330-1337,共8页Jia-Lin Tu Wan Tang Shi-Hui He Ma Su Feng Liu 
supported by the Natural Science Foundation of the Jiangsu Higher Education Institutions of China (18KJA350001);the Priority Academic Program Development of the Jiangsu Higher Education Institutes (PAPD)。
Catalytic amination of alkenes is one of the most attractive reactions for the construction of complex heterocycles with nitrogen centers. Herein, we present that synergistic photoredox and cobaloxime catalysis allows...
关键词:nitrogen-centered radical alkene amination PHOTOREDOX cyclization N-heterocycle 
Visible-light-mediated tungsten-catalyzed C-H amination of unactivated alkanes with nitroarenes被引量:1
《Science China Chemistry》2022年第4期678-685,共8页Qing Wang Shengyang Ni Xiaochen Wang Yi Wang Yi Pan 
supported by the National Natural Science Foundation of China(21772085,21971107,2201101);China Postdoctoral Science Foundation(2021T140309,2021M691511)。
Alkylamines are important motifs in pharmaceutical and material sciences.The existing reports of C-H amination are limited to ammonia,diazo and azide nitrogen sources.This work describes a rapid construction of C-N bo...
关键词:AMINATION PHOTOREDOX light alkane NITROBENZENE 
Photocatalytic divergent decarboxylative amination: a metal-free access to aliphatic amines and hydrazines被引量:1
《Science China Chemistry》2021年第10期1756-1762,共7页Xianli Shu Ruting Xu Saihu Liao 
the National Natural Science Foundation of China(21602028);Beijing National Laboratory for Molecular Sciences(BNLMS201913);the Recruitment Program of Global Experts;Fuzhou University。
Nitrogen-containing motifs are widely present in natural products, bioactive molecules, and drugs. Accordingly, effective synthetic methods with high efficiency and diversity are highly desirable. Here, we present the...
关键词:decarboxylative amination divergent synthesis nitrogen transfer AMINES DIAZIRINES 
Catalytic enantioselective synthesis of β-amino alcohols by nitrene insertion
《Science China Chemistry》2021年第3期452-458,共7页Zijun Zhou Yuqi Tan Xiang Shen Sergei Ivlev Eric Meggers 
supported by the Deutsche Forschungsgemeinschaft(ME 1805/15-1)。
Chiral β-amino alcohols are important building blocks for the synthesis of drugs, natural products, chiral auxiliaries, chiral ligands and chiral organocatalysts. The catalytic asymmetric β-amination of alcohols off...
关键词:asymmetric catalysis NITRENE AMINATION chiral-at-metal RUTHENIUM 
Silver-catalyzed three-component reaction: synthesis of N^2-substituted 1,2,3-triazoles via direct benzylic amination
《Science China Chemistry》2019年第8期1001-1006,共6页Zhenhua Liu Wenjing Hao Wen Gao Guangyu Zhu Xiang Li Lili Tong Bo Tang 
supported by the National Natural Science Foundation of China (21535004, 91753111, 21605097, 21775092, 21390411);the Key Research and Development Program of Shandong Province (2018YFJH0502);the Natural Science Foundation of Shandong Province of China (ZR2016BQ01, ZR2018JL008);the China Postdoctoral Science Foundation (2017M610442)
A novel Ag(Ⅰ)-catalyzed benzylic amination reaction with in situ generation of NH-1,2,3-triazoles for N^2-substituted 1,2,3 triazole scaffolds is described. This protocol is achieved with easily accessible substrate,...
关键词:silver-catalyzed ALKYNES 1 2 3-triazoles AMINATION 
Cu(Ⅱ)-catalyzed aerobic oxidative amidation of azoarenes with amides
《Science China Chemistry》2018年第6期660-663,共4页Gang Li Xiaoting Chen Xulu Lv Chunqi Jia Panpan Gao Ya Wang Suling Yang 
supported by the National Natural Science Foundation of China (21102005);Program for Innovative Research Team of Science and Technology in the University of Henan Province (18IRTSTHN004)
A method for Cu(Ⅱ)-catalyzed dehydrogenative amidation of azoarene using air as the terminal oxidant was developed. Various amides, such as arylamides, alkylamides, lactams, and imides, are all effective amidation re...
关键词:copper C-H activation AMINATION aerobic oxidative azo compounds 
Copper-catalyzed arenes amination with saccharins被引量:1
《Science China Chemistry》2015年第8期1354-1358,共5页Kai Sun Yan Li Qian Zhang 
financially supported by the National Natural Science Foundation of China(21172033,21372041,21302017)
A novel copper-catalyzed direct C–N formation reaction of simple arenes with cheap and pharmacological saccharin derivatives under relatively mild conditions was developed with arenes as limiting reagents.This work p...
关键词:aromatic amines C-N bond formation ARENES saccharins arenes as limiting reagents 
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