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Divergent synthesis of chiral amines via Ni-catalyzed chemo-and enantioselective hydrogenation of alkynone imines: 《Science China Chemistry》2023年第11期3186-3192,共7页Yuchuan Ma Kai Liu Lin He Hui Lv; supported by the National Natural Science Foundation of China (22071188, 21871212);the Open Foundation of CAS Key Laboratory of Molecular Recognition and Function;the “Double First-Class” Project of Shihezi University。; Ligand-mediated nickel-catalyzed asymmetric hydrogenation of alkynone imines has been achieved. By using Ni(OAc)_2·4H_2O/(S,S)-Ph-BPE complex as a catalyst, the chemo-and enantioselective hydrogenation of alkynone im...; 关键词：alkynone imine asymmetric hydrogenation propargyl amine ENANTIOSELECTIVITY chiral amine

Bis(4-methylthio)phenyl)amine-based hole transport materials for highly-efficient perovskite solar cells: insight into the carrier ultrafast dynamics and interfacial transport被引量：1: 《Science China Chemistry》2020年第6期827-832,共6页Xuguang Jia Yi Zhang Jing Zhang Quan Sun Huafei Guo Yikai Wang Shuai Zhang Ningyi Yuan Jianning Ding; supported by the National Key Research and Development Program of China(2017YFB037001);the National Natural Science Foundation of China(91648109、51603021、51602031、51673139);Jiangsu Provincial“333”High-level Talent Training Project;the Priority Academic Program Development of Jiangsu Higher Education Institutions;the Applied Basic Research Program of Changzhou(CJ20190050)。; Hole transport layers(HTLs)play a significant role in the performance of perovskite solar cells.A new class of linear smallmolecules based on bis(4-methylthio)phenyl)amine as an end group,carbon,oxygen and sulfur as t...; 关键词：perovskite solar cell hole transport layer ultrafast carrier dynamics

Enhancement of the efficiency and stability of planar p-i-n perovskite solar cells via incorporation of an amine-modified fullerene derivative as a cathode buffer layer: 《Science China Chemistry》2017年第1期136-143,共8页Xiaodong Liu Peng Huang Qingqing Dong Zhaowei Wang Kaicheng Zhang Hao Yu Ming Lei Yi Zhou Bo Song Yongfang Li; the National Natural Science Foundation of China(21204054,51303118,91333204);the Natural Science Foundation of Jiangsu Province(BK20130289);the Ph.D.Programs Foundation of Ministry of Education of China(20133201120008);the Priority Academic Program Development of Jiangsu Higher Education Institutions;the Scientific Research Foundation for Returned Scholars,Ministry of Education of China;Beijing National Laboratory for Molecular Sciences,State and Local Joint Engineering Laboratory for Novel Functional Polymeric Materials; A methanol-soluble diamine-modified fullerene derivative(denoted as PCBDANI)was applied as an efficient cathode buffer layer(CBL)in planar p-i-n perovskite solar cells(pero-SCs)based on the CH_3NH_3PbI_(3-x)Cl_x absor...; 关键词：planar p-i-n perovskite solar cells cathode buffer layers amine-modified fullerene derivative PCBDANI/LiF double CBLs stability

Recent progress in thin film fluorescent probe for organic amine vapour被引量：4: 《Science China Chemistry》2016年第1期3-15,共13页yanyan fu wei xu qingguo he jiangong cheng; the National Natural Science Foundation of China(61325001,21273267,61321492,51473182);grant from Youth Innovation Promotion Association CAS(2015190);Shanghai Municipal Commission of Economy and Informatization; There are great needs for real-time detection of volatile organic amines(VOA)through low-cost detection methods in public health,food safety,and environmental monitoring area.Organic thin-film fluorescent probe(OTFFP)...; 关键词：fluorescence volatile amine thin-film probe

Unorthodox chemistry for an unorthodox challenge:Exploration of new chemical reactivities for a sustainable future被引量：1: 《Science China Chemistry》2011年第12期1815-1830,共16页LI Chao-Jun; the Canada Research Chair (Tier I) foundation;the E. B. Eddy Endowment Fund;the CFI, NSERC, FQRNT;the NSF and the NSF-EPA Joint Program for a Sustainable Environment for partial support of our research over the years; The sustainable development of our future represents an unorthodox challenge in sciences and technologies.The exploration of unconventional chemical reactivities that could potentially result in more sustainable chemi...; 关键词：green chemistry organometallic reactions in water aldehyde-alkyne-amine coupling cross-dehydrogenative-coupling

One-pot synthesis of hyperbranched poly(amido amine) clicked with a sugar shell via Michael addition polymerization and thiol click reaction被引量：1: 《Science China Chemistry》2010年第8期1663-1668,共6页YU ZhiQiang,CUI MengMeng,YAN JunJie & YOU YeZi CAS Key Lab of Soft Matter Chemistry Department of Polymer Science and Engineering,University of Science and Technology of China,Hefei 230026,China; supported by the National Natural Science Foundation of China (20874093,50973102); This paper reports the production of glycopolymers via a simple and flexible method.A novel glycopolymer with a hyperbranched poly(amido amine) core and a sugar shell (HPAA-GLc) was synthesized by using thiol-ene clic...; 关键词：THIOL-ENE click reaction GLYCOPOLYMERS HYPERBRANCHED poly(amido amine) photoluminescence

Formation of super-concentrated hydrochloric acid in the third phase in tertiary amine N235-PtCl_6^(2-)-HCl system and its influences on the Pt microemulsion extraction被引量：1: 《Science China Chemistry》2009年第11期1825-1834,共10页HUANG Kun1,CHEN Jing1,ZHANG ChengFeng1,2,LI ZhiHong3,PAN QingHua1,SUN Yan1,LIU ShaoXuan1,LIU XueXin2,LI WeiHong1,YANG ZhanLan1,WENG ShiFu1,HU TianDou3,XU YiZhuang1 & WU JinGuang1 1 College of Chemistry and Molecular Engineering,Peking University,Beijing 100871,China 2 Institute of Chemistry,Chinese Academy of Sciences,Beijing 100190,China 3 Institute of High Energy Physics,Chinese Academy of Sciences,Beijing 100049,China; Supported by the National Natural Science Foundation of China (Grant Nos. 50404004, 50673005);China Postdoctoral Science Foundation Funded Project (Grant Nos. 20070410002, 200801007); In this paper,we have investigated the formation of the third-phase in tertiary amine(N235)-PtCl62--HCl system and the microscopic phase structural evolution of platinum-loaded organic phases before and after the occu...; 关键词：solvent EXTRACTION THIRD phase super-concentrated hydrochloric acid TERTIARY AMINE platinum

Small organic amine assisted synthesis of an extra-large pore containing open-framework zinc-cobalt phosphate templated by a chain-type polyamine: 《Science China Chemistry》2009年第9期1485-1489,共5页LI DaiPing SONG HaiBin WANG HongGen LI Niu GUAN NaiJia XIANG ShouHe; Supported by the National Natural Science Foundation of China (Grant No. 20873069);973 Project (Grant No. 2009CB623502); An open-framework zinc-cobalt phosphate CoZnPO4-V with 16-ring extra-large-pore channels has been obtained in the presence of chain-type polyamines as the structure directing agent (SDA). Its large single crystal suit...; 关键词：zinc-cobalt phosphate chain-type polyamines structure directing agent SMALL organic AMINE

Amine-catalyzed polycyclotrimerization of arylene bipropiolate:A metal-free and regioselective route to hyperbranched polymer被引量：3: 《Science China Chemistry》2008年第8期705-708,共4页JIM Cathy K W LAM Jacky W Y HAEUSSLER Matthias; Supported by the Research Grants Council of Hong Kong (Grant Nos. 602707, 602706, HKU2/05C and 603505);the National Science Foundation of China (Grant No. 20634020);the Ministry of Science and Technology of China (Grant No. 2002CD613401).; This paper presents a new synthetic route to hyperbranched polymer. An arylene bipropiolate monomer,dimethylmethylenebis(1,4-phenylene) bipropiolate,was prepared by a one-step esterification reaction of bisphenol A wi...; 关键词：CYCLOTRIMERIZATION regioselectivity HYPERBRANCHED polymer

Synthesis and properties of novel soluble poly(aryl amine ketone)s as high-performance polymers被引量：2: 《Science China Chemistry》2008年第3期275-281,共7页CHANG GuanJun TANG ShiZhen LUO Xuan WANG Qiang XU Zhe ZHANG Lin LIN RunXiong; Supported by the National Natural Science Foundation of China (Grant No. 10576017).; A series of poly(aryl amine ketone)s have been obtained by the condensation polymerization of different aromatic dibromides with different primary aromatic diamines via palladium-catalyzed aryl amination reaction. The...; 关键词：AROMATIC DIBROMIDES AROMATIC diamines palladium-catalyzed poly(aryl AMINE ketone)

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