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AZIDE: 作品数：123被引量：108H指数：5; 导出分析报告; 相关作者：郭松长邹小艳欧育湘李战雄陈博仁更多>>; 相关机构：中国科学院大学青海师范大学中国科学院北京理工大学更多>>; 相关期刊：更多>>; 相关基金：国家自然科学基金国家重点基础研究发展计划中国博士后科学基金广西壮族自治区自然科学基金更多>>

Radical Decarboxylative Cyanomethylation of Aliphatic Carboxylic Acids and Uronic Acids via Vinyl Azide Cascade Fragmentation被引量：2: 《Chinese Journal of Chemistry》2023年第10期1191-1197,共7页Linhua Xu Qishuai Li Dongwei Li Xin Zhou Ni Song Peng Wang Ming Li; support from the National Natural Science Foundation of China(Nos.21977088,21672194);the National Natural Science Foundation of China-Shandong Joint Fund(No.U1906213);the Shandong Provincial National Natural Science Foundation(No.ZR2018MB015).; A direct oxidative radical decarboxylative cyanomethylation of carboxylic acids is described using 3-azido-2-methylbut-3-en-2-ol as the carbon-centered radical acceptor.The transformation is applicable to structurally...; 关键词：CYANIDES Carboxylic acids Carbohydrates Radical decarboxylation Cyanomethylation

Unexpected Electronic Behavior of Organic Azide and Metal-Carbynein Their 1,3-Dipolar Cycloaddition Reaction被引量：1: 《Chinese Journal of Chemistry》2020年第12期1565-1570,共6页Jing-Xuan Zhang Fu Kit Sheong Zhengyu Lu Hong Zhang Zhenyang Lin; We thank the Research Grants Council of Hong Kong(N_HKUST603/15);the NSFC(No.21561162001)for supporting this research.; of main obsevation and conclusion 1,3-Dipolar aycloaddition reaction between organic azide and metal carbyne is a useful strategy to con-struct metallacycles.However,the electronic behavior of organic azide in 1,3-dip...; 关键词：AZIDE POLAR ADDITION

Reactions of Rare-Earth Metal Based Lewis Pairs with Azides被引量：4: 《Chinese Journal of Chemistry》2020年第6期559-564,共6页Yifan Dong Kejian Chang Xin Xu; supported by the National Natural Science Foundation of China(21871204),1000-Youth Talents Plan,and PAPD.; The reactivity of homoleptic rare-earth metal aryloxide based Lewis pairs toward organic azide substrates has been investigated herein.Treatment of RE(OAr)3(RE=La,Sm,X and Sc,Ar=2,6-'Bu2-C6H3),PEt3 and Me3SiN3 in 2:1:...; 关键词：AZIDE RARE complexes

Click Chemistry:Evolving on the Fringe被引量：4: 《Chinese Journal of Chemistry》2020年第4期414-419,共6页Long Xu Jiajia Dong; We acknowledge the National Natural Science Foundation of China(NSFC 21672240,NSFC 25721421002);the Strategic Priority Research Program of the Chinese Academy of Sciences(XDB200203);the Key 258 Research Program of Frontier Sciences(CAS,Grant No.QYZDB-SSWSLH-028);Shanghai Sciences and 259 Technology Committee(18JC1415500,18401933502)for their financial support.; Summary The article herein briefly introduces the story of the birth of click chemistry and its evolution after that.A new angle to interpret click reac-tions was proposed using the"reactivity availability-functionali...; 关键词：FLUORIDE AZIDE herein

Divalent Ytterbium Iodide Supported by β-Diketiminato Based Tridentate Ligand: Synthesis, Structure and Small Molecule Activation被引量：1: 《Chinese Journal of Chemistry》2020年第3期247-253,共7页Xiaojuan Liu Li Xiang Chen Wang Bingwu Wang Xuebing Leng Yaofeng Chen; the National Natural Science Foundation of China(Nos.21602237,21732007,21890721 and 21821002);the Program of Shanghai Academic Research Leader,the Strategic Priority Research Program of the Chinese Academy of Sciences(Grant No.XD20000000);Fujian Institute of In-novation,Chinese Academy of Sciences.; Divalent ytterbium lodide[LYb(μ-I)(THF)]2(1;L=[MeC(NDIPP)CHC(Me)NCH2CH2NMe2]^-,DIPP=2,6-(iPr)2C6H3)was synthesized and its reactivity was studied.Complex 1 was synthesized by salt metathesis of Ybl2(THF)2 with the po...; 关键词：BACKBONE POTASSIUM AZIDE

Design, Synthesis and Antifungal Activity of Benzofuran and Its Analogues被引量：6: 《Chinese Journal of Chemistry》2019年第12期1245-1250,共6页Hang Xu Zhuang Hou Zhen Liang Meng-Bi Guo Xin Su Chun Guo; The authors appreciate the financial supports from the National Natural Science Foundation of China(Nos.81573292 and 81903463);Department of Education of Liaoning Province(2017LQN03);Department of Science and Technology of Liaoning Province(20180540032).; Summary of main observation and conclusion Benzofuran has antifungal activity as the inhibitor of N-myristoyltransferase.Twenty-nine novel benzofuran-semicarbazide hybrids were designed and synthesized by principle of...; 关键词：simplified FURAN AZIDE

Recent Developments in Azide-Free Synthesis of 1,2,3-Triazoles被引量：1: 《Chinese Journal of Chemistry》2017年第12期1797-1807,共11页Zhengkai Chen Gangjian Cao Jinyu Song Hongjun Ren; Acknowledgement We are grateful for the financial support from the National Natural Science Foundation of China （Grant Nos. 21602202）, the Science Foundation of Zhejiang Sci-Tech University （Grant Nos. 15062092-Y, 1206820-Y and 1206821-Y） as well as the Zhejiang Provincial Top Key Academic Discipline of Chemical Engineering and Technology of Zhejiang Sci-Tech University.; 1,2,3-Triazoles, as one of the most significant nitrogen-containing heterocycles due to their extensive use in biology, material science and organic synthesis, have aroused great interest, 1,2,3-Triazoles are commonly...; 关键词：1 2 3-triazoles azide-free HYDRAZONES diazo compounds nitrogen heterocycles

Copper-Catalyzed Three-Component Azidotrifluoromethylation/Difunctionalization of Alkenes: 《Chinese Journal of Chemistry》2014年第9期833-837,共5页Mingbo Yang Wenlu Wang Yin Liu Lijie Feng Xuexia Ju; We thank the Gansu Province Key Laboratory of Fine Chemical(No.1206RTSA022);the Gansu Province Science and Technology Innovation Service Platform Construction Plan(No.1306TTPA024)for financial support.We also acknowledge support from the Gansu Province Containing Fluorine Meticulous Chemicals R&D Platform Project and Program for Pharmaceutical Intermediates Innovation Research Team in Gansu Province(No.1207TTCA009).; A novel three-component strategy for the azidotrifluoromethylation of alkenes has been presented here.The reaction proceeded smoothly under gentle temperature and gave the bifunctional olefins in high yields.Furthermo...; 关键词：azidotrifluoromethylation ALKENES azide-containing

Density Functional Theory Study on （Cl2GaN3）n （n=1 4） Clusters被引量：1: 《Chinese Journal of Chemistry》2011年第9期1817-1823,共7页Xia, Qiying Ma, Dengxue Zhao, Wenwei Xiao, Heming; Project supported by the Shandong Provincial Natural Science Foundation （No. ZR2010BQ034）.; The molecular geometries, vibrational properties, and thermodynamic properties of the clusters （Cl2GaN3）n （n= 1--4） have been predicted at the B3LYP/6-311 ＋G＊ level. The optimized clusters （Cl2GaN3）n （n=2--4...; 关键词：（Cl2GaN3）. （n =1--4） clusters AZIDE density functional theory （DFT） structural feature IR spectra thermodynamics

Reduction of Azide to Amine Using Fe/AlCl3 or Fe/BiCl3 System in Aqueous EtOH: 《Chinese Journal of Chemistry》2006年第6期825-826,共2页郑鹏武段学民王伟王晓季郭玉萍涂其冬; Azides were reduced to the corresponding amines by two new metal/Lewis acid systems in aqueous EtOH with yields ranging from 80% to 95%. The new reduction systems were Fe/AlCl3·6H2O or Fe/BiCl3 system in H2O/ethanol ...; 关键词：AZIDE REDUCTION AMINE AMIDE

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