A[4+4]annulation reaction for the construction of medium-sized N-heterocycles is reported.This process involves the generation of all-carbon 1,4-dipoles containing aπ-allylpalladium complex from Morita-Baylis-Hillman...
Catalysts for CO_(2)value-added conversion have been extensively explored,but there is still a lack of systematic design for catalysts that achieve efficient CO_(2)conversion under mild conditions.Herein,we explored a...
the financial support from the funding for school-level research projects of Yancheng Institute of Technology(No.XJR2022019,XJ201719).
A phosphine-catalyzed [4+3] annulation between dinucleophilic indole derivatives and Morita−Baylis−Hillman (MBH) carbonates was discovered by using the N1 and N4′/C4′ nucleophilicities of the indole precursors,in wh...
This work was supported by the National Science Foundation of Hubei Province of China(No.2019CFB432);the National Natural Science Foundation of China(Nos.22076052 and 21976063);the China Postdoctoral Science Foundation(No.2018M642850).
This study investigated the enhancement effects of dissolved carbonates on the peroxymonosulfate-based advanced oxidation process with CuS as a catalyst.It was found that the added CO_(3)^(2−)increased both the cataly...
supported by the National Key R&D Program of China(2021YFA1501502,2019YFA0210004);Anhui Provincial Key Research and Development Program(2022a05020054);the National Natural Science Foundation of China(21922509,92163105,21905262,T2122004,21890754,U2032212,U2032160);the Strategic Priority Research Program of Chinese Academy of Sciences(XDB36000000);Anhui Provincial Natural Science Foundation(2008085QB88);the Youth Innovation Promotion Association of CAS(Y2021123);the Fundamental Research Funds for the Central Universities(WK2060000039);the University Synergy Innovation Program of Anhui Province(GXXT-2020-005).
Cycloaddition of epoxides with CO_(2) to synthesis cyclic carbonates is an atom-economic pathway for CO_(2) utilization with promising industry application value,while its efficiency was greatly inhibited for the lack...
supports from the National Natural Science Foundation of China(No.21776015);the University Scientific Research Project of Anhui Province(No.KJ2018A0065&KJ2020A0245).
Adsorptive removal of heavy metal ions from wastewater is very important,and the key is the development of efficient sorbents.In this work,oxygenated alkynyl carbon materials(OACMs)were synthesized via mechanochemical...
This work numerically investigates surfactant effects on spontaneous water imbibition in oil-wet carbonates.An open boundary core-scale imbibition model with 9×9×10 gridblocks was used in UTCHEM to simulate carbonat...
financial support from the National Natural Science Foundation of China(No.21602144);the Science and Technology Program of Sichuan Province(No.2018JY0485);Scientific Research Project of Education Department of Hubei Province(Nos.Q20211503,B2020057)。
The utilization of readily available amino acids,which is not only an oxygen nucleophile but also a nitrogen nucleophile,in palladium-catalyzed allylic substitution is realized under mild conditions.The chemoselectivi...
financially supported by the National Natural Science Foundation of China(51802091,51902102,22075074,U21A2081);the Outstanding Young Scientists Research Funds from Hunan Province(2020JJ2004);the Major Science and Technology Program of Hunan Province(2020WK2013);the China Postdoctoral Science Foundation(2020 M672478);the Natural Science Foundation of Hunan Province(2020JJ5035,2021JJ40047,2020JJ5042);the Major Science and Technology Program of Changsha(kq1804010)。
Even though transition metal carbonates(TMCs, TM = Fe, Mn, Co, Ni etc.), show high theoretical capacities, rich reserves and environmental friendliness as anodes for lithium-ion batteries(LIBs), they suffer from slugg...
We are grateful for the financial support from the NSFC(Nos.21931006 and 21921002);the Fundamental Research Funds for the Central Universities.
A solvent-regulated diastereodivergent[3+2]annulation reaction between Morita-Baylis-Hillman carbonates from aryl trifluoromethyl ketones and cyclic sulfonimines is developed under the catalysis of a modified cinchona...