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Radical rejuvenates the click-clip reaction
《Science China Chemistry》2025年第3期803-805,共3页Jiong Zhou Miaomiao Yan Yuanxin Zhang 
With the widespread attention paid to the construction of functional molecular systems,chemical synthesis is increasingly pursuing the accurate and efficient combination and dissociation of molecular units to achieve ...
关键词：INFINITELY nates SYNTHESIS 
Bioactive polypeptide hydrogels modified with RGD and N-cadherin mimetic peptide promote chondrogenic differentiation of bone marrow mesenchymal stem cells被引量：7
《Science China Chemistry》2020年第8期1100-1111,共12页Yan Rong Zhen Zhang Chaoliang He Xuesi Chen 
supported by the National Natural Science Foundation of China(51973218,51622307,21574127,51520105004);the Youth Innovation Promotion Association,Chinese Academy of Sciences。
Cell-material and cell-cell interactions represent two crucial aspects of the regulation of cell behavior.In the present study,poly(L-glutamic acid)(PLG)hydrogels were prepared by catalyst-free click crosslinking via ...
关键词：polypeptide hydrogel click crosslinking BIOFUNCTIONALIZATION 3D cell culture tissue engineering 
Lab-in-cell based on spontaneous amino-yne click polymerization被引量：2
《Science China Chemistry》2019年第9期1198-1203,共6页Rong Hu Xu Chen Taotao Zhou Han Si Benzhao He Ryan T. K. Kwok Anjun Qin Ben Zhong Tang 
supported by the National Natural Science Foundation of China(21788102,21525417,21490571);the National Program for Support of Top-Notch Young Professionals,the Natural Science Foundation of Guangdong Province(2016A030312002,2018A030313763,2019B030301003);the Fundamental Research Funds for the Central Universities(2015ZY013);the Innovation and Technology Commission of Hong Kong(ITC-CNERC14S01)
Unnatural reaction in the living cells is a powerful tool for biological research. However, the polymerization inside cells is rarely reported. In this work, a lab-in-cell is illustrated based on our developed spontan...
关键词：LAB in CELL INTRACELLULAR POLYMERIZATION aggregation-induced emission CELL imaging 
Recyclable Cu nanoparticle catalyzed azide-alkyne click polymerization
《Science China Chemistry》2019年第8期1017-1022,共6页Yizhao Chen Benzhao He Anjun Qin Ben Zhong Tang 
supported by the National Natural Science Foundation of China (21788102, 21525417, 21490571);the National Program for Support of Top-Notch Young Professionals;the Natural Science Foundation of Guangdong Province (2016A030312002);the Fundamental Research Funds for the Central Universities (2015ZY013);the Innovation and Technology Commission of Hong Kong (ITCCNERC14S01)
The Cu(I)-catalyzed alkyne-azide cycloaddition(CuAAC) has been developed into a powerful polymerization reaction for the synthesis of new polytriazoles with versatile properties. However, research on recyclable and re...
关键词：CLICK POLYMERIZATION CU nanoparticles RECYCLABILITY reusability 
Self-healing hyperbranched polytriazoles prepared by metal-free click polymerization of propiolate and azide monomers被引量：1
《Science China Chemistry》2016年第12期1554-1560,共7页Xin Wang Rongrong Hu Zujin Zhao Anjun Qin Ben Zhong Tang 
supported by the National Natural Science Foundation of China(21525417,21490571,21222402);the key project of the Ministry of Science and Technology of China(2013CB834702);the National Program for Support of Top-Notch Young Professionals,the Fundamental Research Funds for the Central Universities(2015ZY013);the Innovation and Technology Commission of Hong Kong(ITC-CNERC14SC01);support from Guangdong Innovative Research Team Program(201101C0105067115)
The last decade has witnessed the quick develop of self-healing materials. As a newborn strategy, the alternative of irreversible covalent bond formation is, however, to be further developed. In this paper, self-heali...
关键词：SELF-HEALING hyperbranched polytriazole metal-free click polymerization film 
An air-stable supported Cu(?) catalyst for azide-alkyne click polymerization
《Science China Chemistry》2015年第11期1748-1752,共5页Haiqiang Wu Wenhui Dong Zongtan Wang Bicheng Yao Ming Chen Jingzhi Sun Anjun Qin Ben Zhong Tang 
supported by the National Natural Science Foundation of China(21490571,21222402,21174120);the Key Project of the Ministry of Science and Technology of China(2013CB834702);the Research Grants Council of Hong Kong(604711,602212,604913);Anjun Qin and Benzhong Tang thank the support from Guangdong Innovative Research Team Program(201101C0105067115)
An air-stable supported Cu(I) catalyst, Cu I@PS-Phen, was designed and synthesized. Cu I@PS-Phen can efficiently catalyze the click polymerization of diynes a and diazides b to produce soluble and thermally stable pol...
关键词：azide-alkyne click polymerization copper residue polytriazole supported Cu（I） catalyst 
Facile synthesis of poly(aroxycarbonyltriazole)s with aggregation-induced emission characteristics by metal-free click polymerization被引量：8
《Science China Chemistry》2011年第4期611-616,共6页LI HongKun MEI Ju WANG Jian ZHANG Shuang ZHAO QiuLi WEI Qiang QIN AnJun SUN JingZhi TANG Ben Zhong 
supported by the National Natural Science Foundation of China (20634020,50703033,20974098 and 20974028);the Ministry of Science and Technology of China (2009CB623605);the University Grants Committee of Hong Kong ( AoE/P-03/08);the Research Grants Council of Hong Kong (603509,601608 and 602707);the Innovation and Technology Fund of Hong Kong (ITS/168/09). A.J.Q. and B.Z.T acknowledge the supports from the Postdoctoral Research Foundation of China (20081461);the Fundamental Research Funds for the Central Universities (2010KYJD005);the CAO GuangBiao Foundation of Zhejiang University,respectively
Regioseletive 1,3-dipolar polycycloadditions of 4,4'-isopropylidenediphenyl dipropiolate (1) and tetraphenylethene (TPE)-containing diazides (2) are carried out in polar solvents such as DMF/toluene at a moderate temp...
关键词：aggregation-induced emission metal-free click polymerization propiolate chemosensor 
Crosslinking of viral nanoparticles with “clickable” fluorescent crosslinkers at the interface被引量：1
《Science China Chemistry》2010年第6期1287-1293,1459,共8页KAUR Gagandeep BARNHILL Hannah 
We are grateful for the support from the US NSF CAREER Award (CHE-0748690);US DoD–ARO (W911NF-09-1-0236), US DoE;the W. M. Keck Foundation;the Camille Dreyfus Teacher-Scholarship;the Alfred P. Sloan Foundation;the National Natural Science Foundation of China (50673025);the National Basic Research 973 Program (2006CB806200)
Cu (I) catalyzed alkyne-azide cycloaddition (CuAAC) reaction,a typical "click" reaction,is one of the modular synthetic approaches which has been broadly used in various organic syntheses,medicinal chemistry,materials...
关键词：PICKERING emulsion CROSSLINKING NANOPARTICLES CUAAC reaction CLICK chemistry interfacial assembly 
Modular synthesis of a block copolymer with a cleavable linkage via “click” chemistry被引量：1
《Science China Chemistry》2010年第5期1127-1132,共6页Fu, Yu  Liu, GuoJun 
the National Natural Science Foundation of China (20704003 & 20974017);Open Project of State Key Laboratory of Supramolecular Structure and Materials(SKLSSM 200906)
A diblock copolymer poly(ethylene glycol)-block-polystyrene or PEG-b-PS with an olefinic double bond at the PEG and PS junction has been prepared by modular synthesis via"click"chemistry.This involved the synthesis of...
关键词：MODULAR synthesis cleavable block COPOLYMER CLICK chemistry ATRP 
Bioorthogonal chemistry:a covalent strategy for the study of biological systems被引量：2
《Science China Chemistry》2010年第1期61-70,共10页LIM Reyna K.V. 
supported by the US National Institutes of Health (R01 GM085092) and New York State Center of Excellence in Bioinformatics and Life Sciences
The development of genetically encoded,wavelength-tunable fluorescent proteins has provided a powerful imaging tool to the study of protein dynamics and functions in cellular and organismal biology.However,many biolog...
关键词：bioorthogonal reaction proteins biotechnology 1 3-dipolar CYCLOADDITION CLICK CHEMISTRY TETRAZOLE 
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