financial support provided by the National Natural Science Foundation of China(NSFC,grant nos.92156025 and 22271212);the National Key Research and Development Program of China(grant nos.2019YFA0905100 and 2021YFF0701700);X.T.thanks the China Postdoctoral Science Foundation(grant no.2022M712350).
Given the widespread applications of fluorinated substances in pharmaceuticals,biology,and materials,the development of fluorine-containing building blocks remains an important topic in organic chemistry.In the repert...
supported by the National Natural Science Foundation of China(21701059,51902140 and 52102100);the Natural Science Foundation of Jiangsu Province for Youths(BK20170571).
In this work,we report a novel one-dimensional metal-organic framework(MOF)templated for the synthesis of transition metal sulfides with excellent oxygen evolution reaction(OER)performance via a self-sulfidation proce...
projects of National Natural Science Foundation of China (Grant Nos.22175025 and 21905023) for their generous financial support。
The high energy coordination compounds Cu(TZCA)_(2)(ClO_(4))_(2)(ECCs-1) was prepared by 1H-tetrazole-5-carbohydrazide(TZCA) with a high energy skeleton and a strong coordination ability group.At the same time,the rea...
supported by the National Natural Science Foundation of China(Grant No.21875110,22075143);the Science Challenge Project;the Qing Lan Project for the grant。
In recent years,the introduction of fused rings own high density and low sensitivity has promoted the development of energetic materials.However,the development of energetic compounds containing fused and bridged ring...
the financial support from the National Natural Science Foundation of China(No.22175033);Science and Technology Development Plan of Jilin Province(Nos.YDZJ202101ZYTS063,2021050822RQ)。
Solid-state materials that exhibit pressure stimulus-response characteristics in a manner of emission signal,known as piezochromic luminescence(PCL),demonstrate great potential in photoelectric devices.The weakened lu...
financial support and the necessary facilities for this study by the Ecole Militaire polytechnique and the Ludwig-Maximilian University of Munich(LMU)。
In this research,a promising class of insensitive and high-energy dense biopolymers,which contain nitrogen-rich 1H-tetrazol-1-yl acetate and nitrate ester functional groups,was successfully synthesized through tetrazo...
We are thankful to the NSAF(No.U1830134);NSFC(No.21905023 and 22175025);State Key Laboratory of Explosion Science and Technology(No.YBKT21-02);Open Research Fund Program of CAS Key Laboratory of Energy Regulation Materials(No.ORFP2020-01)for their generous financial support.
This review covers recent advances in the synthesis and energetic performance of nitrogen-rich 1,2,4-oxadiazole-azoles-based energetic materials.These materials comprise of 1,2,4-oxadiazole subunit as a key structural...
supported by National Key Research and Development Project (No. 2021YFC2100100);National Natural Science Foundation of China (No. 21901123);Natural Science Foundation of Jiangsu Province (No. BK20190694);Jiangsu Specially Appointed Professor Plan
The Beckmann rearrangement has been predominantly studied for the synthesis of amide and lactam.By strategically using the in situ generated Appel’s salt or Mitsunobu’s zwitterionic adduct as the de-hydrating agent,...
supported by the National Natural Science Foundation of China (Nos.21772142,21901181 and 21961142015);the National Key Research and Development Program of China (No.2019YFA0905100);Tianjin Municipal Science & Technology Commission (No.19JCQNJC04700);the CNRS in France。
Three bench-stable difluoromethylene phosphonate hydrazones were prepared from simple diethyl(difluoromethyl)phosphonate within two steps in good yields. The [3 + 2] cycloaddition reaction of these diazo precursors wi...
supported by the“Fundamental Research Funds for Central Universities”(No.1191329135);the Key Laboratory Construction Program of Xi’an Municipal Bureau of Science and Technology(No.201805056ZD7CG40);the starting fund of Xi’an Jiao Tong University(No.7121182002).
Based on palladium-catalyzed allylic amination reaction,the first general example of enantioselective formation of a tetrazole-bearing quaternary stereocenter has been developed.The protocol uses ambivalent tetrazole ...