相关期刊:《Chemical Research in Chinese Universities》《Chinese Journal of Chemistry》《International Journal of Organic Chemistry》《Chinese Chemical Letters》更多>>
supported by National Key Research and Development Project (No. 2021YFC2100100);National Natural Science Foundation of China (No. 21901123);Natural Science Foundation of Jiangsu Province (No. BK20190694);Jiangsu Specially Appointed Professor Plan
The Beckmann rearrangement has been predominantly studied for the synthesis of amide and lactam.By strategically using the in situ generated Appel’s salt or Mitsunobu’s zwitterionic adduct as the de-hydrating agent,...
Guangdong Medical College(No.XK1110)for financial support
We present here an efficient green process for the synthesis of 1,2,4-thiadiazoles via iodine-catalyzed,oxidative dimerization of thioamides in water using molecular oxygen as a terminal oxidant. Under the optimized r...
The efficient dehydrosulfurization of thioamides to nitriles was carried out using indium(III) triflate as a catalyst. Based on the results of the initial study, the optimal reaction conditions required 5 mol% of indi...
Ketones smoothly reacted with NBS in the presence of a catalytic amount of ptoluenesulfonic acid to give α-bromoketones in good yields in typical ionic liquids, such as [bmim]PF6 and [bmpy]Tf2N, and the ionic liquids...
Antimony(III) complexes of thioamides [thioamides=thiourea (Tu), N,N'dimethylthiourea (Dmtu), tetramethylthiourea (Tmtu), imidazolidine-2-thione (Imt) and diazinane-2-thione (Diaz)] with the general formu...
The title compound, 2-(methoxybenzoyl)-N-phenyl-2-(1,2,4-triazol-1-yl)thioacetamide was synthesized by several reactions from 4-methoxyacetophenone, triazole and phenyl isothiocyanate. The structure was identified by ...