the National Key Research and Development Projects of China(Grant No.2019YFA0308500);the National Natural Science Foundation of China(Grant No.61888102);the Funds from the Chinese Academy of Sciences(Grant Nos.XDB30000000 and YSBR-003)。
Furazan macrocyclic compound 3,4:7,8:11,12:15,16-tetrafurazan-1,9-dioxazo-5,13-diazocyclohexadecane(DOATF)is an ideal energetic material with high heat of formation.Here,using scanning tunneling microscopy(STM)and non...
We are thankful to the NSAF(No.U1830134);NSFC(No.21905023 and 22175025);State Key Laboratory of Explosion Science and Technology(No.YBKT21-02);Open Research Fund Program of CAS Key Laboratory of Energy Regulation Materials(No.ORFP2020-01)for their generous financial support.
This review covers recent advances in the synthesis and energetic performance of nitrogen-rich 1,2,4-oxadiazole-azoles-based energetic materials.These materials comprise of 1,2,4-oxadiazole subunit as a key structural...
the Opening Project of State Key Laboratory of Explosion Science and Technology(Beijing Institute of Technology)(No.KFJJ20-03M);Doctoral Foundation of SWUST(No.17zx7128);Major Special Projects of the Equipment Development Department of the Central Military Commission of China(No.14021001040305-5)。
In this paper,eight 4-(1,2,4-triazole-5-yl)furazan(TZFZ)derivatives were designed,and the molecular configurations of TZFZ compounds were optimized by using the B3LYP/6-311+G*level.Meanwhile,the detonation performance...
financial support from the financial support from the National Natural Science Foundation of China(Nos.21805223 and 21805226);the China Postdoctoral Science Foundation(No.2018M633552);the China Scholarship Council(No.201805290006)。
Furazan and furoxan represent fascinating explosophoric units with intriguing structures and unique properties.Compared with other nitrogen-rich heterocycles,most poly furazan and furoxan-based heterocycles demonstrat...
Supported by the National Natural Science Foundation of China(No.21241003);the Natural Science Foundation of Shaanxi Province,China(No.2018JM2061).
The structure of 4-amino-3-(5-tetrazolate)-fiirazan(HAFT) was characterized by single crystal X-ray diffraction. The thermal decomposition process of HAFT was investigated by MS-FTIR-DSC-TG coupling technique. The res...
financial assistance from the National Natural Science Foundation of China(No.21241003);the Natural Science Basic Research of Shaanxi Province(No.2018JM2061);the Northwest University Graduate Innovation and Creativity Funds(No.YZZ17145)
A new coordination compound of Zn(NH3)3(AFT)2(1,ZnC6H13N17O2,AFT =4-amino-3-(5-tetrazolate)-furazan)was synthesized and characterized by elemental analysis and FT-IR spectrum.Its crystal structure was determined by X-...
Some nitro-substituted triazole-furazan derivatives are considered as potential candidates for high energy density compounds through quantum chemical treatment. Their geometric and electronic structures,band gap,therm...
An energetic salt of bis(l,5-diamino-lH-tetrazolium)3,3"-bis(nitramino)-4, 4x-azo- furazan (C6H10N2206) was synthesized with the total yield of 61.7% by using 3,4-diaminofurazan (DAF) as the starting material...
An acylation method of 3,4-diaminofurazan was developed. Under the catalysts of p-Tolu- enesulfonic acid, 3-amino-4-formylaminofurazan, 3-amino-4-acetylaminofurazan, 3-amino-4-propio- nylaminofurazan, 3-amino-4-butylr...
A sensitive, simple and selective high-performance liquid chromatographic (HPLC) method was developed for the determination of ciprofloxacin in biological fluids. The method is based on the reaction between the drug...