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Transition-Metal-Mediated Fluoroalkylation of Carbon Electrophiles through Cross-Electrophile Couplings
《Chinese Journal of Chemistry》2024年第24期3499-3517,共19页Yun-Cheng Luo Xingang Zhang 
supported by the National Natural Science Foundation of China(21931013,21991122);the National Key R&D Program of China(2021YFF0701700);the Strategic Priority Research Program of the Chinese Academy of Sciences(XDB0590000);the Science and Technology Commission of Shanghai Municipality(22JC1403500,21XD1404400).
Organofluorine compounds have attracted substantial interest in life and materials sciences due to the unique properties of fluorine atom(s)that often change the physicochemical and biological properties of organic mo...
关键词：FLUOROALKYLATION Cross-electrophile coupling Dicarbofunctionalization Copper Nickel catalysis 
Cross-Electrophile Couplings(XECs)between Similar Electrophile Reagents
《Chinese Journal of Chemistry》2024年第24期3518-3532,共15页Jie Lei Shan Yu Zhi-Gang Xu 
the Science and Technology Research Program of Chongqing Municipal Education Commission(KJQN202001338 and KJQN202101340);the Natural Science Foundation Project of CQ CSTSC(cstc2020jcyj-msxmX0733 and cstc2021jcyj-bsh0233).
Cross-electrophile couplings(XEC),a crucial subset of cross-coupling reactions,center on the formation of robust C—C bonds through the union of two electrophiles.Usually,such reactions have primarily been catalyzed b...
关键词：Cross-electrophile coupling(XEC) PHOTOCHEMISTRY Electrochemistry ELECTROPHILE C-C bond formation Synthetic methods CROSS-COUPLING Nickel 
Stereoselective Synthesis of C-Vinyl Glycosides via Nickel-Catalyzed Cross-Electrophile Couplings of 1,2-Glycosyl Orthoesters and Vinyl Halides
《Chinese Journal of Chemistry》2024年第23期3029-3034,共6页Xin Wang Anrong Chen Shiyin Zhao Qiang Tao Bo Yang Xing Zhang Feng Zhu 
sponsored by the National Key R&D Program of China(Grant No.2023YFA1508800);National Natural Science Foundation of China(Grant No.22301178);Shanghai Pilot Program for Basic Research-Shanghai Jiao Tong University(Grant No.21TQ1400210);Fundamental Research Funds for the Central Universities(Grant No.22x010201631);the Open Grant from the Pingyuan Laboratory(2023PY-OP-0102);Excellent Young Scientists Fund Program(Overseas);Natural Science Foundation of Shanghai(Grant No.21ZR1435600).
A highly stereoselective nickel-catalyzed cross-electrophile coupling of readily accessible,novel,stable oxygen-based glycosyl radical precursors,specifically 1,2-glycosyl orthoesters,is developed.This approach offers...
关键词：Glycosylation Nickel catalysis Cross-electrophile couplings 1 2-Glycosyl orthoesters C-C coupling STEREOCHEMISTRY 
Thermocatalytic Dehydrogenation-Enabled Arene-Alkane Couplings
《Chinese Journal of Chemistry》2023年第16期1905-1914,共10页Feng Yu Renqing Tao Lan Gan Hao Ni Qi-Kai Kang Guixia Liu Zheng Huang 
the National Key R&D Program of China(2021YFA1501700);the National Natural Science Foundation of China(21825109,21821002,22072178,22293013).
Comprehensive Summary The direct use of non-prefunctionalized arene and alkane as the starting materials to construct Caryl−Calkyl bond is an unfulfilled target and approaches to this challenge rarely surface in metho...
关键词：ALKANES ARENES Dehydrogenative coupling HYDROARYLATION lridium 
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