CU(I)

作品数:71被引量:156H指数:5
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相关领域:理学更多>>
相关作者:潘志权陈云峰马姗陈绍云沈鸿云更多>>
相关机构:大连理工大学汕头大学武汉工程大学中国科学院更多>>
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相关基金:国家自然科学基金国家重点基础研究发展计划天津市教委科研基金湖北省自然科学基金更多>>
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Temperature-dependent self-trapped exciton emission in Cu(I) doped zinc-based metal halides from well-resolved excited state structures
《Nano Research》2024年第8期7768-7775,共8页Yunlong Bai Shuai Zhang Nengneng Luo Bingsuo Zou Ruosheng Zeng 
supported by the National Natural Science Foundation of China(Nos.22175043 and 52162021);Guangxi Science and Technology Plan Project(No.Guike AA23073018);supported by the high-performance computing platform of Guangxi University。
Zero-dimensional metal halides are of unique structures and tunable photoluminescence properties,showing great potential applications such as light-emitting diodes(LEDs)and sensing.Herein,we successfully synthesized C...
关键词:sky-blue emission self-trapped exciton metal halides excited state structures temperature sensor 
An anthraquinone-based Cu(I) cyclic trinuclear complex for photo-catalyzing C–C coupling reactions被引量:1
《Science China Chemistry》2023年第12期3525-3531,共7页Yu-Mei Wang Kai-Ming Mo Xiao Luo Ri-Qin Xia Jing-Yi Song Guo-Hong Ning Dan Li 
Guo-Hong Ning is thankful for the support from the Guangdong Basic and Applied Basic Research Foundation (2019B151502024);the Guangzhou Science and Technology Project (202201020038);supported by the National Natural Science Foundation of China (22371091, 21975104, 22150004, 22101099);the Guangdong Major Project of Basic and Applied Research (2019B030302009)。
Development of transition metal-based photocatalysts with low cost, strong visible light absorption, and high efficiency is a longstand pursuit for advanced organic synthesis, yet remains highly challenging. In this a...
关键词:cyclic trinuclear complex PHOTOCATALYSIS C–C coupling reaction 
Cu(I)/TEMPO体系催化空气氧化苄醇——一个有机化学综合实验设计
《大学化学》2023年第11期195-205,共11页奉强 王思宇 李倩意 王晓月 何冰 
四川省科技计划资助(2023NSFSC0101);四川省大学生创新创业项目(S202114389166)。
苄醇氧化制备苯甲醛在有机化学教学中占有重要地位,但其易于操作的合成方法常因环境不友好而难以进入大学有机化学基础实验教学课堂。本文介绍一个有机化学综合实验,以氯化亚铜、2,2’-联吡啶(bpy)、N-甲基咪唑(NMI)和2,2,6,6-四甲基哌...
关键词:有机化学综合实验 空气氧化 芳香醛 结构表征 
基于半刚性咪唑羧酸配体构筑的Cu(I)有机骨架材料:合成、晶体结构和性质
《人工晶体学报》2023年第10期1836-1841,共6页潘会宾 吴婷婷 高霞 卢久富 
国家自然科学基金(22003037);陕西高校青年创新团队(2022-94)。
在溶剂热条件下,利用半刚性咪唑羧酸配体4-(2-甲基咪唑)苯甲酸和金属铜合成了一种新的Cu(I)配位聚合物[Cu(H_(2)O)(MIBA)]n,其中HMIBA代表有机化合物4-(2-甲基咪唑)苯甲酸。在室温条件下,研究了基于半刚性咪唑羧酸配体构筑的Cu(I)有机...
关键词:Cu(I)配位聚合物 半刚性咪唑羧酸配体 溶剂热法 拓扑结构 X射线衍射 荧光性能 
Cu(I)负载活性炭的制备及其一氧化碳吸附性能研究
《当代化工》2023年第6期1323-1327,共5页胡方舟 梁峰 张胜中 范得权 张延鹏 杨阳 
中国石化重点科技项目,氢气纯化关键技术提升与应用,子课题1—氢气纯化过程关键材料性能改进及机理研究(项目编号:112103)。
以活性炭原粉和氯化亚铜为原料,利用单层分散原理制备了Cu(I)负载一氧化碳活性炭吸附剂,探究了分散条件对分散效果的影响,不同碘值活性炭的分散阈值以及二次负载对吸附性能的影响。结果表明:300℃、1.5 h下CuCl的分散效果最佳;CuCl分散...
关键词:活性炭 单层分散 分散阈值 氯化亚铜 一氧化碳 
Structural Isomerization in Cu(I)Clusters:Tracing the Cu Thermal Migration Paths and Unveiling the Structure-Dependent Photoluminescence被引量:1
《CCS Chemistry》2023年第2期350-360,共11页Xi Fan Furong Yuan Jiaqi Wang Zhibin Cheng Shengchang Xiang Huayan Yang Zhangjing Zhang 
supported by the National Natural Science Foundation of China(grant nos.22101048,22005054,and 21975044);the Natural Science Foundation of Fujian Province(grant no.2021J01150).
Revealing structural isomerization in metal clusters would bridge a huge structural gap between small molecular isomerization and solid–solid phase transformation.However,genuine structural isomerism in metal cluster...
关键词:cluster compounds metal clusters structural isomerism isomeric transformation structure–property relationships 
The synthesis of tetracyclic coumarins via decarboxylative asymmetric[4+2]cycloadditions enabled by Pd(0)/Cu(I)synergistic catalysis
《Chinese Journal of Catalysis》2022年第7期1812-1817,共6页Kai Wang Xiangfeng Lin Qian Li Yan Liu Can Li 
国家自然科学基金(21871254);大连化物所自主部署基金(DICP ZZBS201602);中国科学院王宽诚率先人才计划(GJTD-2020-08).
Tetracyclic coumarins are a class of important compounds with diverse and superior pharmacolog‐ical activities.However,a direct stereoselective method from simple and readily‐made coumarins derivatives remains chall...
关键词:Synergistic catalysis Pd(0)/Cu(I)catalysis Asymmetric catalysis [4+2]Cycloaddition Tetracyclic coumarins Chiral catalysis 
Is the metal involved or not? A computational study of Cu(I)-catalyzed [4+1] annulation of vinyl indole and carbene precursor
《Chinese Chemical Letters》2022年第4期2031-2035,共5页Xiaoqian He Kangbao Zhong Dan Heng Zhen Zeng Hao Ni Ruopeng Bai Yu Lan 
supported by the National Natural Science Foundation of China (Nos. 21822303, 21772020 and 22003006);a project (No. 2018CDXZ0002) supported by the Fundamental Research Funds for the Central Universities (Chongqing University);supported by the Graduate Research and Innovation Foundation of Chongqing,China (No. CYB20045)。
The Cu(I)-catalyzed [4 + 1] annulation of vinyl indoles and a carbene precursor is a powerful method for constructing cyclopentaindole derivatives. Density functional theory(DFT) calculations were used to elucidate th...
关键词:Carbene precursor Regioselectivity DFT calculations Cyclopentaindol C3-alkylation 
A Top-Down Approach towards Cu(I)Alkynyl Clusters with Unusual Geometry被引量:1
《Chinese Journal of Chemistry》2021年第4期937-941,共5页Huan Li Ting Li Shuimiao Liu Mei Qu Linfeng Liang Fengwei Zhang Xian-Ming Zhang 
the National Natural Science Foundation of China(Nos.21972080,21503123,91961201,21871167);1331 project for Featured Chemistry Discipline in Shanxi Normal University.
Main observation and conclusion To search for novel Cu(I)complexes,traditional approaches focus on designing and screening ligands,metal precursors and reaction parameters.In this report,we propose a top-down approach...
关键词:Copper TOP-DOWN Cluster FLUORESCENCE ALKYNYL 
Rapid Access to Oxabicyclo[2.2.2 ]octane Skeleton through Cu(I)- Catalyzed Generation and Trapping of Vinyl-o-quinodimethanes (Vinyl-0-QDMs)
《Chinese Journal of Chemistry》2020年第10期1052-1056,共5页Hejiang Luo Chuan He Huanfeng Jiang Shifa Zhu 
We appreciate financial support from Ministry of Science and Technology of the People's Republic of China(2016YFA0602900);the National Natural Science Foundation of China(21871096,21672071);Guangdong Science and Technology Department(20188030308007,2018A030310359,2016A030310433);the Science and Technology Program of Guangzhou(201707010316,201707010168).
Summary of main observation and conclusion A Cu(I)-catalyzed three-component reaction of terminal enynals/enynones,diazo compounds,and al kenes has been developed.With this method,a series of oxabicyclo[2.2.2]octanes ...
关键词:OCTANE ETHANE SKELETON 
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