This Highlight is inspired by a recent article in Science in which Gong and co-workers from Tianjin University reported a discovery of defective TiOx overlayers on metallic Ni nanoparticles induced by strong metal-sup...
supported by Tsinghua University(Initiative Scientific Research Program 20211080079);the National Natural Science Foundation of China(21972161,22172186);Chinese Academy of Sciences(CAS)Pioneer Talents Program(2018-095);Shanxi Talent Program(2019SBRJH01);Autonomous Research Project of State Key Laboratory of Coal Conversion(SKLCC)(2020BWZ006,2021BWZ007);Institute of Coal Chemistry(ICC)Innovation Fund(SCJJ-2020-02);Inner Mengolia Science&Technology Project Plan(2021GG0311);Major science and technology project of Ordos(2022EEDSKJZDZX001);Start-Up Grant of Institute of Coal Chemistry(2020SC001);Synfuels China Co.,Ltd.
Long-chain alkanes are abundant feedstocks supplied by natural resources and chemical industry. Specially, normal long-chain alkanes are primary products from Fischer-Tropsch synthesis(FTS) process, which is an import...
supported by the National Natural Science Foundation of China(21422104);the Natural Science Foundation of Tianjin City(17JCJQJC44700,16JCZDJC30600)
The development of a facile strategy to construct stable hierarchal porous heterogeneous photocatalysts remains a great challenge for efficient CO2 reduction.Additionally,hole-trapping sacrificial agents(e.g.,triethan...
supported by the National Natural Science Foundation of China(21472094,21772096,21577071);Natural Science Foundation of Tianjin(14JCZDJC40300,17JCYBJC20300)
Koser's reagent is found to be effective in the oxidative double dehydrogenation of various carbocyclic β-dicarbonyl compounds,which constitutes the first example on dehydrogenation reactivity of hypervalent iodine(...
supported by the National Natural Science Foundation of China(21333003,21622305);Young Elite Scientist Sponsorship Program by China Association for Science and Technology(YESS20150131);"Shu Guang"project supported by Shanghai Municipal Education Commission and Shanghai Education Development Foundation(13SG30);the Fundamental Research Funds for the Central Universities(WJ616007)
Indium oxide(In_2O_3) has demonstrated to be an effective non-noble metal catalyst for methanol steam reforming reaction(MSR).However, the reaction mechanism of MSR and crucial structure-activity relations determining...
supported by the Recruitment Program of Global Youth Experts of China, Chinese Academy of Sciences (KJCX2.YW.H30);the National Natural Science Foundation of China (21533011, 21321063)
In this work, we fabricated the poly(N-vinyl-2-pyrrolidone) (PVP)-stabilized ruthenium(0) nanoclusters by reduction of RuC13 using different reducing agents, and studied their catalytic activity in hydrogen gene...
supported by the National Basic Research Program (2012CB215306);the National Natural Science Foundation of China (21325208, 21361140372, 21572212);Chinese Academy of Sciences (KFJ-EW-STS-051);Fundamental Research Funds for the Central Universities (WK2060190025);Scientific research funds of Anhui University (J10117700074)
Extracting hydrogen from methanol is a safe and cost-efficient strategy for fuel supply. This process was realized recently at a mild condition with excellent efficiency by ruthenium pincer catalysts. Despite the expe...
financially supported by the National Basic Research Program of China(2015CB856600);the National Natural Science Foundation of China(21422209,21432011,21421091)
A novel hydrido iridium chloride complex supported by a tetradentate PNCP ligand has been synthesized and characterized. Upon activation with NaOtBu, the PNCP-IrHC1 complex is active for transfer dehydrogenation of cy...
financially supported by the National Natural Science Foundation of China(U1232120,21273229);the Australian Research Council Discovery Early Career Research Award(DE120101496)
Tremendous efforts have been devoted to the synthesis of new light element hydrides for hydrogen storage. Ammonia borane (AB) is a promising candidate possessing high hydrogen capacity and low dehydrogenation temper...
supported by the National Natural Science Foundation of China (20971132);the Natural Science Foundation of Chongqing City (CSTC2009BB4243);the Foundation of Chongqing Municipal Education Commission (KJ090810,KJ070809)
Using the plane wave ultrasoft pseudopotential method based on the first-principles density functional theory(DFT),the influence on the electronic structure and dehydrogenation properties of VH2 doped with Zr,Cu and Z...