DEHYDROGENATION

作品数:258被引量:471H指数:9
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相关领域:理学更多>>
相关作者:杨新征李伟作郭新闻王小丽魏晓伟更多>>
相关机构:中国科学院中航工业北京航空制造工程研究所西华大学大连理工大学更多>>
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相关基金:国家自然科学基金中国博士后科学基金国家重点基础研究发展计划天津市自然科学基金更多>>
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Sustainable propane dehydrogenation reaction triggered by strong metal-support interaction
《Science China Chemistry》2025年第2期411-413,共3页Lichen Liu Avelino Corma 
This Highlight is inspired by a recent article in Science in which Gong and co-workers from Tianjin University reported a discovery of defective TiOx overlayers on metallic Ni nanoparticles induced by strong metal-sup...
关键词:DEHYDROGENATION PROPYLENE INTERACTION 
Solid catalysts for the dehydrogenation of long-chain alkanes:lessons from the dehydrogenation of light alkanes and homogeneous molecular catalysis被引量:6
《Science China Chemistry》2022年第11期2163-2176,共14页Hongliu Wan Nengfeng Gong Lichen Liu 
supported by Tsinghua University(Initiative Scientific Research Program 20211080079);the National Natural Science Foundation of China(21972161,22172186);Chinese Academy of Sciences(CAS)Pioneer Talents Program(2018-095);Shanxi Talent Program(2019SBRJH01);Autonomous Research Project of State Key Laboratory of Coal Conversion(SKLCC)(2020BWZ006,2021BWZ007);Institute of Coal Chemistry(ICC)Innovation Fund(SCJJ-2020-02);Inner Mengolia Science&Technology Project Plan(2021GG0311);Major science and technology project of Ordos(2022EEDSKJZDZX001);Start-Up Grant of Institute of Coal Chemistry(2020SC001);Synfuels China Co.,Ltd.
Long-chain alkanes are abundant feedstocks supplied by natural resources and chemical industry. Specially, normal long-chain alkanes are primary products from Fischer-Tropsch synthesis(FTS) process, which is an import...
关键词:long-chain alkanes catalytic dehydrogenation α-olefins subnanometric cluster ZEOLITE 
Integrating photocatalytic reduction of CO2 with selective oxidation of tetrahydroisoquinoline over InP–In2O3 Z-scheme p-n junction被引量:3
《Science China Chemistry》2020年第1期28-34,共7页Bohang Zhao Yi Huang Dali Liu Yifu Yu Bin Zhang 
supported by the National Natural Science Foundation of China(21422104);the Natural Science Foundation of Tianjin City(17JCJQJC44700,16JCZDJC30600)
The development of a facile strategy to construct stable hierarchal porous heterogeneous photocatalysts remains a great challenge for efficient CO2 reduction.Additionally,hole-trapping sacrificial agents(e.g.,triethan...
关键词:CO2 reduction DEHYDROGENATION photocatalysis Z-scheme TETRAHYDROISOQUINOLINE 
Double dehydrogenation of carbocyclic β-dicarbonyl compounds:Koser's reagent can do what iodine(V) reagents can
《Science China Chemistry》2019年第5期597-601,共5页Shan-Shan Liu Li Wang Ya-Nan Duan Ao Yu Chi Zhang 
supported by the National Natural Science Foundation of China(21472094,21772096,21577071);Natural Science Foundation of Tianjin(14JCZDJC40300,17JCYBJC20300)
Koser's reagent is found to be effective in the oxidative double dehydrogenation of various carbocyclic β-dicarbonyl compounds,which constitutes the first example on dehydrogenation reactivity of hypervalent iodine(...
关键词:Koser’s REAGENT DOUBLE DEHYDROGENATION HYPERVALENT twisting 2 3-benzotropone DFT calculations 
Theoretical insight into methanol steam reforming on indium oxide with different coordination environments被引量:2
《Science China Chemistry》2018年第3期336-343,共8页Jinglin Wang Haifeng Wang P.Hu 
supported by the National Natural Science Foundation of China(21333003,21622305);Young Elite Scientist Sponsorship Program by China Association for Science and Technology(YESS20150131);"Shu Guang"project supported by Shanghai Municipal Education Commission and Shanghai Education Development Foundation(13SG30);the Fundamental Research Funds for the Central Universities(WJ616007)
Indium oxide(In_2O_3) has demonstrated to be an effective non-noble metal catalyst for methanol steam reforming reaction(MSR).However, the reaction mechanism of MSR and crucial structure-activity relations determining...
关键词:steam reforming reaction DFT In2O3 (211) reaction mechanism DEHYDROGENATION structure-activity relation 
N-vinyl pyrrolidone promoted aqueous-phase dehydrogenation of formic acid over PVP-stabilized Ru nanoclusters
《Science China Chemistry》2016年第10期1342-1347,共6页Hangyu Liu Qingqing Mei Yanyan Wang Huizhen Liu Buxing Han 
supported by the Recruitment Program of Global Youth Experts of China, Chinese Academy of Sciences (KJCX2.YW.H30);the National Natural Science Foundation of China (21533011, 21321063)
In this work, we fabricated the poly(N-vinyl-2-pyrrolidone) (PVP)-stabilized ruthenium(0) nanoclusters by reduction of RuC13 using different reducing agents, and studied their catalytic activity in hydrogen gene...
关键词:carbon dioxide NVP RUTHENIUM dehydrogenation of formic acid 
A self-catalytic role of methanol in PNP-Ru pincer complex catalysed dehydrogenation
《Science China Chemistry》2016年第6期724-729,共6页Yuan-Ye Jiang Zheng-Yang Xu Hai-Zhu Yu Yao Fu 
supported by the National Basic Research Program (2012CB215306);the National Natural Science Foundation of China (21325208, 21361140372, 21572212);Chinese Academy of Sciences (KFJ-EW-STS-051);Fundamental Research Funds for the Central Universities (WK2060190025);Scientific research funds of Anhui University (J10117700074)
Extracting hydrogen from methanol is a safe and cost-efficient strategy for fuel supply. This process was realized recently at a mild condition with excellent efficiency by ruthenium pincer catalysts. Despite the expe...
关键词:DEHYDROGENATION RUTHENIUM pincer ligand METHANOL density functional theory 
Synthesis and characterization of a tetradentate PNCP iridium complex for catalytic alkane dehydrogenation被引量:1
《Science China Chemistry》2015年第8期1340-1344,共5页Xiangqing Jia Zheng Huang 
financially supported by the National Basic Research Program of China(2015CB856600);the National Natural Science Foundation of China(21422209,21432011,21421091)
A novel hydrido iridium chloride complex supported by a tetradentate PNCP ligand has been synthesized and characterized. Upon activation with NaOtBu, the PNCP-IrHC1 complex is active for transfer dehydrogenation of cy...
关键词:ALKANE DEHYDROGENATION IRIDIUM tetradentate ligand 
New synthetic procedure for Na NH_2(BH_3)_2 and evaluation of its hydrogen storage properties被引量:1
《Science China Chemistry》2015年第1期169-173,共5页Weidong Chen Zhenguo Huang Guotao Wu Ping Chen 
financially supported by the National Natural Science Foundation of China(U1232120,21273229);the Australian Research Council Discovery Early Career Research Award(DE120101496)
Tremendous efforts have been devoted to the synthesis of new light element hydrides for hydrogen storage. Ammonia borane (AB) is a promising candidate possessing high hydrogen capacity and low dehydrogenation temper...
关键词:ammonia borane aminodiborane DEHYDROGENATION hydrogen storage 
A theoretical study of the influence of dopants on the dehydrogenation properties of VH_2
《Science China Chemistry》2011年第9期1510-1517,共8页LI Rong LUO XiaoLing LIANG GuoMing FU WenSheng 
supported by the National Natural Science Foundation of China (20971132);the Natural Science Foundation of Chongqing City (CSTC2009BB4243);the Foundation of Chongqing Municipal Education Commission (KJ090810,KJ070809)
Using the plane wave ultrasoft pseudopotential method based on the first-principles density functional theory(DFT),the influence on the electronic structure and dehydrogenation properties of VH2 doped with Zr,Cu and Z...
关键词:element-doped electronic structure dehydrogenation properties first principles calculation 
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