Supported by the High-level Talents Initiation Project of Luoyang Institute of Technology (2018BZ17);the Pre-research Project of Luoyang Institute of Technology (2018YZ15);the Key Scientific Research Project of Higher Education of Henan Province (20B150016);the Training Program for Young Backbone Teachers of Higher Education of Henan Province (2020GGJS243);the Science and Technology Project of Henan Province (182102210102, 202102210058)
Three isomorphic Ln-MOFs[Ln(bcbob)(H_(2)O)(DMF)](Ln=Tb for 1,Eu for 2,Gd for 3;DMF=N,N-dimethylformamide)have been constructed from a semi-rigid V-shaped organic linker 3,5-bis((4'-carboxyl-benzyl)oxy)benzoilate acid(...
supported by the National Natural Science Foundation of China(21973047);Jiangsu Province Double Innovation Talent Program(090300014001)。
By solvothermal reaction of Cd(II)with organic ligand N,N’-bis(3,5-dicarboxylphenyl)-thiophene-2,5-dicarboxamide(H_(4)L),a water-stable complex[Cd_(4)(H_(2)L)_(4)(H_(2)O)_(10)]·2CH_(3)OH·8H_(2)O·4DMF(1,C_(102)H_(1...
the National Natural Science Foundation of China(21822109,2020000052,21905280,21975254,21950410532,24074283);Key Research Program of Frontier Science,CAS(QYZDB-SSW-SLH023);International Partnership Program of CAS(121835KYSB201800);the Natural Science Foundation of Fujian Province(2017J05094);China Post-doctoral Science Foundation(2019M662254);the Youth Innovation Promotion Association CAS(2018342);Key Laboratory of Jiangxi Province for Persistent Pollutants Control and Resources Recycle Open Research Fund(ES202080085)。
Coordination polymers with structurally designable and energy,fluorescence,electrical etc.properties,are expected to become the next generation of multifunctional materials.A new compound,Zn(OAc)SPhNH(HSPhNH_(2)=4-ami...
A new coordination polymer containing mixed ligands, namely [Ni(S_(2)COiBu)_(2)(DBPMF)·(CHCl_(3))]_(∞)(DBPMF = 2,7-dibromo-9,9-(4-pyridylmethyl)fluorine), has been synthesized and structurally characterized by eleme...
As one important member of main group metals,magnesium(Mg)takes great parts in fields involving biology,medicine,industry,and some others.Because of the unique characteristics including but not limited to low-cost,non...
supported by the Natural Science Foundation of He’nan Educational Committee of China(17A150056);the National Natural Science Foundation of China(21501203);the Funds of Basic and Advanced Technology Research Project of Henan Province of China(192012310497);the Research Fund for the Doctoral Program of Higher Education of China(Zhoukou Normal University,No.ZKNUB2013003);the Funds of Zhoukou Normal University(ZKNUB115202)。
Two new heterobimetallic coordination polymers{[Co(NiL)(H2O)3]·4H2O}n(1)and{[Cu(NiL)(H2O)3]·4H2O}n(2)were synthesized based on metalloligand under the same self-assembly conditions.X-ray diffraction analyses reveal ...
supported by the National Natural Science Foundation of China(No.21271129)。
A pair of enatiomerically pure ligands,(R-)/(S-)2-(4-carboxyphenyl)-4,5-dihydrothiazole-4-carboxylic acid(H2L^R & H2L^S), have been synthesized by the reactions of 4-cyanobenzoic acid with L-and D-cysteine, respective...
supported by the Natural Science Foundation of China(No.21463023);the Project of the Beijing National Laboratory for Molecular Sciences(BNLMS20160155);the Research Funding of Gansu Provincial Department of Education(2016B-072);the Key Project of Tianshui Normal University(TSA1501)。
The performance of organic fluorescent materials can be improved by chemical substitutions with auxochrome groups such as amino to increase solubility, alter emitting color, or modify film quality. The complex 6,6-dif...
supported by Industrial pilot(key)project in Fujian Province(No.2017H0018);Subsidized Project for Postgraduates’Innovative Fund in Scientific Research of Huaqiao University。
Three new metal-organic complexes, namely [Zn(POA)2(H2O)2](1), [Zn(POA)2(H2O)2]·2H2O(2) and [Zn(POA)2]n(3), have been synthesized by organic ligand 2-carboxylic acid-4-nitropyridine-1-oxide(POA) and zinc(Ⅱ) ions. Th...
Financially supported by the Natural Science Foundation of Shandong Province(ZR2013BM007);the National Natural Science Foundation of China(21702119)
Four chiral diorganotin complexes of N-[4-(diethylamino)salicylidene]-(L)-tryptophane,R2Sn[4-(Et2N)-2-OC6H3CH=NCH(CH2Ind)COO](Ind=3-indolyl;R=Me(1);Et,(2);n-Bu(3);Cy(cyclohexyl)(4)),have been synthesized and character...